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Locally controlling dynamic exchange reactions in 3D printed thiol-acrylate vitrimers using dual-wavelength digital light processing

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Dynamic Enamine-one Bond Based Vitrimer via Amino-yne Click Reaction

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Cost-efficient and recyclable epoxy vitrimer composite with low initial viscosity based on exchangeable disulfide crosslinks

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Facile in situ construction of a covalent adaptable network polyester vitrimer with advanced performance in repairability, foamability and recyclability

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Developing aligned discontinuous flax fibre composites: Sustainable matrix selection and repair performance of vitrimers

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Characterising different molecular landscapes in dynamic covalent networks

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Bio-Based Reprocessable and Degradable Epoxy Resins via Inverse Vulcanization

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Triazabicyclodecene: A versatile catalyst for polymer synthesis

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Sustainable recycling of polymers: a comprehensive review

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Critical Role of Free Amine Groups in the Imine Bonds Exchange in Dynamic Covalent Networks

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Integration of sustainable polymers with phase change materials

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Macromolecular topology and rheology: beyond the tube model

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Reprocessable and Shape Memory Thermosetting Epoxy Resins Based on Silyl Ether Equilibration

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Hydrolysis and Solvolysis as Benign Routes for the End-of-Life Management of Thermoset Polymer Waste

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Polymer actuators based on covalent adaptable networks

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NIR-triggered dynamic exchange and intrinsic photothermal-responsive covalent adaptable networks

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Thiol–acrylate based vitrimers: From their structure–property relationship to the additive manufacturing of self-healable soft active devices

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Blending Polyurethane Thermosets Using Dynamic Urethane Exchange

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Biobased Carbon Fiber Composites with Enhanced Flame Retardancy: A Cradle-to-Cradle Approach

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Investigations on thermoforming of carbon fiber reinforced epoxy vitrimer composites

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Highly Tunable and Robust Dynamic Polymer Networks via Conjugated–Hindered Urea Bonds

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Fully rosin-based epoxy vitrimers with high mechanical and thermostability properties, thermo-healing and closed-loop recycling

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Fast Upcycling of Poly(ethylene terephthalate) into Catalyst-Free Vitrimers

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Ultrastrong, High Fire Resistance, Repairable, and Recyclable Fluorinated Biobased Polyimine Networks

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High‐Performance Yet Sustainable Triboelectric Nanogenerator Based on Sulfur‐Rich Polymer Composite with MXene Segregated Structure

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Self‐Healing Polycaprolactone Networks through Thermo‐Induced Reversible Disulfide Bond Formation

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Investigation of Secondary Amine-Derived Aminal Bond Exchange toward the Development of Covalent Adaptable Networks

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Self-Healable Superomniphobic Surfaces for Corrosion Protection

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Rapid Fabrication of Malleable Fiber Reinforced Composites with Vitrimer Powder

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Multi-Stimuli-Responsive Supramolecular Polymers Based on Noncovalent and Dynamic Covalent Bonds

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Dynamic healable polyurethane for selective laser sintering

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Fusion of biobased vinylogous urethane vitrimers with distinct mechanical properties

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Dynamic Covalent Chemistry at Interfaces: Development of Tougher, Healable Composites through Stress Relaxation at the Resin–Silica Nanoparticles Interface

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Chain breaking in the statistical mechanical constitutive theory of polymer networks

Buche, M. R., & Silberstein, M. N. (2021) · Journal of the Mechanics and Physics of Solids · doi:10.1016/j.jmps.2021.104593 · Cited by 55

Elastomeric polyolefin vitrimer: Dynamic imine bond cross-linked ethylene/propylene copolymer

He, Z., Niu, H., Liu, L., Xie, S., Hua, Z., & Yang, L. (2021) · Polymer · doi:10.1016/j.polymer.2021.124015 · Cited by 55

Regulating the Dynamic Behaviors of Transcarbamoylation-Based Vitrimers via Mono-Variation in Density of Exchangeable Hydroxyl

Miao, P., Leng, X., Liu, J., Song, G., He, M., & Li, Y. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c00127 · Cited by 55

Vanillin-based liquid crystalline polyimine thermosets and their composites for recyclable thermal management application

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Polyurethane vitrimers: Chemistry, properties and applications

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Triblock Elastomeric Vitrimers: Preparation, Morphology, Rheology, and Applications

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Phase separation in supramolecular and covalent adaptable networks

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High-performance poly(thioctic acid)-based thermosets featuring upcycling ability for in situ foaming enabled by dual-dynamic networks

Ma, Y., Zhao, Z., Zheng, Z., Li, J., Li, M., & Hu, J. (2024) · Matter · doi:10.1016/j.matt.2024.08.008 · Cited by 55

Toward self-healing two dimensional MXene coatings for corrosion protection on metals: Design strategies and mechanisms

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A poly (vinyl butyral)/graphene oxide composite with NIR light-induced shape memory effect and solid-state plasticity

Bai, Y., Zhang, J., Wen, D., Gong, P., & Chen, X. (2018) · Composites Science and Technology · doi:10.1016/j.compscitech.2018.11.039 · Cited by 55

Diselenide Bonds as an Alternative to Outperform the Efficiency of Disulfides in Self-Healing Materials

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An acid-degradable biobased epoxy-imine adaptable network polymer for the fabrication of responsive structural color film

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Inherently degradable cross-linked polyesters and polycarbonates: resins to be cheerful

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Engineering entropy in soft matter: the bad, the ugly and the good

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The effect of matrix on shape properties of aromatic disulfide based epoxy vitrimers

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Fully recyclable and high performance phenolic resin based on dynamic urethane bonds and its application in self-repairable composites

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Novel Phosphazene-Based flame retardant polyimine vitrimers with Monomer-Recovery and high performances

Zhang, X., Eichen, Y., Miao, Z., Zhang, S., Cai, Q., Liu, W., Zhao, J., & Wu, Z. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.135806 · Cited by 55

Catalyst-free transesterification vitrimers: activation via α-difluoroesters

Cuminet, F., Berne, D., Lemouzy, S., Eric Dantras, A., Joly‐Duhamel, C., Caillol, S., Leclerc, E., & Ladmiral, V. (2022) · Polymer Chemistry · doi:10.1039/d2py00124a · Cited by 58

Recyclable, self-healing itaconic acid-based polyurethane networks with dynamic boronic ester bonds for recoverable adhesion application

Li, J., Hu, C., Yang, B., Ning, Z., & Zeng, Y. (2022) · Polymer · doi:10.1016/j.polymer.2022.125227 · Cited by 54

Chemically debondable, high-strength and tough adhesives from sulfur-modified epoxy networks

Jin, Y., Wang, Z., Hu, C., Wang, J., Yan, K., Juan, H., Wang, Z., Wang, Z., & Yuan, L. (2023) · Green Chemistry · doi:10.1039/d2gc04744f · Cited by 54

Preparation of lignin-based vinylogous urethane vitrimer materials and their potential use as on-demand removable adhesives

Liu, J., Pich, A., & Bernaerts, K. V. (2023) · Green Chemistry · doi:10.1039/d3gc02799f · Cited by 54

A Vitrimer Acts as a Compatibilizer for Polyethylene and Polypropylene Blends

Yokoyama, K., & Guan, Z. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202317264 · Cited by 54

High biomass content, anti-flammable and degradable epoxy thermosets by curing a tyramine-derived epoxy monomer with a furan-derived diamine for non-destructively recyclable carbon fiber composite application

Niu, H., Yang, T.-M., Wang, X., Zhang, P., Guo, W., Song, L., & Hu, Y. Z. (2024) · Green Chemistry · doi:10.1039/d4gc00333k · Cited by 54

Molecular dynamics studying on welding behavior in thermosetting polymers due to bond exchange reactions

Yang, H. X., Yu, K., Mu, X., Wei, Y., Guo, Y.-F., & Qi, H. J. (2016) · RSC Advances · doi:10.1039/c5ra26128g · Cited by 54

Sustainable Synthetic Approaches for the Preparation of Plant Oil‐Based Thermosets

Llevot, A. (2016) · Journal of the American Oil Chemists Society · doi:10.1007/s11746-016-2932-4 · Cited by 58

Degradable Thermosets Derived from an Isosorbide/Succinic Anhydride Monomer and Glycerol

Wilbon, P. A., Swartz, J. L., Meltzer, N. R., Brutman, J. P., Hillmyer, M. A., & Wissinger, J. E. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b02096 · Cited by 54

Impact of Dynamic Bond Concentration on the Viscoelastic and Mechanical Properties of Dynamic Poly(alkylurea‐co‐urethane) Networks

Chen, L., Zhang, L., Griffin, P. J., & Rowan, S. J. (2019) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201900440 · Cited by 55

An Orthogonal Dynamic Covalent Polymer Network with Distinctive Topology Transformations for Shape‐ and Molecular Architecture Reconfiguration

Miao, W., Yang, B., Jin, B., Ni, C., Feng, H., Xue, Y., Zheng, N., Zhao, Q., Shen, Y., & Xie, T. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202109941 · Cited by 53

Vitrimeric Polylactide by Two-step Alcoholysis and Transesterification during Reactive Processing for Enhanced Melt Strength

Liu, Y., Peng, L., Bao, R., Yang, M., & Yang, W. M. (2022) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.2c15595 · Cited by 54

Harnessing β-Hydroxyl Groups in Poly(β-Amino Esters) toward Robust and Fast Reprocessing Covalent Adaptable Networks

Lee, G., Song, H. Y., Choi, S., Kim, C. B., Hyun, K., & Ahn, S. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c01872 · Cited by 54

Recycling of flame retardant polymers: Current technologies and future perspectives

Bifulco, A., Chen, J., Sekar, A., Wu, W., Gooneie, A., & Gaan, S. (2024) · Journal of Material Science and Technology · doi:10.1016/j.jmst.2024.02.039 · Cited by 58

Catalyst‐Free Dynamic Covalent C=C/C=N Metathesis Reaction for Associative Covalent Adaptable Networks

Li, P., Jiang, X., Gu, R., Tian, H., & Qu, D. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202406708 · Cited by 53

Rapid repair and degradation: A study of high-performance recyclable vitrimer epoxy resin based on disulfide bonds

Liu, H., Liu, C., Liu, Y., Jiang, Y., Li, X., & Bai, Y. (2024) · Polymer Testing · doi:10.1016/j.polymertesting.2024.108528 · Cited by 53

Improving the transesterification and electrical conductivity of vitrimers by doping with conductive polymer wrapped carbon nanotubes

Zhang, H., & Xu, X. (2017) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2017.03.037 · Cited by 52

Reorganizable and stimuli-responsive polymers based on dynamic carbon–carbon linkages in diarylbibenzofuranones

Imato, K., & Otsuka, H. (2018) · Polymer · doi:10.1016/j.polymer.2018.01.038 · Cited by 54

Ordered polypyrrole nanorings with near-infrared spectrum absorption and photothermal conversion performance

Qin, G., & Qiu, J. H. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.11.088 · Cited by 53

Epoxy-polyhedral oligomeric silsesquioxanes (POSS) nanocomposite vitrimers with high strength, toughness, and efficient relaxation

Yang, H.-K., He, C., Russell, T. P., & Wang, D. (2020) · Giant · doi:10.1016/j.giant.2020.100035 · Cited by 53

Self-healing epoxidized natural rubber with ionic/coordination crosslinks

Gong, Z., Huang, J., Cao, L., Xu, C., & Chen, Y. (2022) · Materials Chemistry and Physics · doi:10.1016/j.matchemphys.2022.126063 · Cited by 51

Aero Grade Epoxy Vitrimer towards Commercialization

de Luzuriaga, A. R., Markaide, N., Salaberria, A. M., Azcune, I., Rekondo, A., & Grande, H. J. (2022) · Polymers · doi:10.3390/polym14153180 · Cited by 53

Thia-Michael Reaction: The Route to Promising Covalent Adaptable Networks

Berne, D., Ladmiral, V., Leclerc, E., & Caillol, S. (2022) · Polymers · doi:10.3390/polym14204457 · Cited by 57

Fabrication of malleable, repairable, weldable, recyclable and robust epoxy vitrimers from itaconic acid for recycled adhesion

Yang, W., Yi, Q., Liu, F., Pan, X., & Zeng, Y. (2023) · European Polymer Journal · doi:10.1016/j.eurpolymj.2023.112278 · Cited by 52

Vitrification and plastic flow in transient elastomer networks

Pritchard, R. H., Redmann, A.-L., Pei, Z., Ji, Y. J., & Terentjev, E. M. (2016) · Polymer · doi:10.1016/j.polymer.2016.04.060 · Cited by 51

Recycling of vitrimer blends with tunable thermomechanical properties

Zhang, B., Yuan, C., Zhang, W., Dunn, M. L., Qi, H. J., Liu, Z., Yu, K., & Ge, Q. (2019) · RSC Advances · doi:10.1039/c9ra00015a · Cited by 52

Reconfigurable Poly(urea‐urethane) Thermoset Based on Hindered Urea Bonds with Triple‐Shape‐Memory Performance

Jia, Y., Ying, H., Zhang, Y., He, H., & Cheng, J. (2019) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201900148 · Cited by 52

Hierarchical Dynamics in a Transient Polymer Network Cross-Linked by Orthogonal Dynamic Bonds

Zhang, R., Zhang, C., Yang, Z., Wu, Q., Sun, P., & Wang, X. (2020) · Macromolecules · doi:10.1021/acs.macromol.0c00407 · Cited by 52

A Degradable and Self-Healable Vitrimer Based on Non-isocyanate Polyurethane

Wu, H., Jin, B., Wang, H., Wu, W., Cao, Z., Wu, J., & Huang, G. (2020) · Frontiers in Chemistry · doi:10.3389/fchem.2020.585569 · Cited by 52

Masked Primary Amines for a Controlled Plastic Flow of Vitrimers

Lijsebetten, F. V., Bruycker, K. D., Winne, J. M., & Prez, F. D. (2022) · ACS Macro Letters · doi:10.1021/acsmacrolett.2c00255 · Cited by 53

Functionalization of polyisoprene and polystyrene via reactive processing using azidoformate grafting agents, and its application to the synthesis of dioxaborolane-based polyisoprene vitrimers

Breuillac, A., Caffy, F., Vialon, T., & Nicolaÿ, R. (2020) · Polymer Chemistry · doi:10.1039/d0py00164c · Cited by 52

Reshapeable, rehealable and recyclable sensor fabricated by direct ink writing of conductive composites based on covalent adaptable network polymers

He, X., Lin, Y., Ding, Y., Abdullah, A. M., Lei, Z., Han, Y., Shi, X., Zhang, W., & Yu, K. (2021) · International Journal of Extreme Manufacturing · doi:10.1088/2631-7990/ac37f2 · Cited by 52

Fully biomass-derived vitrimeric material with water-mediated recyclability and monomer recovery

Png, Z. M., Zheng, J., Kamarulzaman, S., Wang, S., Li, Z., & Goh, S. S. (2022) · Green Chemistry · doi:10.1039/d2gc01556k · Cited by 51

Covalent Adaptable Networks through Dynamic N , S -Acetal Chemistry: Toward Recyclable CO 2 -Based Thermosets

Habets, T., Seychal, G., Caliari, M., Raquez, J., Sardón, H., Grignard, B., & Detrembleur, C. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c10080 · Cited by 51

Extrudable, robust and recyclable bio-based epoxy vitrimer via tailoring the topology of a dual dynamic-covalent-bond network

Wang, C., Xu, H., Xie, Z., Zheng, J., & Wu, J. (2023) · Polymer · doi:10.1016/j.polymer.2023.126487 · Cited by 51

Unraveling the rheology of inverse vulcanized polymers

Bischoff, D. J., Lee, T., Kang, K. S., Molineux, J., Parker, W. O., Pyun, J., & Mackay, M. E. (2023) · Nature Communications · doi:10.1038/s41467-023-43117-1 · Cited by 51

Bicontinuous vitrimer heterogels with wide-span switchable stiffness-gated iontronic coordination

Zhao, Z., Cao, Z., Wu, Z., Du, W., Meng, X., Chen, H., Wu, Y., Jiang, L., & Liu, M. (2024) · Science Advances · doi:10.1126/sciadv.adl2737 · Cited by 51

Controlling the Relaxation Dynamics of Polymer Networks by Combining Associative and Dissociative Dynamic Covalent Bonds

Cornellà, A. C., Furia, F., Assche, G. V., & Brancart, J. (2024) · Advanced Materials · doi:10.1002/adma.202407663 · Cited by 52

Biobased vitrimers: towards sustainability and circularity

Mariani, A., & Malucelli, G. (2025) · Chemical Communications · doi:10.1039/d4cc05967k · Cited by 51

Formation of Cross-Linked Films from Immiscible Precursors through Sintering of Vitrimer Nanoparticles

Tran, T. N., Rawstron, E., Bourgeat‐Lami, É., & Montarnal, D. (2018) · ACS Macro Letters · doi:10.1021/acsmacrolett.8b00173 · Cited by 51

Thermally assisted self-healing behavior of anhydride modified polybenzoxazines based on transesterification

Fu, F., Huang, M., Zhang, W., Zhao, Y., & Liu, X. (2018) · Scientific Reports · doi:10.1038/s41598-018-27942-9 · Cited by 51

Low-k and Recyclable High-Performance POSS/Polyamide Composites Based on Diels–Alder Reaction

Luo, K., Song, G., Wang, Y., Yu, J., Zhu, J., & Hu, Z. (2019) · ACS Applied Polymer Materials · doi:10.1021/acsapm.8b00215 · Cited by 50

Solvent-resistant and fully recyclable perfluoropolyether-based elastomer for microfluidic chip fabrication

Liao, S., He, Y., Chu, Y., Liao, H., & Wang, Y. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta03661j · Cited by 51

Waterborne Methacrylate-Based Vitrimers

Lossada, F., Jiao, D., Yao, X., & Walther, A. (2019) · ACS Macro Letters · doi:10.1021/acsmacrolett.9b00997 · Cited by 51

Catalytic Control of Plastic Flow in Siloxane-Based Liquid Crystalline Elastomer Networks

Saed, M. O., & Terentjev, E. M. (2020) · ACS Macro Letters · doi:10.1021/acsmacrolett.0c00265 · Cited by 53

Preparation of Colorless, Highly Transparent, Epoxy-Based Vitrimers by the Thiol-Epoxy Click Reaction and Evaluation of Their Shape-Memory Properties

Hayashi, M., & Katayama, A. (2020) · ACS Applied Polymer Materials · doi:10.1021/acsapm.0c00397 · Cited by 51

Dual Cross-Linked, Polymer Thermosets: Modular Design, Reversible Transformation, and Triggered Debonding

Oh, Y., Park, J., Park, J., Jeong, S., & Kim, H. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c01392 · Cited by 51

Hot-Melt Adhesive Based on Dynamic Oxime–Carbamate Bonds

Zhong, K., Guan, Q., Sun, W., Qin, M., Liu, Z., Zhang, L., Xu, J., Zhang, F., & You, Z. (2021) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.1c00768 · Cited by 51

Arbitrarily Reconfigurable and Thermadapt Reversible Two-Way Shape Memory Poly(thiourethane) Accomplished by Multiple Dynamic Covalent Bonds

Zhou, J., Yue, H., Huang, M., Hao, C., He, S., Liu, H., Liu, W., Zhu, C., Dong, X., & Wang, D. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.1c13057 · Cited by 51

Oligosiloxane-Based Epoxy Vitrimers: Adaptable Thermosetting Networks with Dual Dynamic Bonds

Putnam‐Neeb, A. A., Stafford, A., Babu, S., Chapman, S. J., Hemmingsen, C. M., Islam, M. S., Roy, A. K., Kalow, J. A., Varshney, V., Nepal, D., et al. (2024) · ACS Applied Polymer Materials · doi:10.1021/acsapm.3c03082 · Cited by 30

Toughened epoxy polymers via rearrangement of network topology

Sharifi, M., Jang, C., Abrams, C. F., & Palmese, G. R. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta03051f · Cited by 74

Self-healing and polymer welding of soft and stiff epoxy thermosets via silanolates

Putnam‐Neeb, A. A., Kaiser, J. M., Hubbard, A. M., Street, D. P., Dickerson, M. B., Nepal, D., & Baldwin, L. A. (2022) · Advanced Composites and Hybrid Materials · doi:10.1007/s42114-022-00558-4 · Cited by 53

Enhanced Viscosity Control in Thermosets Derived from Epoxy and Acrylate Monomers Based on Thermoreversible Aza-Michael Chemistry

Engelen, S., Lijsebetten, F. V., Aksakal, R., Winne, J. M., & Prez, F. D. (2023) · Macromolecules · doi:10.1021/acs.macromol.3c01198 · Cited by 20

Some peculiarities of the behaviour of highly crosslinked epoxy-amine networks in the glassy state

Oleinik, E. F. (1981) · Pure and Applied Chemistry · doi:10.1351/pac198153081567 · Cited by 21