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Cited by 271

The DOI matches its Crossref record; 16 of the 16 references it cites were found in a registry or an index.

Broadband ac conductivity of conductor-polymer composites

Open access
Connor, Marco T., Roy, Saibal, Ezquerra, Tiberio A., Baltá Calleja, Francisco J.·1998·Physical Review B

Abstract

The electrical conductivity of a composite model system formed by highly structured carbon black (CB) filled, within an amorphous polymer, poly(ethylene terephtalate) composite is studied. The dc conductivity as a function of CB content follows a scaling law of the type $\ensuremath{\sigma}\ensuremath{\propto}(p\ensuremath{-}{p}_{c}{)}^{t}$ yielding for the percolation concentration, ${p}_{c}=0.011$ and for the exponent, $t=2.17$. The analysis of the temperature dependence of the conductivity suggests that for temperatures larger than 45 K, conduction can be ascribed to thermal fluctuation induced tunneling of the charge carriers through the insulating layer of polymer separating two CB aggregates. At lower temperatures, conductivity becomes temperature independent, which is typical of conventional tunneling. The frequency dependence of the conductivity is also studied between dc and ${10}^{9}$ Hz. By the introduction of a shift factor ${a}_{p},$ a procedure for the construction of a master curve based on a ``time-length equivalence principle'' is proposed. Finally, a model is introduced to describe the frequency dependence of the conductivity of CB-filled composites based on the behavior of charge carriers placed in a fractal object.

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Crossref · 10.1103/physrevb.57.2286

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Metadata

Authors
Connor, M. T., Roy, S., Ezquerra, T. A., & Baltá Calleja, F. J.
Venue
Physical Review B
Published
1998-01-15
Volume
57
Issue
4
Pages
2286-2294
ISSN
  • 0163-1829 (ISSN-L)
  • 1095-3795
OpenAlex
W1984215072
Cited by
271
References
16
FWCI
1.76
Type
journal article
Language
en
Open access
bronze

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