The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Stable Five- and Six-Coordinated Silicate Anions in Aqueous Solution
Abstract
Addition of aliphatic polyols to aqueous silicate solutions is shown to yield high concentrations of stable polyolate complexes containing five- or six-coordinated silicon. Coordinating polyols require at least four hydroxy groups, two of which must be in threo configuration, and coordinate to silicon via hydroxy oxygens at chain positions on either side of the threo pair. The remarkable ease by which these simple sugar-like molecules react to form hypervalent silicon complexes in aqueous solution supports a long-standing supposition that such species play a significant role in the biological uptake and transport of silicon and in mineral diagenesis.
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Cites
The essentiality of silicon in biology
Birchall, J. D. (1995) · Chemical Society Reviews · doi:10.1039/cs9952400351 · Cited by 126
Cited by
The hydrothermal synthesis of zeolites: Precursors, intermediates and reaction mechanism
Cundy, C. S., & Cox, P. A. (2005) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2005.02.016 · Cited by 1,590
Reffitt, D. M., Ogston, N., Jugdaohsingh, R., Cheung, H. F. J., Evans, B. A. J., Thompson, R. P. H., Powell, J. J., & Hampson, G. N. (2003) · Bone · doi:10.1016/s8756-3282(02)00950-x · Cited by 876
Silicon: its manifold roles in plants.
Epstein, E. (2009) · Annals of Applied Biology · doi:10.1111/j.1744-7348.2009.00343.x · Cited by 680
Fire‐Retardant and Thermally Insulating Phenolic‐Silica Aerogels
Yu, Z., Yang, N., Apostolopoulou‐Kalkavoura, V., Qin, B., Ma, Z., Xing, W., Qiao, C., Bergström, L., Antonietti, M., & Yu, S. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201711717 · Cited by 448
Phair, J. W., & Van Deventer, J. S. J. (2002) · International Journal of Mineral Processing · doi:10.1016/s0301-7516(02)00013-3 · Cited by 295
Metadata
- Authors
- Kinrade, S. D., Del Nin, J. W., Schach, A. S., Sloan, T. A., Wilson, K. L., & Knight, C. T. G.
- Venue
- Science
- Published
- 1999-09-03
- Volume
- 285
- Issue
- 5433
- Pages
- 1542-1545
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2009043709
- Cited by
- 205
- References
- 1
- FWCI
- 8.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kinrade, S. D., Del Nin, J. W., Schach, A. S., Sloan, T. A., Wilson, K. L., & Knight, C. T. G. (1999). Stable Five- and Six-Coordinated Silicate Anions in Aqueous Solution. Science. https://doi.org/10.1126/science.285.5433.1542
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
