The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Carbon Corrosion in PEM Fuel Cells and the Development of Accelerated Stress Tests
Open accessAbstract
Carbon corrosion is an important degradation mechanism that can impair PEMFC performance through the destruction of catalyst connectivity, collapse of the electrode pore structure, loss of hydrophobic character, and an increase of the catalyst particle size. In this study, carbon corrosion was quantified in situ by measurement of carbon dioxide in the fuel cell exhaust gases through non-dispersive infrared spectroscopy during simulated drive cycle operations consisting of potential cycling with varying upper and lower potential limits. These studies were conducted for three different types of carbon supports. A reduction in the catalyst layer thickness was observed during a simulated drive cycle operation with a concomitant decrease in catalyst layer porosity, which led to performance losses due to increased mass transport limitations. The observed thickness reduction was primarily due to compaction of the catalyst layer, with the actual mass of carbon oxidation (loss) contributing only a small fraction (< 20%). The dynamics of carbon corrosion are presented along with a model that simulates the transient and dynamic corrosion rates observed in our experiments. Accelerated carbon corrosion stress tests are presented and their effects are compared to those observed for the drive cycle test.
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Cites
Atlas of Electrochemical Equilibria in Aqueous Solutions
Pourbaix, M. (1974) · doi:10.5006/37502 · Cited by 8,026
Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation
Borup, R., Meyers, J., Pivovar, B., Kim, Y. S., Mukundan, R., Garland, N., Myers, D., Wilson, M., Garzon, F., Wood, D., et al. (2007) · Chemical Reviews · doi:10.1021/cr050182l · Cited by 3,402
Self-citationA Reverse-Current Decay Mechanism for Fuel Cells
Reiser, C. A., Bregoli, L., Patterson, T. W., Yi, J. S., Yang, J. D., Perry, M. L., & Jarvi, T. D. (2005) · Electrochemical and Solid-State Letters · doi:10.1149/1.1896466 · Cited by 976
Carbon support oxidation in PEM fuel cell cathodes
Maass, S., Finsterwalder, F., Frank, G., Hartmann, R., & Merten, C. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2007.08.053 · Cited by 740
Electrocatalytic Corrosion of Carbon Support in PEMFC Cathodes
Roen, L. M., Paik, C. H., & Jarvi, T. D. (2004) · Electrochemical and Solid-State Letters · doi:10.1149/1.1630412 · Cited by 658
Characterization of Vulcan Electrochemically Oxidized under Simulated PEM Fuel Cell Conditions
Kangasniemi, K. H., Condit, D. A., & Jarvi, T. D. (2004) · Journal of The Electrochemical Society · doi:10.1149/1.1649756 · Cited by 599
Chalk, S. G., & Miller, J. F. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.04.058 · Cited by 545
PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode
Tang, H., Qi, Z., Ramani, M., & Elter, J. F. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.10.059 · Cited by 488
Direct observation of the oxygenated species during oxygen reduction on a platinum fuel cell cathode
Casalongue, H. S., Kaya, S., Viswanathan, V., Miller, D. J., Friebel, D., Hansen, H. A., Nørskov, J. K., Nilsson, A., & Ogasawara, H. (2013) · Nature Communications · doi:10.1038/ncomms3817 · Cited by 426
Surface Area Loss of Supported Platinum in Polymer Electrolyte Fuel Cells
Wilson, M. S., Garzon, F. H., Sickafus, K. E., & Gottesfeld, S. (1993) · Journal of The Electrochemical Society · doi:10.1149/1.2220925 · Cited by 411
Cited by
Ren, P., Pei, P., Li, Y., Wu, Z., Chen, D., & Huang, S. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100859 · Cited by 737
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies
Yang, Y., Peltier, C. R., Zeng, R., Schimmenti, R., Li, Q., Huang, X., Yan, Z., Potsi, G., Selhorst, R., Lu, X., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00331 · Cited by 544
Grim, R. G., Huang, Z., Guarnieri, M. T., Ferrell, J. R., Tao, L., & Schaidle, J. A. (2020) · Energy & Environmental Science · doi:10.1039/c9ee02410g · Cited by 454
Recent developments in catalyst-related PEM fuel cell durability
Borup, R. L., Kusoglu, A., Neyerlin, K. C., Mukundan, R., Ahluwalia, R. K., Cullen, D. A., More, K. L., Weber, A. Z., & Myers, D. J. (2020) · Current Opinion in Electrochemistry · doi:10.1016/j.coelec.2020.02.007 · Cited by 432
Self-citationDu, L., Prabhakaran, V., Xie, X., Park, S., Wang, Y., & Shao, Y. (2021) · Advanced Materials · doi:10.1002/adma.201908232 · Cited by 357
Metadata
- Authors
- Macauley, N., Papadias, D. D., Fairweather, J., Spernjak, D., Langlois, D., Ahluwalia, R., More, K. L., Mukundan, R., & Borup, R. L.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2018
- Volume
- 165
- Issue
- 6
- Pages
- F3148-F3160
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2793801153
- Cited by
- 341
- References
- 35
- FWCI
- 10.91
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Macauley, N., Papadias, D. D., Fairweather, J., Spernjak, D., Langlois, D., Ahluwalia, R., More, K. L., Mukundan, R., & Borup, R. L. (2018). Carbon Corrosion in PEM Fuel Cells and the Development of Accelerated Stress Tests. Journal of The Electrochemical Society. https://doi.org/10.1149/2.0061806jes
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