PNP-Perthionitrit und PNP-Monothionitrit / PNP-Perthionitrite and PNP-M onothionitrite
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Abstract As a major product from the reaction of PNP-nitrite [P = P(C6H5)3] with elementary sulfur or a PNP-polysulfide (PNP)2S12 in acetone under anaerobic conditions PNP-perthionitrite (PNPnitrosodisulfide) PNP-SSNO has been isolated. VIS/UV-spectra point to a thionitrate or perthionitrate as a precursor. The structures of PNP-SSNO and of the product obtained on treating the perthionitrite with triphenylphosphane in acetonitrile, PNP -SNO (PNP-monothionitrite, PNP-nitrososulfide), have been elucidated through X-ray diffraction and independently from new chemical and NMRspectrometric arguments. PNP-SSN O crystallizes in the orthorhombic space group P ben with a = 11.843(3), b = 16.647(5), c = 15.556(4) Å , PNP -SNO in the triclinic group P1̄ with a = 10.525(3), b = 17.196(5), c = 9.451(3) Å , a = 95.22(3), β = 92.32(3), γ = 91.65(3)°.
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SSNO- is considerably more stable than HSNO even in the presence of high concentrations of thiols.
“The resulting nitroso compound, nitrosopersulfide (perthionitrite; SSNO -) appears, from our recent work [19] and that of Seel et al. [58,59], to be considerably more stable than HSNO -even in the presence of high concentrations of thiols -and, therefore, a potentially better signaling molecule.”
From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [58]
SSNO- is potentially a better signaling molecule than HSNO.
“The resulting nitroso compound, nitrosopersulfide (perthionitrite; SSNO -) appears, from our recent work [19] and that of Seel et al. [58,59], to be considerably more stable than HSNO -even in the presence of high concentrations of thiols -and, therefore, a potentially better signaling molecule.”
From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [58]
The NO-containing yellow compound formed from nitrite and S8 is assigned to be nitrosopersulfide, SSNO-.
“Based on Seel's earlier findings [58,68,69] we assign this product to be nitrosopersulfide, SSNO - [19].”
From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [58]
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Cites
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- Authors
- Seel, F., Kuhn, R., Simon, G., & Wagner, M.
- Affiliations
- Saarland University (DE)
- Venue
- Zeitschrift für Naturforschung B
- Publisher
- Walter de Gruyter GmbH
- Published
- 1985-12-01
- Volume
- 40
- Issue
- 12
- Pages
- 1607-1617
- ISSN
- 0044-3174 (ISSN-L)
- 1865-7117
- 0932-0776
- OpenAlex
- W2068152852
- Cited by
- 59
- References
- 1
- Citations by year
- 2026: 2 · 2025: 4 · 2024: 3 · 2023: 2 · 2022: 1 · 2021: 3 · 2020: 2 · 2019: 4 · 2018: 6 · 2017: 7 · 2016: 4 · 2015: 5 · 2014: 2 · 2013: 1 · 2012: 1
- FWCI
- 4.54
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Zeitschrift für Naturforschung B (publishedVersion, cc-by-nc-nd)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Synthesis and Reactivity of Sulfur-Containing Compounds
- Physical Sciences › Chemistry › Inorganic Chemistry › Synthesis and characterization of novel inorganic/organometallic compounds
- Physical Sciences › Chemistry › Inorganic Chemistry › Crystal structures of chemical compounds
- Keywords
- triphenylphosphine, sulfur, polysulfides, crystal structure
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