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Optical detection and spectroscopy of single molecules in a solid

Moerner, W. E., Kador, L.·1989·Physical Review Letters

Abstract

Using two different double-modulation techniques, we have observed the optical-absorption spectrum of single dopant molecules of pentacene in a p-terphenyl host crystal at liquid-helium temperatures. To achieve this, frequency-modulation spectroscopy was combined either with Stark or ultrasonic modulation to remove interfering background signals from residual amplitude modulation, and the number of molecules in resonance was reduced to one by operating in the wings of the inhomogeneous line. Triplet bottleneck saturation appears to be suppressed in the single-molecule regime.

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Metadata

Authors
Moerner, W. E., & Kador, L.
Venue
Physical Review Letters
Published
1989-05-22
Volume
62
Issue
21
Pages
2535-2538
ISSN
0031-9007 (ISSN-L)
OpenAlex
W2067733907
Cited by
1,271
References
0
FWCI
9.79
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Optical detection and spectroscopy of single molecules in a solid. https://app.cochat.ai/papers/10.1103/physrevlett.62.2535
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Moerner, W. E., & Kador, L. (1989). Optical detection and spectroscopy of single molecules in a solid. Physical Review Letters. https://doi.org/10.1103/physrevlett.62.2535

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