The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes
Abstract
Modifying MXene surfaces: Unlike graphene and transition-metal dichalcogenides, two-dimensional transition-metal carbides (MXenes) have many surface sites that can be chemically modified. Etching of the aluminum layer of a parent MAX phase Ti 3 AlC 2 layered material with hydrofluoric acid leads to the MXene Ti 3 C 2 with various surface terminations. Molten salts can achieve uniform chloride terminations, but these are difficult to further modify. Kamysbayev et al. show that etching of MAX phases in molten cadmium bromide leads to bromide-terminated MXenes that can then be substituted with oxygen, sulfur, selenium, tellurium, and NH groups as well as with vacancy sites. The surface groups can alter electronic transport. For example, the Nb 2 C MXenes exhibit surface group–dependent superconductivity. Science , this issue p. 979
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Citations
Cites
Raman Spectroscopy Analysis of the Structure and Surface Chemistry of Ti3C2T x MXene
Sarycheva, A., & Gogotsi, Y. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c00359 · Cited by 1,467
Cited by
Ten Years of Progress in the Synthesis and Development of MXenes
Naguib, M., Barsoum, M. W., & Gogotsi, Y. (2021) · Advanced Materials · doi:10.1002/adma.202103393 · Cited by 1,257
A Review on MXene Synthesis, Stability, and Photocatalytic Applications
Murali, G., Reddy Modigunta, J. K., Park, Y. H., Lee, J.-H., Rawal, J., Lee, S.-Y., In, I., & Park, S.-J. (2022) · ACS Nano · doi:10.1021/acsnano.2c04750 · Cited by 668
Recent Advances in Oxidation Stable Chemistry of 2D MXenes
Cao, F., Zhang, Y., Wang, H., Khan, K., Tareen, A. K., Qian, W., Zhang, H., & Ågren, H. (2022) · Advanced Materials · doi:10.1002/adma.202107554 · Cited by 648
Ambient‐Stable Two‐Dimensional Titanium Carbide (MXene) Enabled by Iodine Etching
Shi, H., Zhang, P., Liu, Z., Park, S., Lohe, M. R., Wu, Y., Shaygan Nia, A., Yang, S., & Feng, X. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202015627 · Cited by 459
High‐Entropy Atomic Layers of Transition‐Metal Carbides (MXenes)
Du, Z., Wu, C., Chen, Y., Cao, Z., Hu, R., Zhang, Y., Gu, J., Cui, Y., Chen, H., Shi, Y., et al. (2021) · Advanced Materials · doi:10.1002/adma.202101473 · Cited by 322
Metadata
- Authors
- Kamysbayev, V., Filatov, A. S., Hu, H., Rui, X., Lagunas, F., Wang, D., Klie, R. F., & Talapin, D. V.
- Venue
- Science
- Published
- 2020-08-21
- Volume
- 369
- Issue
- 6506
- Pages
- 979-983
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W3039783515
- Cited by
- 1,703
- References
- 1
- FWCI
- 75.23
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kamysbayev, V., Filatov, A. S., Hu, H., Rui, X., Lagunas, F., Wang, D., Klie, R. F., & Talapin, D. V. (2020). Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes. Science. https://doi.org/10.1126/science.aba8311
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