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Holocene dolomitization of supratidal sediments by active tidal pumping, Sugarloaf Key, Florida
Abstract
Sugarloaf Key is an area where Holocene dolomitization is occurring Calcium-rich dolomite is found in a 0.25- to 10-cm-thick surface crust which transgresses a thin layer of carbonate mud overlying the karsted Pleistocene Miami oolite. Radiocarbon ages of the crust range from 160 years B.P. to 1420 years B.P., with a corresponding increase in dolomite content from 0% to 80%. The relatively high permeability of the underlying Pleistocene oolite and low permeability of the Holocene carbonate mud results in a tidal lag between surface water and the partly confined aquifer. Consequently, seawater is pumped upward and downward through the Holocene sediment during spring tides. The highest concentration of dolomite is found in areas where the sediment layer is thinnest and tidal pumping is most effective. Limited analyses of surface and subsurface water taken at intervals throughout the pumping cycle suggest that the dolomitizing fluid is essentially Florida Bay water. The earliest diagenesis is caused by precipitation of dolomite cement, which occurs as 0.1- to 0.3-micron, subrounded crystallites that show no distinct crystal form. During further cementation, and somewhat later, during replacement of preexisting crystallites, poorly ordered dolomite forms as 1- to 5-micron euhedral rhombs. X-ray diffraction data indicate that the crystallized dolomite is better ordered and less calcium-rich than the dolomite composed of crystallites.
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The slow rate derived by Peterson et al. contrasts greatly with the observed size of Holocene dolomite crystals forming in the Florida Keys, the Persian Gulf, and the Coorong of South Australia.
“This result is in great contrast with the observed size of Holocene dolomite crystals forming, for example, in the Florida Keys (Carballo, Land, and Miser, 1987), the Persian Gulf (Baltzer and others, 1994), and the Coorong (von der Borch, Rubin, and Skinner, 1964) of South Australia.”
From The dolomite problem; control of precipitation kinetics by temperature and saturation state (1999) · cites this paper as Carballo, Land, and Miser, 1987
Dolomite is found in environments ranging from the shallow subtidal to supratidal.
“Dolomite is also found in environments ranging from the shallow subtidal (Mazzullo, Bischoff, and Teal, 1995) to supratidal (Carballo, Land, and Miser, 1987).”
From The dolomite problem; control of precipitation kinetics by temperature and saturation state (1999) · cites this paper as Carballo, Land, and Miser, 1987
This style of growth, in which larger crystals form as aggregates of small nuclei, appears quite similar to that described by Carballo, Land, and Miser (1987) in supratidal dolomite forming in contact with little-modified seawater.
“This style of growth, in which larger crystals form as aggregates of small nuclei, appears quite similar to that described by Carballo, Land, and Miser (1987) in supratidal dolomite forming in contact with little-modified seawater”
From The dolomite problem; control of precipitation kinetics by temperature and saturation state (1999) · cites this paper as Carballo, Land, and Miser (1987)
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Dolomite: occurrence, evolution and economically important associations
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“Carballo et al., 1987; Mazzullo et al., 1995 , seawaŽter modified by extensive sulfate reduction Baker .and Kastner, 1981; Kelts and Mackenzie, 1982 , Žseawater mixed with meteoric water Land, 1973; .”
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“These include hypersaline peritidal settings (e.g. Deffeyes et al., 1965; Illing et al., 1965; McKenzie, 1981; Furman et al., 1993) as well as peritidal settings with near-normal sea water (Carballo et al., 1987; Gregg et al., 1992).”
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The dolomite problem; control of precipitation kinetics by temperature and saturation state
Arvidson, R. S. (1999) · American Journal of Science · doi:10.2475/ajs.299.4.257 · Cited by 447
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Microbially catalyzed dolomite formation: From near-surface to burial
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“Interestingly, in aged examples, some rhombohedra appear to be composed of numerous subcrystallites (e.g., Carballo et al., 1987) that may exhibit stepped crystal faces (Lasemi et al., 1989), indicating heterogeneous nucleation and rapid crystal growth from supersaturated solutions (Gregg, 1985;…”
BackgroundLacustrine dolomite—an overview of modern, Holocene, and Pleistocene occurrences
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Geochemical and neomorphic alteration of dolomite: A review
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“Other modern dolomite from the Coorong area, Australia (Von der Borch and Jones, 1976; Rosen et al., 1988), Sugarloaf Key, Florida (Carballo et al., 1987), Ojo de Liebre,Mexico (Pierre et al., 1984),West Caicos, BritishWest Indies (Perkins et al., 1994) andWestern Australia (DeDekker and Last, 1988) have been reported…”
BackgroundPresence of sulfate does not inhibit low-temperature dolomite precipitation
Sánchez-Román, M., McKenzie, J. A., de Luca Rebello Wagener, A., Rivadeneyra, M. A., & Vasconcelos, C. (2009) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2009.06.003 · Cited by 182
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Dissolution enables dolomite crystal growth near ambient conditions
Kim, J., Kimura, Y., Puchala, B., Yamazaki, T., Becker, U., & Sun, W. (2023) · Science · doi:10.1126/science.adi3690 · Cited by 138
Shallow‐burial dolomite cement: a major component of many ancient sucrosic dolomites
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“An alternative interpretation is that the limpid, planar dolomite cements in Pleistocene and older Phanerozoic dolomites are instead coarser analogues of the ultracrystalline dolomite cements (in the order of 0Æ1 to 1 lm) that have been found in Holocene dolomites of lime-mud origin (Gebelein et al., 1980; Carballo et…”
BackgroundMelim, L. A., & Scholle, P. A. (2002) · Sedimentology · doi:10.1046/j.1365-3091.2002.00492.x · Cited by 140
“, 1971; Land, 1973a,b; Folk & Land, 1975) to normal sea water (Saller, 1984; Carballo et al., 1987; Saller & Yaremko, 1994) to hypersaline (1)Present address: Department of Geology, Western Illinois University, 1 University Circle, Macomb, IL 61456, USA.”
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“Butwhat is the evidence for this assumption? On modern tidal-flats, laminated, cm-thick dolomite crusts develop directly underneath the sediment surface (e.g., Shinn et al., 1965; Carballo et al., 1987; Mazullo et al., 1995).”
InfluentialMa, Y., Fan, M., Lu, Y., Guo, X., Hu, H., Chen, L., Wang, C., & Liu, X. (2016) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2016.04.024 · Cited by 130
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“Dolomites directly precipitated from seawater typically have Sr contents of several hundred ppm (Carballo et al., 1987); higher contents are typical for dolomites precipitated in evaporitic environments (Butler and Burns, 1969).”
BackgroundRecrystallization of dolomite: An experimental study from
Malone, M. J., Baker, P. A., & Burns, S. J. (1996) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(96)00062-2 · Cited by 122
Dolomitization: from conceptual to numerical models
Whitaker, F., Smart, P. L., & Jones, G. (2004) · Geological Society London Special Publications · doi:10.1144/gsl.sp.2004.235.01.05 · Cited by 111
“The larger scale of circulation driven by tectonic compaction alleviates somewhat the volumetric limitations. For instance, Knoop et al. (2002) considered syntectonic fluid migration across carbonate units in the western ranges of the Rocky Mountain foreland from deeper siliciclastic rocks during the Mesozoic contract…”
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Unstable to Stable Transformations during Dolomitization
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“This suggests that early dolomite precipitated at or near the sediment–water interface soon after deposition (e.g., Carballo et al. 1987; James et al. 1993; Mazzullo et al. 1995).”
BackgroundKaczmarek, S. E., Gregg, J. M., Bish, D. L., Machel, H. G., & Fouke, B. W. (2017) · Characterization and Modeling of Carbonates–Mountjoy Symposium 1 · doi:10.2110/sepmsp.109.01 · Cited by 95
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Christ, N., Immenhauser, A., Amour, F., et al. (2012) · Sedimentary Geology · doi:10.1016/j.sedgeo.2012.02.008 · Cited by 77
A global study of dolomite stoichiometry and cation ordering through the Phanerozoic
Manche, C. J., & Kaczmarek, S. E. (2021) · Journal of Sedimentary Research · doi:10.2110/jsr.2020.204 · Cited by 76
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Nutman, A. P., Friend, C. R. L., Bennett, V. C., Wright, D., & Norman, M. D. (2010) · Precambrian Research · doi:10.1016/j.precamres.2010.08.006 · Cited by 73
“One model commonly referred to as the ‘magnesium pump’ was nvoked to explain massive dolomitization of carbonate platforms y the circulation or tidal pumping of normal seawater through caronate platforms (e.g. Carballo et al., 1987; Land, 1991).”
BackgroundMineralogical footprints of microbial life
Douglas, S. (2005) · American Journal of Science · doi:10.2475/ajs.305.6-8.503 · Cited by 72
Ma, Y., Lu, Y., Liu, X., Zhai, G., Wang, Y., & Zhang, C. (2019) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2019.06.039 · Cited by 71
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Teal, C. S., Mazzullo, S. J., & Bischoff, W. D. (2000) · Journal of Sedimentary Research · doi:10.1306/2dc4092e-0e47-11d7-8643000102c1865d · Cited by 62
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“Unit A compares well with ‘Type 2 dolomites’ of Rameil (2008) and is considered as ‘penecontemporaneous dolomites’ in presentday tidal flats (Budd, 1997); their formation may be related to tidal and evaporative pumping processes (Carballo et al., 1987).”
MethodRyan, B. H., Kaczmarek, S. E., & Rivers, J. M. (2020) · Sedimentology · doi:10.1111/sed.12726 · Cited by 56
“Some of the most prominent models include dolomitization by normal seawater (Sass & Katz, 1982; Land, 1985, 1991; Carballo et al., 1987; Manche & Kaczmarek, 2019), hypersaline reflux (Adams & Rhodes, 1960; Deffeyes et al.”
BackgroundPetrographic products of freshwater diagenesis in Holocene ooid sands, Schooner Cays, Bahamas
Budd, D. A. (1988) · Carbonates and Evaporites · doi:10.1007/bf03175114 · Cited by 56
Energetics of calcium-rich dolomite
Chai, L., Navrotsky, A., & Reeder, R. J. (1995) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(95)00011-9 · Cited by 67
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Climate-Controlled Early Dolomite, Late Triassic Cyclic Platform Carbonates, Hungary
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“The presence of small amounts of syndepositional dolomite is consistent with observations in modern dolomiteforming environments (Deffeyes et al., 1965; Illing et al., 1965; Shinn et al., 1965; Carballo et al., 1987; Mazzullo et al., 1987).”
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Recrystallization of Dolomite with Time
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Dolomitization of Triassic microbial mat deposits (Hungary): Origin of microcrystalline dolomite
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“624 Tidal pumping across the tidal flat is relatively short-lived but it is regarded as an efficient flow 625 mechanism for dolomitization of surficial intertidal sedimentary veneers (Carballo et al., 1987; Mazullo et 626 al., 1987; Gregg et al., 1992; Teal et al., 2000).”
BackgroundEarly dolomitisation of Late Triassic platform carbonates in the Transdanubian Range (Hungary)
Haas, J., & Demény, A. (2002) · Sedimentary Geology · doi:10.1016/s0037-0738(01)00259-7 · Cited by 42
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“Processes for the near-surface circulation of slightly evaporated seawater driven by brine density and/or sea-level fluctuations include reflux (Adams and Rhodes 1960), evaporative pumping (Hsü and Siegenthler 1969), and marine recharge (Carballo et al. 1987).”
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“Modern primary or penecontemporaneous dolomites occur in several lacustrine and shallow-marine regions, namely South Bonaire, the Bahamas, the Persian Gulf, the Florida keys and the ephemeral lakes of the Coorong region of Australia (Deffeyes et al., 1965; Illings et al., 1965; Shinn et al., 1965; Shinn, 1968; Von der…”
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An urban model for dolomite precipitation: authigenic dolomite on weathered building stones
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“According to Carballo et al. (1987), this kind of dolomitization increases in the first centimeters underneath the sediment surface and provokes cementation of the sediment during the first centuries of burial.”
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“Tidal pumping across the tidal flat is relatively shortlived but it is regarded as an efficient flow mechanism for alteration of surficial intertidal sedimentary veneers (Carballo et al. 1987; Mazzullo et al. 1987; Gregg et al. 1992; Teal et al. 2000).”
BackgroundRyan, B. H., Kaczmarek, S. E., & Rivers, J. M. (2021) · Journal of Sedimentary Research · doi:10.2110/jsr.2020.056 · Cited by 23
Warm acidified seawater: a dolomite solution
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Dolomite Formation in Caribbean Islands: Driven by Plate Tectonics?!
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Formation of Dolomite in Recent Island-Arc Sediments Due to Gas-Seawater-Sediment Interaction
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“Compared to penecontemporaneous sedimentary dolomites, d 18O values for Luise Harbor dolomites (210.2‰ to 28.8‰ VPDB) are extremely low (e.g., Budd 1997; Carballo et al. 1987; Mitchell et al. 1987; Swart et al. 1989).”
BackgroundInfluentialOrigin of modern dolomite in surface lake sediments on the central and western Tibetan Plateau
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Chapter 6 - Marine Diagenetic Environment✩
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Mud cracks and dedolomitization in the Wittenoom Dolomite, Hamersley Group, Western Australia
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Sabkha vs. Salt Basin Model for the Arab Formation Understanding in the Umm Shaif Field, U.A.E.
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Groundwater flow beneath a hypersaline pond, Cluett Key, Florida Bay, Florida
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“The Sr contents of dolomites precipitated from seawater, and evaporitic environments normally reach several hundred parts per million (Carballo et al. 1987), while during digenesis and hydrothermal alteration, Sr is depleted to below 100 ppm (Brand and Veizer 1980).”
BackgroundDynamic hydrology and diagenesis of a submerged Pleistocene fringing reef, Discovery Bay, Jamaica
McCullough, M. L., & Land, L. S. (1992) · Marine Geology · doi:10.1016/0025-3227(92)90089-z · Cited by 11
Self-citationChapter 2 Carbonate Rock Classifications
Mazzullo, S. J., Chilingarian, G. V., & Bissell, H. J. (1992) · Developments in petroleum science · doi:10.1016/s0376-7361(09)70125-6 · Cited by 12
Zhang, Y., Mueller, M., Hoffmann, R., Riechelmann, S., Chakraborty, S., Kaczmarek, S. E., Beyer, C., & Immenhauser, A. (2024) · Sedimentology · doi:10.1111/sed.13228 · Cited by 9
“Fabric-retentive dolomites may replace biogenic and non-biogenic precursor carbonates and form mimetic textures (e.g. Carballo et al ., 1987; Scholle & Ulmer-Scholle, 2003).”
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Diagenetic modification of dolomite in middle Ordovician carbonates, Taiyuan City area, China
Wu, Y., & Wu, Z. (1998) · Sedimentary Geology · doi:10.1016/s0037-0738(97)00079-1 · Cited by 8
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Rock-dominated diagenesis of lacustrine magnesian calcite micrite
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Metadata
- Authors
- Carballo, J., Land, L. S., & Miser, D. E.
- Affiliations
- The University of Texas at Austin (US)
- Venue
- Journal of Sedimentary Research
- Publisher
- Society for Sedimentary Geology
- Published
- 1987-01-01
- Volume
- 57
- Issue
- 1
- Pages
- 153-165
- ISSN
- 0022-4472 (ISSN-L)
- 1938-3681
- 1527-1404
- OpenAlex
- W2144181640
- Semantic Scholar
- 403dab4c052c7923102c47d90442d34d62ed550a
- Cited by
- 139
- References
- 0
- Citations by year
- 2026: 1 · 2025: 2 · 2024: 7 · 2023: 4 · 2021: 2 · 2020: 5 · 2019: 2 · 2018: 4 · 2017: 4 · 2016: 6 · 2015: 5 · 2014: 3 · 2013: 4 · 2012: 2
- FWCI
- 9.43
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Sedimentary Research (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Earth-Surface Processes › Geological formations and processes
- Physical Sciences › Earth and Planetary Sciences › Earth-Surface Processes › Karst Systems and Hydrogeology
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- dolomitization, tidal pumping, karst aquifers, carbonate mud, dolomite cementation, Holocene, early diagenesis, spring tides
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