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Efficient Photovoltaic Current Generation at Ferroelectric Domain Walls

Open access
Seidel, Jan, Fu, Deyi, Yang, Seung-Yeul, Alarcón-Lladó, Esther, Wu, Junqiao, Ramesh, Ramamoorthy, Ager, Joel W.·2011·Physical Review Letters

Abstract

We elucidate the mechanism of a newly observed photovoltaic effect which occurs in ferroelectrics with periodic domain structures. Under sufficiently strong illumination, domain walls function as nanoscale generators of the photovoltaic current. The steps in the electrostatic potential function to accumulate electrons and holes on opposite sides of the walls while locally reducing the concentration of the oppositely charged carriers. As a result, the recombination rate adjacent to the walls is reduced, leading to a net diffusion current. In open circuit, photovoltages for periodically ordered domain walls are additive and voltages much larger than the band gap can be generated. The internal quantum efficiency for individual domain walls can be surprisingly high, approaching 10% for above band-gap photons. Although we have found the effect in BiFeO(3) films, it should occur in any system with a similar periodic potential.

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Metadata

Authors
Seidel, J., Fu, D., Yang, S.-Y., Alarcón-Lladó, E., Wu, J., Ramesh, R., & Ager, J. W.
Venue
Physical Review Letters
Published
2011-09-15
Volume
107
Issue
12
Pages
126805-126805
ISSN
  • 0031-9007 (ISSN-L)
  • 1079-7114
OpenAlex
W2033473244
Cited by
414
References
8
FWCI
11.48
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Efficient Photovoltaic Current Generation at Ferroelectric Domain Walls. https://app.cochat.ai/papers/10.1103/physrevlett.107.126805
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Seidel, J., Fu, D., Yang, S.-Y., Alarcón-Lladó, E., Wu, J., Ramesh, R., & Ager, J. W. (2011). Efficient Photovoltaic Current Generation at Ferroelectric Domain Walls. Physical Review Letters. https://doi.org/10.1103/physrevlett.107.126805

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