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How an oxide shell affects the ultraviolet plasmonic behavior of Ga, Mg, and Al nanostructures
Open accessAbstract
The ultraviolet (UV) range presents new challenges for plasmonics, with interesting applications ranging from engineering to biology. In previous research, gallium, aluminum, and magnesium were found to be very promising UV plasmonic metals. However, a native oxide shell surrounds nanostructures of these metals that affects their plasmonic response. Here, through a nanoparticle-oxide core-shell model, we present a detailed electromagnetic analysis of how oxidation alters the UV-plasmonic response of spherical or hemisphere-on-substrate nanostructures made of those metals by analyzing the spectral evolution of two parameters: the absorption efficiency (far-field analysis) and the enhancement of the local intensity averaged over the nanoparticle surface (near-field analysis).
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Al suffers from formation of an oxide layer several nanometers thick that limits UV plasmonic performance.
“However, similar to Mg, Al suffers from the formation of an oxide layer several nanometers thick that limits the UV plasmonic performance.”
From Nanoparticles Engineering by Pulsed Laser Ablation in Liquids: Concepts and Applications (2020) · cites this paper as [194]
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Magnesium as Novel Material for Active Plasmonics in the Visible Wavelength Range
Sterl, F., Strohfeldt, N., Walter, R., Griessen, R., Tittl, A., & Giessen, H. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b03029 · Cited by 188
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Cited by
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Nanoparticles Engineering by Pulsed Laser Ablation in Liquids: Concepts and Applications
Fazio, E., Gökce, B., De Giacomo, A., Meneghetti, M., Compagnini, G., Tommasini, M., Waag, F., Lucotti, A., Zanchi, C. G., Ossi, P. M., et al. (2020) · Nanomaterials · doi:10.3390/nano10112317 · Cited by 346
Metadata
- Authors
- Gutierrez, Y., Ortiz, D., Sanz, J. M., Saiz, J. M., Gonzalez, F., Everitt, H. O., & Moreno, F.
- Affiliations
- Universidad de Cantabria (ES)
- Duke University (US)
- Venue
- Optics Express
- Publisher
- Optica Publishing Group
- Published
- 2016-08-29
- Volume
- 24
- Issue
- 18
- Pages
- 20621
- ISSN
- 1094-4087 (ISSN-L)
- OpenAlex
- W2518415957
- Cited by
- 73
- References
- 1
- Citations by year
- 2026: 2 · 2025: 3 · 2024: 4 · 2023: 7 · 2022: 7 · 2021: 6 · 2020: 16 · 2019: 10 · 2018: 8 · 2017: 10
- FWCI
- 4.50
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Optics Express (publishedVersion)
- PubMed (publishedVersion)
- UCrea (University of Cantabria) (acceptedVersion)
- DukeSpace (Duke University) (submittedVersion, cc-by-nc-nd)
- Funders
- Ministerio de Ciencia e Innovación (MICINN) (FIS2013-45854-P)
- Universidad de Cantabria (UC)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Plasmonic and Surface Plasmon Research
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Gold and Silver Nanoparticles Synthesis and Applications
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Near-Field Optical Microscopy
- Keywords
- ultraviolet plasmonics, oxidation effects, aluminum nanostructures, core-shell nanoparticles, absorption efficiency, electromagnetic simulation
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