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Stable Ordering in Langmuir-Blodgett Films
Abstract
Defects in the layering of Langmuir-Blodgett (LB) films can be eliminated by depositing from the appropriate monolayer phase at the air-water interface. LB films deposited from the hexagonal phase of cadmium arachidate (CdA 2 ) at pH 7 spontaneously transform into the bulk soap structure, a centrosymmetric bilayer with an orthorhombic herringbone packing. A large wavelength folding mechanism accelerates the conversion between the two structures, leading to a disruption of the desired layering. At pH > 8.5, though it is more difficult to draw LB films, almost perfect layering is obtained due to the inability to convert from the as-deposited structure to the equilibrium one.
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Metadata
- Authors
- Takamoto, D. Y., Aydil, E., Zasadzinski, J. A., Ivanova, A. T., Schwartz, D. K., Yang, T., & Cremer, P. S.
- Venue
- Science
- Published
- 2001-08-17
- Volume
- 293
- Issue
- 5533
- Pages
- 1292-1295
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2033144355
- Cited by
- 208
- References
- 0
- FWCI
- 5.43
- Type
- journal article
- Language
- en
- Open access
- closed
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- Takamoto, D. Y., Aydil, E., Zasadzinski, J. A., Ivanova, A. T., Schwartz, D. K., Yang, T., & Cremer, P. S. (2001). Stable Ordering in Langmuir-Blodgett Films. Science. https://doi.org/10.1126/science.1060018
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