First implementation of alkaline polymer electrolyte water electrolysis working only with pure water
Abstract
A new type of water electrolysis is implemented using an alkaline polymer electrolyte (APE) and non-precious metal catalysts, and working only with pure water. The membrane–electrode assembly (MEA) is fabricated by sandwiching a self-crosslinking quaternary ammonia polysulfone (xQAPS) membrane between a Ni–Fe anode and a Ni–Mo cathode, both impregnated with xQAPS ionomer. Such an initial prototype of APE water electrolysis has exhibited decent performance comparable to that of the well-developed alkaline water electrolyzer.
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Highly efficient HER catalysts have a Gibbs free energy of H* adsorption close to zero.
“Highly efficient HER catalysts have a Gibbs free energy of H* adsorption, jDGH* j , close to zero”
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- Authors
- Xiao, L., Zhang, S., Pan, J., Yang, C., He, M., Zhuang, L., & Lu, J.
- Affiliations
- Wuhan University (CN)
- Corresponding author
- Zhuang, Lin
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 7
- Pages
- 7869
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2018990243
- Cited by
- 313
- References
- 23
- Citations by year
- 2026: 15 · 2025: 26 · 2024: 43 · 2023: 34 · 2022: 25 · 2021: 30 · 2020: 26 · 2019: 23 · 2018: 23 · 2017: 16 · 2016: 7 · 2015: 16 · 2014: 16 · 2013: 9 · 2012: 4
- FWCI
- 9.20
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Energy & Environmental Science (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced battery technologies research
- Keywords
- alkaline polymer electrolytes, water electrolysis, non-noble metal catalysts, membrane electrode assembly, ionomers, hydrogen production
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