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Viscosity of Interfacial Water
Abstract
The effective shear viscosity and frequency-dependent dynamic oscillatory shear spectra of water containing monovalent or divalent ions (ionic strength 25 mM), confined between mica crystals at 1-2 water molecules thickness, oscillated with twist angle with the period expected for the pseudohexagonal surface lattice. The effective viscosity varied by orders of magnitude as the twist angle was changed. Confinement appeared to imprint lateral spatial correlation on the ultrathin liquid, the more so the better the confining lattices were aligned, but the oft-proposed "ice structure" was not observed dynamically.
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Cited by
Fluidity of Bound Hydration Layers
Raviv, U., & Klein, J. (2002) · Science · doi:10.1126/science.1074481 · Cited by 721
Molecular Structure of Water at Interfaces: Wetting at the Nanometer Scale
Verdaguer, A., Sacha, G. M., Bluhm, H., & Salmeron, M. (2006) · Chemical Reviews · doi:10.1021/cr040376l · Cited by 627
Interfacial Water at Hydrophobic and Hydrophilic Surfaces: Slip, Viscosity, and Diffusion
Sendner, C., Horinek, D., Bocquet, L., & Netz, R. R. (2009) · Langmuir · doi:10.1021/la901314b · Cited by 567
Thermal Conductance of Hydrophilic and Hydrophobic Interfaces
Ge, Z., Cahill, D. G., & Braun, P. V. (2006) · Physical Review Letters · doi:10.1103/physrevlett.96.186101 · Cited by 455
Long range interactions in nanoscale science
French, R. H., Parsegian, V. A., Podgornik, R., Rajter, R. F., Jagota, A., Luo, J., Asthagiri, D., Chaudhury, M. K., Chiang, Y.-M., Granick, S., et al. (2010) · Reviews of Modern Physics · doi:10.1103/revmodphys.82.1887 · Cited by 441
Self-citation
Metadata
- Authors
- Zhu, Y., & Granick, S.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2001-08-10
- Volume
- 87
- Issue
- 9
- Pages
- 096104-096104
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2118933978
- Cited by
- 269
- References
- 1
- FWCI
- 6.74
- Type
- journal article
- Language
- en
- Open access
- closed
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