The DOI matches its Crossref record.
Exceeding 5000-Fold Concentration of Dilute Analytes in Micellar Electrokinetic Chromatography
Abstract
When a neutral analyte zone is injected into a charged pseudostationary phase, the length of the zone is predicted to be narrowed by 1/(1 + k ), where k is the retention factor. The conditions for zone narrowing to occur assume negligible electroosmotic flow, a relatively constant electric field along the capillary column, and no pseudostationary phase in the injected analyte mixture. The theoretically expected concentration enhancement was demonstrated experimentally. Consequently, the detection sensitivity of analytes in micellar electrokinetic chromatography (MEKC) can be improved significantly. For example, 9 to 18 parts per billion of an environmentally important racemic herbicide spiked in lake water was separated by MEKC and detected by ultraviolet absorption.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Chen, Y., Guo, Z., Wang, X., & Qiu, C. (2008) · Journal of Chromatography A · doi:10.1016/j.chroma.2007.10.026 · Cited by 316
Wang, C., Li, C., Zang, X., Han, D., Liu, Z., & Wang, Z. (2007) · Journal of Chromatography A · doi:10.1016/j.chroma.2007.01.027 · Cited by 56
Metadata
- Authors
- Quirino, J. P., & Terabe, S.
- Venue
- Science
- Published
- 1998-10-16
- Volume
- 282
- Issue
- 5388
- Pages
- 465-468
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2005086794
- Cited by
- 644
- References
- 0
- FWCI
- 26.42
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Exceeding 5000-Fold Concentration of Dilute Analytes in Micellar Electrokinetic Chromatography. https://app.cochat.ai/papers/10.1126/science.282.5388.465
- The paper
- Quirino, J. P., & Terabe, S. (1998). Exceeding 5000-Fold Concentration of Dilute Analytes in Micellar Electrokinetic Chromatography. Science. https://doi.org/10.1126/science.282.5388.465
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
