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Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media

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Durst, Julien, Simon, Christoph, Hasché, Frédéric, Gasteiger, Hubert A.·2015·Journal of The Electrochemical Society
DOI 10.1149/2.0981501jes
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Abstract

The hydrogen oxidation and evolution reaction (HOR/HER) behavior of carbon supported metal (Pt, Ir, Rh, Pd) nanoparticle electrocatalysts is studied using the H 2 pump approach, in a proton exchange membrane fuel cell (PEMFC) setup. After describing the best method for normalizing the net faradaic currents to the active surface area of the electrodes, we measure the HOR/HER kinetic parameters (exchange current densities and transfer coefficients) in a temperature range from 313 K to 353 K and calculate the activation energy for the HOR/HER process. We compare the measured kinetic parameters with those extracted from different mass-transport limitation free setups in literature, to evaluate the hydrogen electrocatalysis on these most active surfaces. The HOR/HER activity scales with the following: Pt > Ir ≫ Rh > Pd. The anodic and cathodic transfer coefficients are similar for all metals (ca. 0.5), leading to Tafel slopes of ca. 140 mV/decade at 353 K (except for the anodic branch of Pd and the cathodic branch of Rh). The lowest activation energies are found for Pt and Ir (≈20 kJ/mol). For Rh and Pd, higher activation energies are found (≈30 kJ/mol), and attributed to the formation of surface oxides and hydride phase, respectively.

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Metadata

Authors
Durst, J., Simon, C., Hasché, F., & Gasteiger, H. A.
Venue
Journal of The Electrochemical Society
Publisher
The Electrochemical Society
Published
2014-12-06
Volume
162
Issue
1
Pages
F190-F203
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
DOI
10.1149/2.0981501jes
OpenAlex
W2157440750
Cited by
550
References
10
FWCI
10.48
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media. https://app.cochat.ai/papers/10.1149/2.0981501jes
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Durst, J., Simon, C., Hasché, F., & Gasteiger, H. A. (2015). Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media. Journal of The Electrochemical Society. https://doi.org/10.1149/2.0981501jes

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