Determination of the oxidation states of metals and metalloids: An analytical review
Abstract
The hazard of many heavy metals/metalloids in the soil depends on their oxidation state. The problem of determining the oxidation state has been solved due to the use of synchrotron radiation methods with the analysis of the X-ray absorption near-edge structure (XANES). The determination of the oxidation state is of special importance for some hazardous heavy elements (arsenic, antimony, selenium, chromium, uranium, and vanadium). The mobility and hazard of each of these elements depend on its oxidation state. The mobilities are higher at lower oxidation states of As, Cr, V, and Se and at higher oxidation states of Sb and U. The determination of the oxidation state of arsenic has allowed revealing its fixation features in the rhizosphere of hydrophytes. The known oxidation states of chromium and uranium are used for the retention of these elements on geochemical barriers. Different oxidation states have been established for vanadium displacing iron in goethite. The determination of the oxidation state of manganese in the rhizosphere and the photosynthetic apparatus of plants is of special importance for agricultural chemists.
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The bioavailability of metal(loid)s is closely interlinked with their chemical speciation.
“many scientific studies demonstrated that the bioavailability of the metal(loid)s is closely interlinked with their chemical speciation [82 -85].”
From Chemical Processes Affecting the Mobility of Heavy Metals and Metalloids in Soil Environments (2016) · cites this paper as [83]
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- Authors
- Vodyanitskii, Y. N.
- Venue
- Eurasian Soil Science
- Publisher
- Pleiades Publishing Ltd
- Published
- 2013-12
- Volume
- 46
- Issue
- 12
- Pages
- 1139-1149
- ISSN
- 1064-2293 (ISSN-L)
- 1556-195X
- OpenAlex
- W2088012892
- Cited by
- 19
- References
- 89
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 3 · 2022: 2 · 2021: 2 · 2020: 2 · 2019: 1 · 2018: 1 · 2017: 2 · 2016: 2 · 2015: 2
- FWCI
- 1.32
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Eurasian Soil Science (publishedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Radiation › X-ray Spectroscopy and Fluorescence Analysis
- Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Keywords
- metal oxidation state, metalloids, X-ray absorption near edge structure, synchrotron radiation, heavy metals in soil, arsenic, antimony, selenium, chromium, uranium, vanadium, manganese, element mobility, geochemical barriers, rhizosphere, goethite, photosynthetic apparatus, soil contamination
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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