The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
THE SPECIFIC ADSORPTION OF DIVALENT Cd, Co, Cu, Pb, AND Zn ON GOETHITE
Abstract
Summary: The specific adsorption of divalent Cd, Co, Cu, Pb, and Zn on goethite is measured as a function of pH. For each mole of heavy metal adsorbed approximately two moles of H+ ions are displaced from the interface. Using these results the heavy metal adsorption data are expressed as functions of the solution concentrations of both H+ and metal ions, and the interfacial reaction is described by the equation, 2 SH+M 2+ = S 2 M+ 2 H + . The adsorption data are consistent with an electrochemical model of the simultaneous adsorption of H + ions and divalent metal ions on to the oxide. The intrinsic affinities of the metal ions for the oxide surface increase in the order, Cd < Co < Zn < Pb < Cu. However, besides the affinity of the metal ion for the surface, the adsorption curves are considered to be influenced by surface charge, the adsorption density of the metal ions and their size. The analysis of the data in terms of H + and M 2+ ion adsorption is considered to be complementary to the hydrolysis model for heavy metal adsorption.
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Cites
The Electrical Double Layer and the Theory of Electrocapillarity.
Grahame, D. C. (1947) · Chemical Reviews · doi:10.1021/cr60130a002 · Cited by 3,323
James, R. O., & Healy, T. W. (1972) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(72)90172-5 · Cited by 537
Dissociation Constants of Inorganic Acids and Bases in Aqueous Solution
Perrin, D. D. (2016) · IUPAC Standards Online · doi:10.1515/iupac.20.0001 · Cited by 284
Rankin, W. J. (2019) · Chemical Thermodynamics · doi:10.1201/9780429277252-12 · Cited by 271
Generalized Model for Anion and Cation Adsorption at Oxide Surfaces
Bowden, J. W., Bolland, M. D. A., Posner, A. M., et al. (1973) · Nature Physical Science · doi:10.1038/physci245081a0 · Cited by 101
Self-citation
Cited by
Ionic-strength and pH effects on the sorption of cadmium and the surface charge of soils
NAIDU, R., BOLAN, N. S., KOOKANA, R. S., & TILLER, K. G. (1994) · European Journal of Soil Science · doi:10.1111/j.1365-2389.1994.tb00527.x · Cited by 565
Bioavailability of heavy metals in soils: definitions and practical implementation—a critical review
Kim, R.-Y., Yoon, J.-K., Kim, T.-S., Yang, J. E., Owens, G., & Kim, K.-R. (2015) · Environmental Geochemistry and Health · doi:10.1007/s10653-015-9695-y · Cited by 541
Heavy Metal Species, Mobility and Availability in Soils
Brümmer, G. W. (1986) · The Importance of Chemical “Speciation” in Environmental Processes · doi:10.1007/978-3-642-70441-3_11 · Cited by 466
Competitive adsorption behavior of heavy metals on kaolinite
Srivastava, P., Singh, B., & Angove, M. (2005) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2005.04.036 · Cited by 357
Heavy metal species, mobility and availability in soils
Bruemmer, G. W., Gerth, J., & Herms, U. (1986) · Zeitschrift für Pflanzenernährung und Bodenkunde · doi:10.1002/jpln.19861490404 · Cited by 319
Metadata
- Authors
- FORBES, E. A., POSNER, A. M., & QUIRK, J. P.
- Venue
- Journal of Soil Science
- Publisher
- Wiley
- Published
- 1976-06
- Volume
- 27
- Issue
- 2
- Pages
- 154-166
- ISSN
- 0022-4588 (ISSN-L)
- OpenAlex
- W2074233838
- Cited by
- 444
- References
- 5
- FWCI
- 23.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- FORBES, E. A., POSNER, A. M., & QUIRK, J. P. (1976). THE SPECIFIC ADSORPTION OF DIVALENT Cd, Co, Cu, Pb, AND Zn ON GOETHITE. Journal of Soil Science. https://doi.org/10.1111/j.1365-2389.1976.tb01986.x
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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