Cited by 19X-ray Spectroscopy and Fluorescence AnalysisHeavy metals in environmentEnvironmental and Analytical Chemistry Studies

Determination of the oxidation states of metals and metalloids: An analytical review

Vodyanitskii, Yu. N.·2013·Eurasian Soil Science

Abstract

The hazard of many heavy metals/metalloids in the soil depends on their oxidation state. The problem of determining the oxidation state has been solved due to the use of synchrotron radiation methods with the analysis of the X-ray absorption near-edge structure (XANES). The determination of the oxidation state is of special importance for some hazardous heavy elements (arsenic, antimony, selenium, chromium, uranium, and vanadium). The mobility and hazard of each of these elements depend on its oxidation state. The mobilities are higher at lower oxidation states of As, Cr, V, and Se and at higher oxidation states of Sb and U. The determination of the oxidation state of arsenic has allowed revealing its fixation features in the rhizosphere of hydrophytes. The known oxidation states of chromium and uranium are used for the retention of these elements on geochemical barriers. Different oxidation states have been established for vanadium displacing iron in goethite. The determination of the oxidation state of manganese in the rhizosphere and the photosynthetic apparatus of plants is of special importance for agricultural chemists.

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Crossref · 10.1134/s1064229313120077

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Authors
Vodyanitskii, Y. N.
Venue
Eurasian Soil Science
Published
2013-12
Volume
46
Issue
12
Pages
1139-1149
ISSN
  • 1064-2293 (ISSN-L)
  • 1556-195X
OpenAlex
W2088012892
Cited by
19
References
89
Citations by year
2026: 1 · 2025: 1 · 2024: 3 · 2022: 2 · 2021: 2 · 2020: 2 · 2019: 1 · 2018: 1 · 2017: 2 · 2016: 2 · 2015: 2
FWCI
1.32
Type
journal article
Language
en
Open access
closed
Locations
Eurasian Soil Science (publishedVersion)
Topics
  • Physical Sciences › Physics and Astronomy › Radiation › X-ray Spectroscopy and Fluorescence Analysis
  • Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
  • Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
Keywords
metal oxidation state, metalloids, X-ray absorption near edge structure, synchrotron radiation, heavy metals in soil, arsenic, antimony, selenium, chromium, uranium, vanadium, manganese, element mobility, geochemical barriers, rhizosphere, goethite, photosynthetic apparatus, soil contamination

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