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Cited by 439

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Rechargeable Lithium/TEGDME-LiPF[sub 6]∕O[sub 2] Battery

Open access
Laoire, Cormac Ó, Mukerjee, Sanjeev, Plichta, Edward J., Hendrickson, Mary A., Abraham, K. M.·2011·Journal of The Electrochemical Society

Abstract

A rechargeable Li–air cell utilizing an electrolyte composed of a solution of in tetraethylene glycol dimethyl ether, (TEGDME), and an uncatalyzed porous carbon electrode, investigated to elucidate the baseline Li–air battery chemistry, is reported. From the x-ray diffraction patterns of the discharged carbon electrodes, the discharge product of the cell was identified to be during normal discharge to . Discharging the cell to or below produces as well. The cell can be recharged without a catalyst in the carbon cathode, albeit at low depths of discharge. The high resistance of the discharged carbon cathode is a major impediment to recharging cells displaying a high specific capacity. The cell capacity decreases with continued cycling, which was found to be due to the poor cycling efficiency of the Li anode and the high resistance of the discharge products, which slowly accumulate in the porous electrode.

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Crossref · 10.1149/1.3531981

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Metadata

Authors
Laoire, C. O., Mukerjee, S., Plichta, E. J., Hendrickson, M. A., & Abraham, K. M.
Venue
Journal of The Electrochemical Society
Published
2011
Volume
158
Issue
3
Pages
A302
ISSN
0013-4651 (ISSN-L)
OpenAlex
W1664474894
Cited by
439
References
1
FWCI
46.35
Type
journal article
Language
en
Open access
bronze

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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