Cationic Polymerizations

doi:10.1201/9780585400433

Cited by 426Advanced Polymer Synthesis and CharacterizationOrganic and Inorganic Chemical ReactionsOrganometallic Complex Synthesis and Catalysis

Cationic Polymerizations

·1996·CRC Press eBooks

DOI 10.1201/9780585400433

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Abstract

Fundamentals of the reactions of carbocations with nucleophiles mechanistic aspects of cationic polymerization of alkenes controlled/living carbocationic polymerization controlled polymer synthesis by cationic polymerization cationic polymerization of heterocyclics step-growth electrophilic oligomerization and polymerization reactions industrial cationic polymerizations - an overview.

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The three-membered ring of vinyl cyclopropane has considerable ring strain of 115 kJ mol-1.
“The three membered ring has considerable ring strain (115 kJ mol -1 ) [2]”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
The ring strain for oxiranes is 116 kJ mol-1.
“the ring strain for oxiranes [2] is 116 kJ mol -1”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
Rings composed of 3-8 atoms may polymerize due to the loss of enthalpy associated with the loss of ring strain.
“Rings composed of 3 -8 atoms may polymerize due to the loss of enthalpy associated with the loss of ring strain.”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
Lewis acids require a coinitiator (activator), e.g., an alkyl halide or water, in order to polymerize heterocyclic monomers.
“These compounds require a coinitiator (activator), e.g., an alkyl halide or water, in order to polymerize heterocyclic monomers [2,38,60].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
Sulfonium and iodonium salts have achieved industrial importance as cationic photoinitiators.
“Sulfoniumand iodonium-salts have achieved industrial importance as cationic photo initiators [39].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [39]

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“However, it was later realized that since the reactivities of carbocations are much higher than those of carbanions, the exchange reactions were too slow relative to propagation to achieve narrow MWD and controlled MW [6].”
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Venue: CRC Press eBooks
Publisher: CRC Press
Published: 1996-04-26
DOI: 10.1201/9780585400433
OpenAlex: W625995254
Cited by: 426
References: 0
Citations by year: 2026: 3 · 2025: 10 · 2024: 8 · 2023: 6 · 2022: 4 · 2021: 11 · 2020: 13 · 2019: 11 · 2018: 16 · 2017: 11 · 2016: 7 · 2015: 12 · 2014: 11 · 2013: 19 · 2012: 19
Type: reference entry
Language: en
Open access: closed
Locations: CRC Press eBooks (publishedVersion)
Topics: Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Physical Sciences › Chemistry › Spectroscopy › Organic and Inorganic Chemical Reactions
Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
Keywords: cationic polymerization, carbocations, nucleophilic addition, reaction mechanism, living polymerization, controlled polymerization, step-growth polymerization, industrial polymerization

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