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Direct synthesis and chemical vapor deposition of 2D carbide and nitride MXenes

Open access
Wang, Di, Zhou, Chenkun, Filatov, Alexander S., Cho, Wooje, Lagunas, Francisco, Wang, Mingzhan, Vaikuntanathan, Suriyanarayanan, Liu, Chong, Klie, Robert F., Talapin, Dmitri V.·2023·Science

Abstract

Two-dimensional transition-metal carbides and nitrides (MXenes) are a large family of materials actively studied for various applications, especially in the field of energy storage. MXenes are commonly synthesized by etching the layered ternary compounds, called MAX phases. We demonstrate a direct synthetic route for scalable and atom-economic synthesis of MXenes, including compounds that have not been synthesized from MAX phases, by the reactions of metals and metal halides with graphite, methane, or nitrogen. The direct synthesis enables chemical vapor deposition growth of MXene carpets and complex spherulite-like morphologies that form through buckling and release of MXene carpet to expose fresh surface for further reaction. The directly synthesized MXenes showed excellent energy storage capacity for lithium-ion intercalation.

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Metadata

Authors
Wang, D., Zhou, C., Filatov, A. S., Cho, W., Lagunas, F., Wang, M., Vaikuntanathan, S., Liu, C., Klie, R. F., & Talapin, D. V.
Venue
Science
Published
2023-03-24
Volume
379
Issue
6638
Pages
1242-1247
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W4360609356
Cited by
744
References
46
FWCI
52.35
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Direct synthesis and chemical vapor deposition of 2D carbide and nitride MXenes. https://app.cochat.ai/papers/10.1126/science.add9204
The paper
Wang, D., Zhou, C., Filatov, A. S., Cho, W., Lagunas, F., Wang, M., Vaikuntanathan, S., Liu, C., Klie, R. F., & Talapin, D. V. (2023). Direct synthesis and chemical vapor deposition of 2D carbide and nitride MXenes. Science. https://doi.org/10.1126/science.add9204

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.