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High-Resolution X-Ray Photoelectron Spectroscopy as a Probe of Local Atomic Structure: Application to Amorphous SiO2and the Si-SiO2Interface

Grunthaner, F. J., Grunthaner, P. J., Vasquez, R. P., Lewis, B. F., Maserjian, J., Madhukar, A.·1979·Physical Review Letters

Abstract

The chemical structure of thin Si${\mathrm{O}}_{2}$ films and Si${\mathrm{O}}_{2}$-Si interfaces has been investigated using high-resolution x-ray photoelectron spectroscopy. The data are consistent with a continuous random network of four-, six-, seven-, and eight-member rings of Si${\mathrm{O}}_{4}$ tetrahedra joined together by bridging oxygens. This distribution changes substantially within 30 \AA{} of the Si${\mathrm{O}}_{2}$-Si interface. The near-interface region is comprised of ${\mathrm{Si}}_{2}$${\mathrm{O}}_{3}$, SiO, and ${\mathrm{Si}}_{2}$O. This structure is interpreted by means of a structure-induced-charge-transfer model.

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Metadata

Authors
Grunthaner, F. J., Grunthaner, P. J., Vasquez, R. P., Lewis, B. F., Maserjian, J., & Madhukar, A.
Venue
Physical Review Letters
Published
1979-11-26
Volume
43
Issue
22
Pages
1683-1686
ISSN
0031-9007 (ISSN-L)
OpenAlex
W2005332140
Cited by
365
References
0
FWCI
7.22
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: High-Resolution X-Ray Photoelectron Spectroscopy as a Probe of Local Atomic Structure: Application to Amorphous SiO2and the Si-SiO2Interface. https://app.cochat.ai/papers/10.1103/physrevlett.43.1683
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Grunthaner, F. J., Grunthaner, P. J., Vasquez, R. P., Lewis, B. F., Maserjian, J., & Madhukar, A. (1979). High-Resolution X-Ray Photoelectron Spectroscopy as a Probe of Local Atomic Structure: Application to Amorphous SiO2and the Si-SiO2Interface. Physical Review Letters. https://doi.org/10.1103/physrevlett.43.1683

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