Auger Electron Angular Distribution of Double Core-Hole States in the Molecular Reference Frame
Open accessAbstract
The Linac Coherent Light Source free electron laser is a source of high brightness x rays, 2×10(11) photons in a ∼5 fs pulse, that can be focused to produce double core vacancies through rapid sequential ionization. This enables double core vacancy Auger electron spectroscopy, an entirely new way to study femtosecond chemical dynamics with Auger electrons that probe the local valence structure of molecules near a specific atomic core. Using 1.1 keV photons for sequential x-ray ionization of impulsively aligned molecular nitrogen, we observed a rich single-site double core vacancy Auger electron spectrum near 413 eV, in good agreement with ab initio calculations, and we measured the corresponding Auger electron angle dependence in the molecular frame.
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Direct two-photon processes have been observed in above-threshold ionization and in formation of double core hole states.
“Direct two-photon processes have been observed in the manifestation of above threshold ionization [75] and formation of double core hole states [76].”
From Roadmap of ultrafast x-ray atomic and molecular physics (2018) · cites this paper as [76]
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- Authors
- Cryan, J. P., Glownia, J. M., Andreasson, J., Belkacem, A., Berrah, N., Blaga, C. I., Bostedt, C., Bozek, J., Buth, C., DiMauro, L. F., Fang, L., Gessner, O., Guehr, M., Hajdu, J., Hertlein, M. P., Hoener, M., Kornilov, O., Marangos, J. P., March, A. M., McFarland, B. K., Merdji, H., Petrović, V. S., Raman, C., Ray, D., Reis, D., Tarantelli, F., Trigo, M., White, J. L., White, W., Young, L., Bucksbaum, P. H., & Coffee, R. N.
- Affiliations
- SLAC National Accelerator Laboratory (US)
- Uppsala University (SE)
- Lawrence Berkeley National Laboratory (US)
- Western Michigan University (US)
- The Ohio State University (US)
- Louisiana State University (US)
- Imperial College London (GB)
- Argonne National Laboratory (US)
- Commissariat à l'Énergie Atomique et aux Énergies Alternatives (FR)
- Stanford University (US)
- Georgia Institute of Technology (US)
- University of Perugia (IT)
- ORCID
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2010-08-20
- Volume
- 105
- Issue
- 8
- Pages
- 083004-083004
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2133206212
- Cited by
- 177
- References
- 28
- Citations by year
- 2025: 3 · 2024: 3 · 2023: 4 · 2022: 6 · 2021: 8 · 2020: 7 · 2019: 2 · 2018: 7 · 2017: 9 · 2016: 18 · 2015: 17 · 2014: 14 · 2013: 20 · 2012: 31
- FWCI
- 13.52
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Physical Review Letters (publishedVersion)
- PubMed (publishedVersion)
- K-State Research Exchange (Kansas State University) (submittedVersion)
- DESY Publication Database (PUBDB) (Deutsches Elektronen-Synchrotron) (submittedVersion, other-oa)
- The Knowledge Bank (The Ohio State University) (submittedVersion)
- European XFEL (submittedVersion)
- DESY Publication Database (PUBDB) (Deutsches Elektronen-Synchrotron)
- Funders
- National Science Foundation (0649578, DEAC02-05CH11231, 0449235, 0701372)
- U.S. Department of Energy (-AC02-05CH11231, DEFG0292ER14299, Contract No. DE-AC02-05-CH11231, FG02-92ER14299, DE‐FG02‐, 05CH11231, No. DE-AC02-05-CH11231, DE AC02 05CH11231, FG02-04ER15614, DEFG0204ER15614, DE-AC02-)
- Swedish Foundation for International Cooperation in Research and Higher Education
- Vetenskapsrådet
- Basic Energy Sciences (DE-AC02, Contract No. DE-AC02-05-CH11231, DE-AC02-05CH11231., DE-FG02, No. DE-AC02-05-CH11231, AC02–05CH11231, DE-FG02- 04ER15614)
- SLAC National Accelerator Laboratory (DE-AC02-05-CH11231)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Laser-Matter Interactions and Applications
- Physical Sciences › Physics and Astronomy › Radiation › X-ray Spectroscopy and Fluorescence Analysis
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Atomic and Molecular Physics
- Keywords
- double-core-hole states, Auger electron angular distribution, first-principles calculations
- MeSH terms
- Electrons, Light, Nitrogen, Quantum Theory, Spectrum Analysis, Time Factors, Physical Phenomena
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