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Temperature–Time Texture Transition of Pb(Zr 1− x Ti x )O 3 Thin Films: I, Role of Pb‐rich Intermediate Phases
Open accessAbstract
Lead‐rich intermediate phases, in particular Pt 5–7 Pb and PbO, are found to form on Pt(111) atop Ti–buffered Si substrates prior to formation of Pb(Zr 1− x Ti x )O 3 (PZT) thin films. Pt 5–7 Pb is a [111] textured transient intermetallic phase that nucleates PZT[111] texture. PbO is a [001] textured layer compound that nucleates PZT[100] texture. The formation conditions and lattice matching of these intermediate phases have been examined. The presence of other possible intermediate phases, such as pyrochlore and Zr and Ti‐rich phases, has also been investigated but found unrelated to the texture selection of perovskite PZT.
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Citations
Cited by
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Schwartz, R. W. (1997) · Chemistry of Materials · doi:10.1021/cm970286f · Cited by 537
Chemical solution deposition of electronic oxide films
Schwartz, R. W., Schneller, T., & Waser, R. (2004) · Comptes Rendus. Chimie · doi:10.1016/j.crci.2004.01.007 · Cited by 469
Polla, D. L., & Francis, L. F. (1998) · Annual Review of Materials Science · doi:10.1146/annurev.matsci.28.1.563 · Cited by 317
Electrical fatigue of ferroelectric PbZr0.5Ti0.5O3 and antiferroelectric PbZrO3 thin films
Jang, J. H., Yoon, K. H., & Oh, K. Y. (2000) · Materials Research Bulletin · doi:10.1016/s0025-5408(00)00225-7 · Cited by 15
Microstructure Analysis of Porous Lead Zirconate–Titanate Films
Atanova, A. V., Zhigalina, O. M., Khmelenin, D. N., Orlov, G. A., Seregin, D. S., Sigov, A. S., & Vorotilov, K. A. (2022) · Journal of the American Ceramic Society · doi:10.1111/jace.18064 · Cited by 15
Metadata
- Authors
- Chen, S., & Chen, I.
- Venue
- Journal of the American Ceramic Society
- Publisher
- Wiley
- Published
- 1994-09
- Volume
- 77
- Issue
- 9
- Pages
- 2332-2336
- ISSN
- 0002-7820 (ISSN-L)
- 1551-2916
- OpenAlex
- W2160011176
- Cited by
- 228
- References
- 0
- FWCI
- 7.72
- Type
- journal article
- Language
- en
- Open access
- green
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- Chen, S., & Chen, I. (1994). Temperature–Time Texture Transition of Pb(Zr 1− x Ti x )O 3 Thin Films: I, Role of Pb‐rich Intermediate Phases. Journal of the American Ceramic Society. https://doi.org/10.1111/j.1151-2916.1994.tb04602.x
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