The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Nitrogen reduction to ammonia at high efficiency and rates based on a phosphonium proton shuttle
Open accessAbstract
Shuttling protons in ammonia synthesis: An electrochemical route to ammonia could substantially lower the greenhouse gas emissions associated with the current thermal Haber-Bosch process. One relatively promising option under study involves reductive formation of lithium nitride, which can be protonated to ammonia. However, the ethanol used to date as a local proton source in these studies may degrade under the reaction conditions. Suryanto et al. report the use of a tetraalkyl phosphonium salt in place of ethanol (see the Perspective by Westhead et al. ). This cation can stably undergo deprotonation–reprotonation cycles and, as an added benefit, it enhances the ionic conductivity of the medium. Science , abg2371, this issue p. 1187 ; see also abi8329, p. 1149
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Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Review of electrochemical ammonia production technologies and materials
Giddey, S., Badwal, S. P. S., & Kulkarni, A. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.09.054 · Cited by 886
Energy efficiency improvements in ammonia production—perspectives and uncertainties
Rafiqul, I., Weber, C., Lehmann, B., & Voss, A. (2005) · Energy · doi:10.1016/j.energy.2004.12.004 · Cited by 439
Cited by
Continuous-flow electrosynthesis of ammonia by nitrogen reduction and hydrogen oxidation
Fu, X., Pedersen, J. B., Zhou, Y., Saccoccio, M., Li, S., Sažinas, R., Li, K., Andersen, S. Z., Xu, A., Deissler, N. H., et al. (2023) · Science · doi:10.1126/science.adf4403 · Cited by 616
Ammonia and Nitric Acid Demands for Fertilizer Use in 2050
Lim, J., Fernández, C. A., Lee, S. W., & Hatzell, M. C. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c01614 · Cited by 523
Pulsed Nitrate-to-Ammonia Electroreduction Facilitated by Tandem Catalysis of Nitrite Intermediates
Li, P., Li, R., Liu, Y., Xie, M., Jin, Z., & Yu, G. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c00334 · Cited by 466
Electroreduction of nitrogen with almost 100% current-to-ammonia efficiency
Du, H.-L., Chatti, M., Hodgetts, R. Y., Cherepanov, P. V., Nguyen, C. K., Matuszek, K., MacFarlane, D. R., & Simonov, A. N. (2022) · Nature · doi:10.1038/s41586-022-05108-y · Cited by 448
Self-citationA comprehensive review of solid oxide fuel cells operating on various promising alternative fuels
Xu, Q., Guo, Z., Xia, L., He, Q., Li, Z., Temitope Bello, I., Zheng, K., & Ni, M. (2022) · Energy Conversion and Management · doi:10.1016/j.enconman.2021.115175 · Cited by 382
Metadata
- Authors
- Suryanto, B. H. R., Matuszek, K., Choi, J., Hodgetts, R. Y., Du, H.-L., Bakker, J. M., Kang, C. S. M., Cherepanov, P. V., Simonov, A. N., & MacFarlane, D. R.
- Venue
- Science
- Published
- 2021-06-11
- Volume
- 372
- Issue
- 6547
- Pages
- 1187-1191
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W3169660990
- Cited by
- 644
- References
- 3
- FWCI
- 19.69
- Type
- journal article
- Language
- en
- Open access
- green
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- Suryanto, B. H. R., Matuszek, K., Choi, J., Hodgetts, R. Y., Du, H.-L., Bakker, J. M., Kang, C. S. M., Cherepanov, P. V., Simonov, A. N., & MacFarlane, D. R. (2021). Nitrogen reduction to ammonia at high efficiency and rates based on a phosphonium proton shuttle. Science. https://doi.org/10.1126/science.abg2371
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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