Cited by 17Clay minerals and soil interactionsGeochemistry and Elemental AnalysisTherapeutic Uses of Natural Elements

Particle properties of hydrothermal ammonium-bearing illite-smectite

Šucha, Vladimír, Uhlík, Peter, Madejová, Jana, Petit, Sabine, Kraus, Ivan, Puškelová, L’ubica·2007·Clays and Clay Minerals

Abstract

Mixed-layer illite-smectite with high degree of ordering (rectorite-like clay) and with three types of interlayer cations — K+, Na+ and NH4+, was determined in the high-sulfide epithermal mineralization of the Western Carpathian Mountains. The tobelitic portion of the clay comprises 5–10%. Ammonium was detected both by chemical analysis and by Fourier transform infrared analysis. Some of the ammonium can be assigned to a poorly bound form, not fully fixed in the illitic interlayer. The finest size fraction separated from the samples behaves differently from the rest of the sample. It contains two layers of water molecules in the expandable interlayers as determined by X-ray diffraction, whereas coarser fractions have only one water layer in the interlayers.

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Crossref · 10.1346/ccmn.2007.0550103

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29 of 29 references verified0 citation errors · 0 not checkable

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Authors
Šucha, V., Uhlík, P., Madejová, J., Petit, S., Kraus, I., & Puškelová, L.
Affiliations
  • Comenius University Bratislava (SK)
  • Slovak Academy of Sciences (SK)
  • Centre National de la Recherche Scientifique (FR)
Corresponding author
Šucha, Vladimír
Venue
Clays and Clay Minerals
Published
2007-02
Volume
55
Issue
1
Pages
36-44
ISSN
  • 0009-8604 (ISSN-L)
  • 1552-8367
OpenAlex
W2159900874
Cited by
17
References
29
Citations by year
2026: 1 · 2024: 1 · 2023: 1 · 2022: 1 · 2019: 1 · 2018: 2 · 2016: 1 · 2015: 2 · 2014: 2 · 2013: 1 · 2012: 2
FWCI
0.17
Type
journal article
Language
en
Open access
closed
Locations
  • Clays and Clay Minerals (publishedVersion)
  • Dipòsit Digital de Documents de la UAB (Universitat Autònoma de Barcelona) (submittedVersion, public-domain)
Funders
Vedecká Grantová Agentúra MŠVVaŠ SR a SAV
Topics
  • Physical Sciences › Materials Science › Biomaterials › Clay minerals and soil interactions
  • Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
  • Health Sciences › Health Professions › Complementary and Manual Therapy › Therapeutic Uses of Natural Elements
Keywords
illite-smectite, ammonium, interlayer cations, particle size fractionation, interlayer water, clay mineralogy, Western Carpathians

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