A new approach to geobarometry by combining fluid inclusion and clumped isotope thermometry in hydrothermal carbonates
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This study presents a new approach to geobarometry by combining fluid inclusion and clumped isotope (Δ 47) thermometry on carbonate minerals. The offset between homogenisation temperatures of primary fluid inclusions with known composition and Δ 47 temperatures of the host mineral allows a direct estimation of the fluid pressure at the time of carbonate crystallisation. This new approach is illustrated via hydrothermal dolomite samples from the Variscan foreland fold‐and‐thrust belt in northern Spain. Clumped isotope analyses yield crystallisation temperatures (107–168°C) which are higher than homogenisation temperatures in corresponding samples (95–145°C). The calculated pressure values suggest that dolomitizing fluids were overpressured during formation of zebra dolomite textures, whereas lower pressures are obtained for dolomite cement from breccia textures. This new approach to geobarometry opens up the possibility of estimating the pressure of carbonate crystallisation and has potential applications in diagenesis, basin analysis, ore geology and tectonics.
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Clumped isotope data for subsurface carbonates have placed new constraints on geothermal processes.
“geothermal processes (Honlet et al. 2018, Lu et al. 2018)”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Honlet et al. 2018
Comparisons to other dolomite Δ47-fluid inclusion studies that used calcite-specific Δ47-T calibrations (Came et al., 2017; Honlet et al., 2017) are inconclusive.
“the inconclusive comparisons to other dolomite Δ 47 -fluid inclusion studies that used calcite specific Δ 47 -T calibrations (Came et al., 2017;Honlet et al., 2017)”
From Calibration of the oxygen and clumped isotope thermometers for (proto-)dolomite based on synthetic and natural carbonates (2019) · cites this paper as Honlet et al., 2017
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Cites
Systematics of Fluid Inclusions in Diagenetic Minerals
(1994) · SEPM (Society for Sedimentary Geology) eBooks · doi:10.2110/scn.94.31 · Cited by 1,728 · see citing works
13C–18O bonds in carbonate minerals: a new kind of paleothermometer
Ghosh, P., Adkins, J., Affek, H., Balta, B., Guo, W., Schauble, E. A., Schrag, D., & Eiler, J. M. (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2005.11.014 · Cited by 914 · see citing works
Geologic Pressure Determinations from Fluid Inclusion Studies
Roedder, E., & Bodnar, R. J. (1980) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev.ea.08.050180.001403 · Cited by 773 · see citing works
Zhang, Y., & Frantz, J. D. (1987) · Chemical Geology · doi:10.1016/0009-2541(87)90012-x · Cited by 690 · see citing works
Defining an absolute reference frame for ‘clumped’ isotope studies of CO2
Dennis, K. J., Affek, H. P., Passey, B. H., Schrag, D. P., & Eiler, J. M. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.09.025 · Cited by 627 · see citing works
Fluid inclusions in sedimentary and diagenetic systems
Goldstein, R. H. (2001) · Lithos · doi:10.1016/s0024-4937(00)00044-x · Cited by 495 · see citing works
Huntington, K. W., Eiler, J. M., Affek, H. P., Guo, W., Bonifacie, M., Yeung, L. Y., Thiagarajan, N., Passey, B., Tripati, A., Daëron, M., et al. (2009) · Journal of Mass Spectrometry · doi:10.1002/jms.1614 · Cited by 436 · see citing works
Carbonate clumped isotope bond reordering and geospeedometry
Passey, B. H., & Henkes, G. A. (2012) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2012.07.021 · Cited by 326 · see citing works
Absolute isotopic abundance ratios and the accuracy of Δ47 measurements
Daëron, M., Blamart, D., Peral, M., & Affek, H. P. (2016) · Chemical Geology · doi:10.1016/j.chemgeo.2016.08.014 · Cited by 310 · see citing works
Clumped isotope thermometry of carbonatites as an indicator of diagenetic alteration
Dennis, K. J., & Schrag, D. P. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.04.005 · Cited by 292 · see citing works
Petroleum inclusions in sedimentary basins: systematics, analytical methods and applications
Munz, I. A. (2001) · Lithos · doi:10.1016/s0024-4937(00)00045-1 · Cited by 267 · see citing works
Decollement tectonics in the Hercynian Cordillera of Northwest Spain
Julivert, M. (1971) · American Journal of Science · doi:10.2475/ajs.270.1.1 · Cited by 249 · see citing works
John, C. M., & Bowen, D. (2016) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7720 · Cited by 247 · see citing works
Self-citationMeckler, A. N., Ziegler, M., Millán, M. I., Breitenbach, S. F. M., & Bernasconi, S. M. (2014) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.6949 · Cited by 239 · see citing works
Bonifacie, M., Calmels, D., Eiler, J. M., Horita, J., Chaduteau, C., Vasconcelos, C., Agrinier, P., Katz, A., Passey, B. H., Ferry, J. M., et al. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.11.028 · Cited by 233 · cited 2× · see citing works
“The Kluge et al. (2015) calibration, which is based on calcite, has been shown to be indistinguishable from several other calibrations (Petersen et al., 2017), including calibrations based on dolomite (Bonifacie et al., 2017).”
BackgroundKluge, T., John, C. M., Jourdan, A.-L., Davis, S., & Crawshaw, J. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.02.028 · Cited by 155 · see citing works
Self-citationWeil, A. B., Gutiérrez‐Alonso, G., Johnston, S. T., & Pastor‐Galán, D. (2012) · Tectonophysics · doi:10.1016/j.tecto.2012.10.006 · Cited by 151 · see citing works
Müller, I., Fernandez, A., Radke, J., van Dijk, J., Bowen, D. A., Schwieters, J., & Bernasconi, S. (2017) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7878 · Cited by 138 · see citing works
Gasparrini, M., Bechstädt, T., & Boni, M. (2006) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2006.05.003 · Cited by 128 · see citing works
Self-citationAlonso, J. L. A., MARCOS, A., & Rodríguez, A. S. (2009) · Geologica Acta · doi:10.1344/105.000001449 · Cited by 127 · see citing works
Dale, A., John, C. M., Mozley, P. S., Smalley, P. C., & Muggeridge, A. H. (2014) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2014.03.004 · Cited by 123 · see citing works
Self-citationGutiérrez‐Alonso, G., Collins, A. S., Fernández‐Suárez, J., Pastor‐Galán, D., Clavijo, E. J. G., Jourdan, F., Weil, A. B., & Johnston, S. T. (2015) · Tectonophysics · doi:10.1016/j.tecto.2014.12.009 · Cited by 112 · see citing works
Non‐linear mixing effects on mass‐47 CO 2 clumped isotope thermometry: Patterns and implications
Defliese, W. F., & Lohmann, K. C. (2015) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7175 · Cited by 93 · see citing works
Vandeginste, V., Swennen, R., Gleeson, S. A., Ellam, R. M., Osadetz, K., & Roure, F. (2005) · Sedimentology · doi:10.1111/j.1365-3091.2005.00724.x · Cited by 86 · see citing works
Self-citationEichhubl, P. (2000) · American Journal of Science · doi:10.2475/ajs.300.7.571 · Cited by 85 · see citing works
Hu, B., Radke, J., Schlüter, H., Heine, F., Zhou, L., & Bernasconi, S. (2014) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.6909 · Cited by 79 · see citing works
Clumped isotope thermometry of calcite and dolomite in a contact metamorphic environment
Lloyd, M. K., Eiler, J. M., & Nabelek, P. I. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.037 · Cited by 68 · see citing works
Origin of Dinantian zebra dolomites south of the Brabant‐Wales Massif, Belgium
Nielsen, P., Swennen, R. L., Muchez, P., & Keppens, E. (1998) · Sedimentology · doi:10.1046/j.1365-3091.1998.00171.x · Cited by 63 · see citing works
Self-citationOrigin and migration of palaeofluids in the Upper Visean of the Campine Basin, northern Belgium
Muchez, P., Marshall, J. D., Touret, J. L. R., & Viaene, W. (1994) · Sedimentology · doi:10.1111/j.1365-3091.1994.tb01395.x · Cited by 49 · see citing works
Self-citationGasparrini, M., Bäkker, R. J., & Bechstädt, T. (2006) · Journal of Sedimentary Research · doi:10.2110/jsr.2006.106 · Cited by 38 · see citing works
Self-citationMerino, E., SABATÉ, À. C. I., & Fletcher, R. C. (2006) · Geologica Acta · doi:10.1344/105.000000352 · Cited by 38 · see citing works
Evolution of metamorphic fluids at the Variscan fold-and-thrust belt in eastern Belgium
Schroyen, K., & Muchez, P. (2000) · Sedimentary Geology · doi:10.1016/s0037-0738(99)00133-5 · Cited by 36 · see citing works
Self-citationCame, R. E., Azmy, K., Tripati, A., & Olanipekun, B.-J. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.028 · Cited by 29 · see citing works
(1890) · Geological Magazine · doi:10.1017/s0016756800146205 · Cited by 18 · see citing works
Gasparrini, M. (2003) · heiDOK (Heidelberg University) · doi:10.11588/heidok.00003586 · Cited by 15 · see citing works
Self-citationCarrière, K. L. (2006) · heiDOK (Heidelberg University) · doi:10.11588/heidok.00006664 · Cited by 10 · see citing works
Honlet, R., Gasparrini, M., Jäger, H., Muchez, P., & Swennen, R. (2017) · International Journal of Earth Sciences · doi:10.1007/s00531-017-1541-2 · Cited by 7 · see citing works
Self-citationMuchez, P., & Sintubin, M. (2002) · Lirias · Cited by 5 · see citing works
Self-citationQuijano, I. N. M. (2015) · heiDOK (Heidelberg University) · doi:10.11588/heidok.00018289 · Cited by 2 · see citing works
Flagged first, then by citations
Research works printed but not linked: 1
- [18]18. Petersen, S.V., Daëron, M., Defliese, W.F., John, C.M., Bernasconi, S.M., Colman, A.S., Huntington, K.W., Kelson, J.R., Kluge, T., Olack, G.A., Saenger, C., Schauer, A.J., Bajnai, D., Bonifacie, M., Fiebig, J., Fernandez, A.B., Garcia de Real, P., Henkes, G.A., Katz, A., Kele, S., Lohmann, K.C., Passey, B.H., Petrizzo, D.A., Rosenheim, B.E., Tang, J., Tripati, A.E., Venturelli, R., Young, E.D., Wacker, U. and Winkelstern, I.Z., 2017. Continued efforts towards a universal clumped isotope calibration: updating published calibrations to Brand et al. (2010) parameters. International Workshop on Clumped Isotopes, Paris, August 2017.
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Koeshidayatullah, A., Corlett, H., Stacey, J., Swart, P. K., Boyce, A. J., Robertson, H. A., Whitaker, F., & Hollis, C. (2020) · Sedimentology · doi:10.1111/sed.12729 · Cited by 94 · see citing works
Origin and evolution of fault-controlled hydrothermal dolomitization fronts: A new insight
Koeshidayatullah, A., Corlett, H., Stacey, J., Swart, P. K., Boyce, A. J., & Hollis, C. (2020) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2020.116291 · Cited by 80 · see citing works
Müller, I. A., Rodriguez-Blanco, J. D., Storck, J.-C., do Nascimento, G. S., Bontognali, T. R. R., Vasconcelos, C., Benning, L. G., & Bernasconi, S. M. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2019.07.014 · Cited by 77 · see citing works
Frontiers of Carbonate Clumped Isotope Thermometry
Huntington, K. W., & Petersen, S. V. (2023) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev-earth-031621-085949 · Cited by 66 · see citing works
Pan, L., Hu, A., Liang, F., Jiang, L., Hao, Y., Feng, Y., Shen, A., & Zhao, J. (2021) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2021.105080 · Cited by 44 · see citing works
Lukoczki, G., Haas, J., Gregg, J. M., Machel, H. G., Kele, S., & John, C. M. (2018) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2018.12.004 · Cited by 38 · see citing works
Self-citationMcCormick, C. A., Corlett, H., Clog, M., Boyce, A. J., Tartèse, R., Steele‐MacInnis, M., & Hollis, C. (2023) · Basin Research · doi:10.1111/bre.12789 · Cited by 33 · see citing works
Nooitgedacht, C. W., van der Lubbe, J. J. L., de Graaf, S., Ziegler, M., Staudigel, P. T., & Reijmer, J. J. G. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.12.008 · Cited by 27 · see citing works
Gasparrini, M., Olivier Lacombe, F., Rohais, S., Belkacemi, M., & Euzen, T. (2020) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2020.104826 · Cited by 27 · see citing works
Self-citationMansurbeg, H., Alsuwaidi, M., Salih, N. M., Shahrokhi, S., & Morad, S. (2021) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2021.104989 · Cited by 26 · see citing works
Towards a better understanding of the geochemical proxy record of complex carbonate archives
Mueller, M., Walter, B. F., Giebel, R. J., Beranoaguirre, A., Swart, P. K., Lu, C., Riechelmann, S., & Immenhauser, A. (2024) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2024.04.029 · Cited by 24 · see citing works
Lukoczki, G., Haas, J., Gregg, J. M., Machel, H. G., Kele, S., & John, C. M. (2020) · International Journal of Earth Sciences · doi:10.1007/s00531-020-01851-7 · Cited by 23 · see citing works
Self-citationNardini, N., Muñoz‐López, D., Cruset, D., Cantarero, I., Martín‐Martín, J. D., Benedicto, A., Gómez-Rivas, E., John, C. M., & Travé, A. (2019) · Minerals · doi:10.3390/min9020117 · Cited by 21 · see citing works
Self-citationLu, C., Zou, H., Wang, G., Cong, F., Quan, Y., & Swart, P. K. (2023) · Chemical Geology · doi:10.1016/j.chemgeo.2022.121264 · Cited by 18 · see citing works
Huston, D. L., Trumbull, R. B., Beaudoin, G., & Ireland, T. R. (2023) · Mineral resource reviews · doi:10.1007/978-3-031-27897-6_8 · Cited by 18 · see citing works
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Adlan, Q., Davies, A. J., & John, C. M. (2020) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8802 · Cited by 17 · see citing works
Self-citationMueller, M., Walter, B. F., Swart, P. K., Jöns, N., Jacquemyn, C., Igbokwe, O. A., & Immenhauser, A. (2022) · Journal of Sedimentary Research · doi:10.2110/jsr.2022.047 · Cited by 17 · see citing works
Lu, C., Koeshidayatullah, A., Li, F., Cui, H., Zou, H., & Swart, P. K. (2023) · Sedimentology · doi:10.1111/sed.13144 · Cited by 14 · see citing works
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Liu, J., Li, Z., Wallace, M. W., Hood, A. V. S., Liu, Y., Lu, C., Purkis, S. J., & Swart, P. K. (2023) · AAPG Bulletin · doi:10.1306/10242220140 · Cited by 9 · see citing works
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Jautzy, J. J., Savard, M. M., Lavoie, D., Ardakani, O. H., Dhillon, R. S., Defliese, W. F., & Castagner, A. (2020) · Journal of the Geological Society · doi:10.1144/jgs2020-102 · Cited by 5 · see citing works
Sassarini, N. A. V., Gasparrini, M., Bernasconi, S. M., & Corrado, S. (2023) · Basin Research · doi:10.1111/bre.12814 · Cited by 4 · see citing works
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Spagnolo, G. S., Gori, F., Barberio, M. D., Boschetti, T., Marchesini, B. B., Ruggieri, G., Caracausi, A., Sciarra, A., Paternoster, M., Novella, D., et al. (2025) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2025.179193 · Cited by 4 · see citing works
Chen, P., Fu, M., Deng, H., Wang, X., Wu, D. H., He, P., & Guo, H. (2021) · Minerals · doi:10.3390/min11111212 · Cited by 4 · see citing works
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Lu, Y.-C., Song, S., Liu, L.-W., Peng, T., Chen, B.-C., Tu, R. K.-C., Lin, L., & Wang, P. (2022) · Geothermics · doi:10.1016/j.geothermics.2023.102728 · Cited by 3 · see citing works
Lucca, A., Mittempergher, S., Balsamo, F., Cipriani, A., Cilona, A., & Storti, F. (2025) · Geosciences · doi:10.3390/geosciences15020035 · Cited by 3 · see citing works
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Hollis, S., Dennis, P., Menuge, J., Doran, A., Marca, A., Davidheiser-Kroll, B., Wilkinson, J. J., Snell, K., Turner, O., Güven, J. F., et al. (2024) · Economic Geology · doi:10.5382/econgeo.5100 · Cited by 1 · see citing works
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Ping, H., Deng, W., Chen, H., Guo, Y., Kong, K., Yang, X., & Liu, J. (2024) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2024.106773
- Authors
- Honlet, R., Gasparrini, M., Muchez, P., Swennen, R., & John, C. M.
- Affiliations
- KU Leuven (BE)
- IFP Énergies nouvelles (FR)
- Imperial College London (GB)
- Corresponding author
- Honlet, Robin
- Venue
- Terra Nova
- Publisher
- Wiley
- Published
- 2018-02-12
- Volume
- 30
- Issue
- 3
- Pages
- 199-206
- ISSN
- 0954-4879 (ISSN-L)
- 1365-3121
- OpenAlex
- W2782550030
- Cited by
- 32
- References
- 39
- Citations by year
- 2025: 5 · 2024: 4 · 2023: 6 · 2022: 3 · 2021: 4 · 2020: 6 · 2019: 2 · 2018: 2
- FWCI
- 2.51
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Terra Nova (publishedVersion)
- HAL (submittedVersion, other-oa)
- Archivio Istituzionale della Ricerca (Universita Degli Studi Di Milano) (submittedVersion, other-oa)
- Lirias (submittedVersion, other-oa)
- Spiral (Imperial College London) (submittedVersion)
- Funders
- Fonds Wetenschappelijk Onderzoek (131241)
- Qatar Petroleum
- Shell
- Qatar Science and Technology Park
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Physical Sciences › Engineering › Mechanics of Materials › Hydrocarbon exploration and reservoir analysis
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Keywords
- geobarometry, fluid inclusions, clumped isotope thermometry, hydrothermal carbonates, dolomite, fluid pressure, crystallization temperature, homogenization temperature, dolomite cement, diagenesis
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