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Cited by 1,703

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Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes

Kamysbayev, Vladislav, Filatov, Alexander S., Hu, Huicheng, Rui, Xue, Lagunas, Francisco, Wang, Di, Klie, Robert F., Talapin, Dmitri V.·2020·Science

Abstract

Modifying MXene surfaces: Unlike graphene and transition-metal dichalcogenides, two-dimensional transition-metal carbides (MXenes) have many surface sites that can be chemically modified. Etching of the aluminum layer of a parent MAX phase Ti 3 AlC 2 layered material with hydrofluoric acid leads to the MXene Ti 3 C 2 with various surface terminations. Molten salts can achieve uniform chloride terminations, but these are difficult to further modify. Kamysbayev et al. show that etching of MAX phases in molten cadmium bromide leads to bromide-terminated MXenes that can then be substituted with oxygen, sulfur, selenium, tellurium, and NH groups as well as with vacancy sites. The surface groups can alter electronic transport. For example, the Nb 2 C MXenes exhibit surface group–dependent superconductivity. Science , this issue p. 979

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Metadata

Authors
Kamysbayev, V., Filatov, A. S., Hu, H., Rui, X., Lagunas, F., Wang, D., Klie, R. F., & Talapin, D. V.
Venue
Science
Published
2020-08-21
Volume
369
Issue
6506
Pages
979-983
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W3039783515
Cited by
1,703
References
1
FWCI
75.23
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes. https://app.cochat.ai/papers/10.1126/science.aba8311
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Kamysbayev, V., Filatov, A. S., Hu, H., Rui, X., Lagunas, F., Wang, D., Klie, R. F., & Talapin, D. V. (2020). Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes. Science. https://doi.org/10.1126/science.aba8311

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