The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Electrocatalytic Activity Studies of Select Metal Surfaces and Implications in Li-Air Batteries
Open accessAbstract
Rechargeable lithium-air batteries have the potential to provide ≈3 times higher specific energy of fully packaged batteries than conventional lithium rechargeable batteries. However, very little is known about the oxygen reduction reaction (ORR) and oxygen evolution in the presence of lithium ions in aprotic electrolytes, which hinders the improvement of low round-trip efficiencies of current lithium-air batteries. We report the intrinsic ORR activity on glassy carbon (GC) as well as polycrystalline Au and Pt electrodes, where Au is the most active with an activity trend of . Rotating disk electrode (RDE) measurements were used to obtain the kinetic current of the ORR and the reaction order with respect to oxygen partial pressure in 1 M propylene carbonate:1,2-dimethoxyethane (1:2 v/v). In addition, air electrodes with Vulcan carbon or Au or Pt nanoparticles supported on Vulcan were examined in single cells, where the observed discharge cell voltages follow the catalytic trend established by RDE measurements. The ORR mechanism and the rate-determining steps were discussed and contrasted with the ORR activity trend in acid and alkaline solutions.
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Gasteiger, H. A., Kocha, S. S., Sompalli, B., & Wagner, F. T. (2005) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2004.06.021 · Cited by 4,876
Self-citationMarkovic, N., Gasteiger, H., & Ross, P. N. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1837646 · Cited by 564
Self-citationAdsorbate‐Induced Surface Segregation for Core–Shell Nanocatalysts
Mayrhofer, K. J. J., Juhart, V., Hartl, K., Hanzlik, M., & Arenz, M. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806209 · Cited by 319
Cited by
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Graphene and Graphene‐Based Materials for Energy Storage Applications
Zhu, J., Yang, D., Yin, Z., Yan, Q., & Zhang, H. (2014) · Small · doi:10.1002/smll.201303202 · Cited by 825
Current density dependence of peroxide formation in the Li–O2 battery and its effect on charge
Adams, B. D., Radtke, C., Black, R., Trudeau, M. L., Zaghib, K., & Nazar, L. F. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40697k · Cited by 678
Catalytic Activity Trends of Oxygen Reduction Reaction for Nonaqueous Li-Air Batteries
Lu, Y.-C., Gasteiger, H. A., & Shao-Horn, Y. (2011) · Journal of the American Chemical Society · doi:10.1021/ja208608s · Cited by 567
Self-citationRuthenium-Based Electrocatalysts Supported on Reduced Graphene Oxide for Lithium-Air Batteries
Jung, H.-G., Jeong, Y. S., Park, J.-B., Sun, Y.-K., Scrosati, B., & Lee, Y. J. (2013) · ACS Nano · doi:10.1021/nn400477d · Cited by 382
Metadata
- Authors
- Lu, Y.-C., Gasteiger, H. A., Crumlin, E., McGuire, R., & Shao-Horn, Y.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2010
- Volume
- 157
- Issue
- 9
- Pages
- A1016
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2135571158
- Cited by
- 275
- References
- 3
- FWCI
- 13.64
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Lu, Y.-C., Gasteiger, H. A., Crumlin, E., McGuire, R., & Shao-Horn, Y. (2010). Electrocatalytic Activity Studies of Select Metal Surfaces and Implications in Li-Air Batteries. Journal of The Electrochemical Society. https://doi.org/10.1149/1.3462981
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