The DOI matches its Crossref record, with a small difference in title or year; 1 of the 1 references it cites were found in a registry or an index.
Structural Identification of a Major Cytokinin in Coconut Milk as 14-O-{3-O-(.BETA.-D-Galactopyranosyl-(1.RAR.2)-.ALPHA.-D-galactopyranosyl-(1.RAR.3)-.ALPHA.-L-arabinofuranosyl)-4-O-(.ALPHA.-L-arabinofuranosyl)-.BETA.-D-galactopyranosyl}-trans-zeatin Riboside.
Open accessAbstract
A cytokinin isolated from the fluid endosperm of Cocos mucifera L. (coconut milk), accounting for more than 20% of the total cytokinin activity, was structurally analyzed by NMR techniques, mass spectrometry, and sugar analysis by high performance liquid chromatography (HPLC). The planar structure of the cytokinin was deduced from its NMR and mass spectrometric data. The structure of the sugar moiety, including its absolute structure, was determined by HPLC analysis of alditol acetates and aldononitrile acetates derived from the cytokinin. The configuration of the sugar-sugar bonds was determined by NMR, and the structure was finally identified as 14-O-(3-O-[-beta-D-galactopyranosyl-(1-->2)-alpha-galactopyranosyl-(1--> 3)- alpha-L-arabinofuranosyl]-4-O-(alpha-L-arabino-furanosyl)-beta-D- galactopyranosyl)-trans-zeatin riboside.
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Coconut water contains auxin, various cytokinins, GAs and ABA (Table 2).
“Coconut water contains auxin, various cytokinins, GAs and ABA (Table 2) [4,32,33,34,35].”
From The Chemical Composition and Biological Properties of Coconut (Cocos nucifera L.) Water (2009) · cites this paper as [4]
The paper identifies a cytokinin in coconut milk (p. 1), and the Discussion (p. 4) reports several other substances with cytokinin activity. It does not establish that coconut milk also contains auxin, gibberellins (GAs), or ABA; its general mention of auxins and gibberellins does not place them in coconut milk. (LLM, conf=0.87)
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Cites
Die Kohlenstoff‐13‐NMR‐Spektroskopie
Breitmaier, E., & Bauer, G. R. (1976) · Pharmazie in unserer Zeit · doi:10.1002/pauz.19760050401 · Cited by 605
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Research works printed but not linked: 4
- [2]Mok D. W. S., Mok M. C. (eds.), "Cytokinins: Chemistry, Activity, and Function," CRC Press, Boca Raton, 1994.
- [5]Shantz E. M., Steward F. C., J. Am. Chem. Soc., 74, 6133 (1952).
- [8]Miller C. O., Skoog F., Von Saltza M. H., Strong F. M., J. Am. Chem. Soc., 77, 1392 (1955).
- [9]Miller C. O., Skoog F., Okumura F. S., Von Saltza M. H., Strong F. M., J. Am. Chem. Soc., 77, 2662 (1955).
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The Chemical Composition and Biological Properties of Coconut (Cocos nucifera L.) Water
Yong, J. W. H., Ge, L., Ng, Y. F., & Tan, S. N. (2009) · Molecules · doi:10.3390/molecules14125144 · Cited by 753
Ge, L., Yong, J. W. H., Goh, N. K., Chia, L. S., Tan, S. N., & Ong, E. S. (2005) · Journal of Chromatography B · doi:10.1016/j.jchromb.2005.09.026 · Cited by 126
Composition, Properties and Reactions of Coconut Water
Rethinam, P., & Krishnakumar, V. (2022) · Coconut Water · doi:10.1007/978-3-031-10713-9_4 · Cited by 9
Metadata
- Authors
- KOBAYASHI, H., MORISAKI, N., TAGO, Y., HASHIMOTO, Y., IWASAKI, S., KAWACHI, E., NAGATA, R., & SHUDO, K.
- Affiliations
- Institute for Quantitative Biosciences, The University of Tokyo (JP)
- The University of Tokyo (JP)
- ORCID
- HASHIMOTO, Yuichi
- Venue
- Chemical and Pharmaceutical Bulletin
- Publisher
- Pharmaceutical Society of Japan
- Published
- 1997
- Volume
- 45
- Issue
- 2
- Pages
- 260-264
- ISSN
- 0009-2363 (ISSN-L)
- 1347-5223
- OpenAlex
- W2094202823
- Cited by
- 18
- References
- 1
- Citations by year
- 2025: 1 · 2024: 1 · 2023: 1 · 2022: 3 · 2019: 1 · 2018: 1 · 2017: 1 · 2013: 1
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Chemical and Pharmaceutical Bulletin (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Life Sciences › Agricultural and Biological Sciences › Plant Science › Plant Molecular Biology Research
- Life Sciences › Agricultural and Biological Sciences › Food Science › Coconut Research and Applications
- Life Sciences › Agricultural and Biological Sciences › Plant Science › Plant-Derived Bioactive Compounds
- Keywords
- cytokinins, coconut milk, Cocos nucifera, trans-zeatin riboside, structure elucidation, endosperm, sugar moiety, absolute configuration, alditol acetates, NMR spectroscopy, mass spectrometry
- MeSH terms
- Carbohydrate Sequence, Carbohydrates, Cocos, Cytokinins, Molecular Sequence Data, Magnetic Resonance Spectroscopy, Oligosaccharides, Mass Spectrometry, Zeatin
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