The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF6, LiBF4, LiDFOB, LiBOB, and LiTFSI
Open accessAbstract
The reduction products of common lithium salts for lithium ion battery electrolytes, LiPF 6 , LiBF 4 , lithium bisoxalato borate (LiBOB), lithium difluorooxalato borate (LiDFOB), and lithium trifluorosulfonylimide (LiTFSI), have been investigated. The solution phase reduction of different lithium salts via reaction with the one electron reducing agent, lithium naphthalenide, results in near quantitative reactions. Analysis of the solution phase and head space gasses suggests that all of the reduction products are precipitated as insoluble solids. The solids obtained through reduction were analyzed with solution NMR, IR-ATR and XPS. All fluorine containing salts generate LiF upon reduction while all oxalate containing salts generate lithium oxalate. In addition, depending upon the salt other species including, Li x PF y O z , Li x BF y , oligomeric borates, and lithium bis[N-(trifluoromethylsulfonylimino)] trifluoromethanesulfonate are observed.
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Citations
Cites
Michan, A. L., Parimalam, B. S., Leskes, M., Kerber, R. N., Yoon, T., Grey, C. P., & Lucht, B. L. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02282 · Cited by 541
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Cited by
Hou, T., Yang, G., Rajput, N. N., Self, J., Park, S.-W., Nanda, J., & Persson, K. A. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.103881 · Cited by 470
Electrolyte Oxidation Pathways in Lithium-Ion Batteries
Rinkel, B. L. D., Hall, D. S., Temprano, I., & Grey, C. P. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c06363 · Cited by 455
Yu, L., Chen, S., Lee, H., Zhang, L., Engelhard, M. H., Li, Q., Jiao, S., Liu, J., Xu, W., & Zhang, J.-G. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00935 · Cited by 363
Lin, W., Zhu, M., Fan, Y., Wang, H., Tao, G., Ding, M., Liu, N., Yang, H., Wu, J., Fang, J., et al. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.164163 · Cited by 64
Metadata
- Authors
- Parimalam, B. S., & Lucht, B. L.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2018
- Volume
- 165
- Issue
- 2
- Pages
- A251-A255
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2789452614
- Cited by
- 335
- References
- 1
- FWCI
- 8.28
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Parimalam, B. S., & Lucht, B. L. (2018). Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF6, LiBF4, LiDFOB, LiBOB, and LiTFSI. Journal of The Electrochemical Society. https://doi.org/10.1149/2.0901802jes
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