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The Dealloying Critical Potential

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Sieradzki, K., Dimitrov, N., Movrin, D., McCall, C., Vasiljevic, N., Erlebacher, J.·2002·Journal of The Electrochemical Society

Abstract

This paper reexamines the concept of the dealloying critical potential by considering the critical potential to be a kinetically controlled morphological transition dependent not only on extensive system parameters such as alloy and electrolyte composition, but also on the rate of application of an intrinsic parameter such as the potential ramp rate. In the limit of a quasi-static potential sweep rate, an expression for the critical potential is derived which considers both compositional and morphological fluctuations on the alloy surface at the incipient point of either stability (passivation) or instability (bulk dealloying). In addition, we present detailed critical potential results for the entire range of Ag-Au alloy compositions in and and 1). These results are shown to be consistent with the expression for the critical potential. Finally, we present and discuss ancillary experiments examining the effect of potential sweep rate on the determination of the critical potential. © 2002 The Electrochemical Society. All rights reserved.

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Metadata

Authors
Sieradzki, K., Dimitrov, N., Movrin, D., McCall, C., Vasiljevic, N., & Erlebacher, J.
Venue
Journal of The Electrochemical Society
Published
2002
Volume
149
Issue
8
Pages
B370
ISSN
0013-4651 (ISSN-L)
OpenAlex
W2088020291
Cited by
260
References
3
FWCI
3.28
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: The Dealloying Critical Potential. https://app.cochat.ai/papers/10.1149/1.1492288
The paper
Sieradzki, K., Dimitrov, N., Movrin, D., McCall, C., Vasiljevic, N., & Erlebacher, J. (2002). The Dealloying Critical Potential. Journal of The Electrochemical Society. https://doi.org/10.1149/1.1492288

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.