The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Role of Lithium Salt on Solid Electrolyte Interface (SEI) Formation and Structure in Lithium Ion Batteries
Open accessAbstract
A comparative investigation of the different lithium salts on formation of the solid electrolyte interface (SEI) on binder free graphite anodes for lithium ion batteries has been conducted. The electrolytes investigated include 1 M LiPF 6 , LiBF 4 , LiTFSI, LiFSI, LiDFOB or LiBOB dissolved in ethylene carbonate (EC). The SEI has been investigated via a combination of spectroscopic and microscopic techniques. Transmission electron microscopy (TEM) allows direct observation of the SEI formed from the different electrolytes. Nuclear magnetic resonance (NMR) spectroscopy of D 2 O extracts are utilized to characterize the soluble species of SEI. XPS and FTIR provide additional elemental and functional group information for the SEI components. The SEI for all electrolytes contains lithium ethylene dicarbonate (LEDC), the primary reduction product of EC. In addition, the SEI for all electrolytes contain LiF except for the SEI generated from the LiBOB electrolyte. The SEI generated in the presence of LiBOB or LiDFOB electrolytes contain multiple oxalate containing species, including lithium oxalate (Li 2 C 2 O 4 ), and borates.
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Citations
Cites
An unique lithium salt for the improved electrolyte of Li-ion battery
Shui Zhang, S. (2006) · Electrochemistry Communications · doi:10.1016/j.elecom.2006.06.016 · Cited by 382
LiBOB: Is it an alternative salt for lithium ion chemistry?
Xu, K., Zhang, S. S., Lee, U., Allen, J. L., & Jow, T. R. (2005) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.03.153 · Cited by 203
Cited by
Review—SEI: Past, Present and Future
Peled, E., & Menkin, S. (2017) · Journal of The Electrochemical Society · doi:10.1149/2.1441707jes · Cited by 2,182
An, S. J., Li, J., Daniel, C., Mohanty, D., Nagpure, S., & Wood, D. L. (2016) · Carbon · doi:10.1016/j.carbon.2016.04.008 · Cited by 2,121
Electrolyte Oxidation Pathways in Lithium-Ion Batteries
Rinkel, B. L. D., Hall, D. S., Temprano, I., & Grey, C. P. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c06363 · Cited by 455
Wang, X., Zhang, M., Alvarado, J., Wang, S., Sina, M., Lu, B., Bouwer, J., Xu, W., Xiao, J., Zhang, J.-G., et al. (2017) · Nano Letters · doi:10.1021/acs.nanolett.7b03606 · Cited by 409
Feng, T., Yang, G., Zhang, S., Xu, Z., Zhou, H., & Wu, M. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.134138 · Cited by 88
Metadata
- Authors
- Nie, M., & Lucht, B. L.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2014
- Volume
- 161
- Issue
- 6
- Pages
- A1001-A1006
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2055559797
- Cited by
- 269
- References
- 2
- FWCI
- 7.25
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Nie, M., & Lucht, B. L. (2014). Role of Lithium Salt on Solid Electrolyte Interface (SEI) Formation and Structure in Lithium Ion Batteries. Journal of The Electrochemical Society. https://doi.org/10.1149/2.054406jes
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