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Electron-Electron Interaction Effects on the Optical Excitations of Semiconducting Single-Walled Carbon Nanotubes
Open accessAbstract
We report correlated-electron calculations of optically excited states in ten semiconducting single-walled carbon nanotubes with a wide range of diameters. Optical excitation occurs to excitons whose binding energies decrease with increasing nanotube diameter, and are smaller than the binding energy of an isolated strand of poly-(paraphenylene vinylene). The ratio of the energy of the second optical exciton polarized along the nanotube axis to that of the lowest exciton is smaller than the value predicted within single-particle theory. The experimentally observed weak photoluminescence is an intrinsic feature of semiconducting nanotubes.
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Cites
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Brightening of carbon nanotube photoluminescence through the incorporation of sp3 defects
Piao, Y., Meany, B., Powell, L. R., Valley, N., Kwon, H., Schatz, G. C., & Wang, Y. (2013) · Nature Chemistry · doi:10.1038/nchem.1711 · Cited by 480
Biosensing with Fluorescent Carbon Nanotubes
Ackermann, J., Metternich, J. T., Herbertz, S., & Kruss, S. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202112372 · Cited by 280
Controlling the optical properties of carbon nanotubes with organic colour-centre quantum defects
Brozena, A. H., Kim, M., Powell, L. R., & Wang, Y. (2019) · Nature Reviews Chemistry · doi:10.1038/s41570-019-0103-5 · Cited by 207
Metadata
- Authors
- Zhao, H., & Mazumdar, S.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2004-10-05
- Volume
- 93
- Issue
- 15
- Pages
- 157402-157402
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2035071805
- Cited by
- 329
- References
- 21
- FWCI
- 20.62
- Type
- journal article
- Language
- en
- Open access
- green
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- Zhao, H., & Mazumdar, S. (2004). Electron-Electron Interaction Effects on the Optical Excitations of Semiconducting Single-Walled Carbon Nanotubes. Physical Review Letters. https://doi.org/10.1103/physrevlett.93.157402
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