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Electrochemical Reduction of Carbon Dioxide at Various Metal Electrodes in Aqueous Potassium Hydrogen Carbonate Solution
Open accessAbstract
The electrochemical reduction of carbon dioxide at various metallic electrodes was carried out potentiostatically at 298 K in aqueous potassium hydrogen carbonate solution in order to make clear the electrocatalysis of metals in reduction of CO2. It was found that metals used as electrodes are classified into four groups according to their main products from CO2, i. e., metallic In, Sn, Hg, and Pb are selective for the production of formic acid; metallic Ag and Au are selective for the formation of carbon monoxide; metallic copper has the highest electrocatalytic activities in formation of hydrocarbons, aldehydes, and alcohols; and metallic Al, Ga, Group a, and Group VIII elements except Pd have scarce electrocatalytic activity in reduction of CO2. Effects of the reduction potential on products from CO2 were also examined in detail for Zn, In, and Au electrodes which have some interesting properties.
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Cites
Electrolytic Reduction of Carbon Dioxide at Mercury Electrode in Aqueous Solution
Hori, Y., & Suzuki, S. (1982) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.55.660 · Cited by 140
Carbon dioxide reduction at low temperature on various metal electrodes
Azuma, M., Hashimoto, K., Hiramoto, M., Watanabe, M., & Sakata, T. (1989) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/0022-0728(89)87158-x · Cited by 89
Cited by
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A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO2 to CO
Zhu, W., Michalsky, R., Metin, Ö., Lv, H., Guo, S., Wright, C. J., Sun, X., Peterson, A. A., & Sun, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409445p · Cited by 1,382
Exceptional Size-Dependent Activity Enhancement in the Electroreduction of CO2 over Au Nanoparticles
Mistry, H., Reske, R., Zeng, Z., Zhao, Z.-J., Greeley, J., Strasser, P., & Cuenya, B. R. (2014) · Journal of the American Chemical Society · doi:10.1021/ja508879j · Cited by 690
Metadata
- Authors
- Noda, H., Ikeda, S., Oda, Y., Imai, K., Maeda, M., & Ito, K.
- Venue
- Bulletin of the Chemical Society of Japan
- Publisher
- Oxford University Press (OUP)
- Published
- 1990-09-01
- Volume
- 63
- Issue
- 9
- Pages
- 2459-2462
- ISSN
- 0009-2673 (ISSN-L)
- 1348-0634
- OpenAlex
- W2117005960
- Cited by
- 256
- References
- 2
- FWCI
- 5.39
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Noda, H., Ikeda, S., Oda, Y., Imai, K., Maeda, M., & Ito, K. (1990). Electrochemical Reduction of Carbon Dioxide at Various Metal Electrodes in Aqueous Potassium Hydrogen Carbonate Solution. Bulletin of the Chemical Society of Japan. https://doi.org/10.1246/bcsj.63.2459
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