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Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy
Abstract
The valence states of Mn in mixed-valent layer and tunnel structure manganese dioxides (MnO 2 ), usually referred to as phyllomanganates and tectomanganates, can be measured by X-ray absorption near-edge structure (XANES) spectroscopy with a precision and accuracy that are difficult to estimate owing to the paucity of well-characterized standards. A compilation of the Mn K-edge XANES spectra of most naturally occurring manganates, synthetic analogs of known structure and chemical composition, and pure-valence phase species is presented and made available as an open source. We intend this compilation to serve as a basis for the spectroscopic determination of the fractions of the Mn 2+, 3+, and 4+ valences in mixed-valent manganates and phase mixtures. The XANES derivatives of tectomanganates and phyllomanganates with no or little Mn 3+ in the MnO 2 layer exhibit intensities, shapes, and relative energy positions of the main features characteristics of a particular valence composition. For these compounds, valence fractions can be derived using linear combination fitting analysis. Best quantitative results are obtained when the unknown spectrum is fit to a weighted sum of all reference spectra in the database with the fractions of species constrained to be non-negative (Combo method). The accuracy of the average valence is estimated to 0.04 v.u. in the range of 3+ to 4+, and decreases when the proportion of divalent Mn is higher than 15%. The accuracy of the method is also lower in (layer Mn 3+ , Mn 4+ ) manganates, because the XANES features are affected non-additively by the amount and distribution of the Jahn-Teller Mn 3+ cations. The merit of the Combo method for the determination of manganese valence sums relative to the methods based on calibration curves is discussed.
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Citations
Cites
Charge Storage Mechanism of MnO2 Electrode Used in Aqueous Electrochemical Capacitor
Toupin, M., Brousse, T., & Bélanger, D. (2004) · Chemistry of Materials · doi:10.1021/cm049649j · Cited by 2,690
Blackwood, L. G., & Malinowski, E. R. (1994) · Technometrics · doi:10.2307/1269209 · Cited by 2,210
Manganese oxides for lithium batteries
Thackeray, M. M. (1997) · Progress in Solid State Chemistry · doi:10.1016/s0079-6786(97)81003-5 · Cited by 1,475
Fast and reversible surface redox reaction of graphene–MnO2 composites as supercapacitor electrodes
Yan, J., Fan, Z., Wei, T., Qian, W., Zhang, M., & Wei, F. (2010) · Carbon · doi:10.1016/j.carbon.2010.06.047 · Cited by 1,403
K-edge absorption spectra of selected vanadium compounds
Wong, J., Lytle, F. W., Messmer, R. P., & Maylotte, D. H. (1984) · Physical Review B · doi:10.1103/physrevb.30.5596 · Cited by 1,078
Characterization of the manganese oxide produced by pseudomonas putida strain MnB1
Villalobos, M., Toner, B., Bargar, J., & Sposito, G. (2003) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(03)00217-5 · Cited by 680
Determination of the number of factors and the experimental error in a data matrix
Malinowski, E. R. (1977) · Analytical Chemistry · doi:10.1021/ac50012a027 · Cited by 514
Quantitative Speciation of Heavy Metals in Soils and Sediments by Synchrotron X-ray Techniques
Manceau, A., Marcus, M. A., & Tamura, N. (2002) · Reviews in Mineralogy and Geochemistry · doi:10.2138/gsrmg.49.1.341 · Cited by 451
Self-citationDrits, V. A., Silvester, E., Gorshkov, A. I., & Manceau, A. (1997) · American Mineralogist · doi:10.2138/am-1997-9-1012 · Cited by 414
Self-citationEvidence for the presence of Mn(III) intermediates in the bacterial oxidation of Mn(II)
Webb, S. M., Dick, G. J., Bargar, J. R., & Tebo, B. M. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0409119102 · Cited by 360
Electron-energy-loss core-edge structures in manganese oxides
Kurata, H., & Colliex, C. (1993) · Physical Review B · doi:10.1103/physrevb.48.2102 · Cited by 345
Ressler, T., Wong, J., Roos, J., & Smith, I. L. (2000) · Environmental Science & Technology · doi:10.1021/es990787x · Cited by 340
XANES calibrations for the oxidation state of iron in a silicate glass
Berry, A. J., O’Neill, H. S. C., Jayasuriya, K. D., Campbell, S. J., & Foran, G. J. (2003) · American Mineralogist · doi:10.2138/am-2003-0704 · Cited by 313
Silvester, E., Manceau, A., & Drits, V. A. (1997) · American Mineralogist · doi:10.2138/am-1997-9-1013 · Cited by 306
Self-citationPinaud, B. A., Chen, Z., Abram, D. N., & Jaramillo, T. F. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp200015p · Cited by 294
McKeown, D. A., & Post, J. E. (2001) · American Mineralogist · doi:10.2138/am-2001-5-611 · Cited by 275
Biotic and abiotic products of Mn(II) oxidation by spores of the marine Bacillus sp.strain SG-1
Bargar, J. R., Tebo, B. M., Bergmann, U., Webb, S. M., Glatzel, P., Chiu, V. Q., & Villalobos, M. (2005) · American Mineralogist · doi:10.2138/am.2005.1557 · Cited by 273
Kraft, S., Stümpel, J., Becker, P., & Kuetgens, U. (1996) · Review of Scientific Instruments · doi:10.1063/1.1146657 · Cited by 273
Ab initio and experimental pre-edge investigations of the MnK-edge XANES in oxide-type materials
Farges, F. (2005) · Physical Review B · doi:10.1103/physrevb.71.155109 · Cited by 263
Lanson, B., Drits, V. A., Silvester, E. J., & Manceau, A. (2000) · American Mineralogist · doi:10.2138/am-2000-5-625 · Cited by 234
Self-citationGaloisy, L., Calas, G., & Arrio, M. A. (2001) · Chemical Geology · doi:10.1016/s0009-2541(00)00322-3 · Cited by 232
Manceau, A., Gorshkov, A. I., & Drits, V. A. (1992) · American Mineralogist · Cited by 231
Self-citationApplications of Synchrotron Radiation in Low-Temperature Geochemistry and Environmental Science
(2002) · De Gruyter eBooks · doi:10.1515/9781501508882 · Cited by 218
Lafferty, B. J., Ginder-Vogel, M., Zhu, M., Livi, K. J. T., & Sparks, D. L. (2010) · Environmental Science & Technology · doi:10.1021/es102016c · Cited by 211
Gaillot, A., Flot, D. M., Drits, V. A., Manceau, A., Burghammer, M. C., & Lanson, B. (2003) · Chemistry of Materials · doi:10.1021/cm021733g · Cited by 191
Self-citationGlatzel, P., Bergmann, U., Yano, J., Visser, H., Robblee, J. H., Gu, W., de Groot, F. M. F., Christou, G., Pecoraro, V. L., Cramer, S. P., et al. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038579z · Cited by 188
Manceau, A., Marcus, M. A., Tamura, N., Proux, O., Geoffroy, N., & Lanson, B. (2004) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2003.11.021 · Cited by 184
Self-citationStructure of synthetic Na-birnessite: Evidence for a triclinic one-layer unit cell
Lanson, B., Drits, V. A., Feng, Q. C., & Manceau, A. (2002) · American Mineralogist · doi:10.2138/am-2002-11-1215 · Cited by 181
Self-citationGunter, T. E., Gavin, C. E., Aschner, M., & Gunter, K. K. (2006) · NeuroToxicology · doi:10.1016/j.neuro.2006.05.002 · Cited by 177
Chalmin, É., Farges, F., & Brown, G. E. (2008) · Contributions to Mineralogy and Petrology · doi:10.1007/s00410-008-0323-z · Cited by 164
Malinowski, E. R. (1978) · Analytica Chimica Acta · doi:10.1016/s0003-2670(01)83099-3 · Cited by 158
Structure of nanocrystalline phyllomanganates produced by freshwater fungi
Grangeon, S., Lanson, B., Miyata, N., Tani, Y., & Manceau, A. (2010) · American Mineralogist · doi:10.2138/am.2010.3516 · Cited by 158
Self-citationManceau, A., Tommaseo, C. E., Rihs, S., Geoffroy, N., Chateigner, D., Schlegel, M. L., Tisserand, D., Marcus, M. A., Tamura, N., & Chen, Z. (2005) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2005.03.018 · Cited by 131
Self-citationEXAFS and principal component analysis: a new shell game
Wasserman, S. R., Allen, P. G., Shuh, D. K., Bucher, J. J., & Edelstein, N. M. (1999) · Journal of Synchrotron Radiation · doi:10.1107/s0909049599000965 · Cited by 130
Garvie, L. A. J., & Craven, A. J. (1994) · Physics and Chemistry of Minerals · doi:10.1007/bf00202132 · Cited by 130
Enzymatic formation of manganese oxides by an Acremonium-like hyphomycete fungus, strain KR21-2
Miyata, N., Tani, Y., Iwahori, K., & Soma, M. (2003) · FEMS Microbiology Ecology · doi:10.1016/s0168-6496(03)00251-4 · Cited by 128
Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy
Wilke, M., Farges, F., Partzsch, G. M., et al. (2006) · American Mineralogist · doi:10.2138/am.2007.1976 · Cited by 123
Determination of the iron oxidation state in Earth materials using XANES pre-edge information
Petit, P.-E., Farges, F., Wilke, M., et al. (2001) · Journal of Synchrotron Radiation · doi:10.1107/s0909049500021063 · Cited by 118
Potentialausbildung an der Mangandioxid-Elektrode als oxidelektrode mit nichtstöchiometrischem oxid
Vetter, K. J., & Jaeger, N. (1966) · Electrochimica Acta · doi:10.1016/0013-4686(66)80018-x · Cited by 109
Ammundsen, B., Jones, D. J., Rozière, J., & Burns, G. R. (1996) · Chemistry of Materials · doi:10.1021/cm960287s · Cited by 96
Jürgensen, A., Widmeyer, J. R., Gordon, R. A., Bendell‐Young, L. I., Moore, M. M., & Crozier, E. D. (2004) · American Mineralogist · doi:10.2138/am-2004-0724 · Cited by 88
Synchrotron X-ray diffraction study of the structure and dehydration behavior of todorokite
Post, J. E., Heaney, P. J., & Hanson, J. C. (2003) · American Mineralogist · doi:10.2138/am-2003-0117 · Cited by 86
Gaillot, A., Drits, V. A., Manceau, A., & Lanson, B. (2006) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2006.09.010 · Cited by 86
Self-citationDetermination of the oxidation states of manganese in brain, liver, and heart mitochondria
Gunter, T. E., Miller, L. M., Gavin, C. E., Eliseev, R. A., Salter, J. D., Buntinas, L., Alexandrov, A., Hammond, S. T., & Gunter, K. K. (2003) · Journal of Neurochemistry · doi:10.1046/j.1471-4159.2003.02122.x · Cited by 83
Birnessite catalysis of the Maillard Reaction: Its significance in natural humification
Jokic, A., Frenkel, A. I., Vairavamurthy, M. A., & Huang, P. M. (2001) · Geophysical Research Letters · doi:10.1029/2001gl013839 · Cited by 83
Zhang, S., Livi, K. J. T., Gaillot, A., Stone, A. T., & Veblen, D. R. (2010) · American Mineralogist · doi:10.2138/am.2010.3468 · Cited by 76
Pecher, K., McCubbery, D., Kneedler, E., Rothe, J., Bargar, J., Meigs, G., Cox, L., Nealson, K. H., & Tonner, B. P. (2003) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(02)01229-2 · Cited by 58
Nakayama, M., Shamoto, M., & Kamimura, A. (2010) · Chemistry of Materials · doi:10.1021/cm101970b · Cited by 57
Classification of Fe-bearing species fromK-edge XANES data using two-parameter correlation plots
Marcus, M. A., Westphal, A. J., & Fakra, S. C. (2008) · Journal of Synchrotron Radiation · doi:10.1107/s0909049508018293 · Cited by 53
Self-citationX-ray absorption studies of manganese valence and local environment in borosilicate waste glasses
McKeown, D. A., Kot, W. K., Gan, H., & Pegg, I. L. (2003) · Journal of Non-Crystalline Solids · doi:10.1016/s0022-3093(03)00482-4 · Cited by 47
Mansot, J. L., Léone, P., Euzen, P., & Palvadeau, P. (1994) · Microscopy Microanalysis Microstructures · doi:10.1051/mmm:019940050207900 · Cited by 47
Rumble, C. A., Conry, T. E., Doeff, M. M., Cairns, E. J., Penner‐Hahn, J. E., & Deb, A. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3494211 · Cited by 38
XANES Spectroscopy: A Promising Tool for Toxicology:
Gunter, K. K., Miller, L. M., Aschner, M., Eliseev, R. A., Depuis, D., Gavin, C. E., & Gunter, T. E. (2002) · NeuroToxicology · doi:10.1016/s0161-813x(02)00034-7 · Cited by 36
Nanometer-sized, divalent-Mn, hydrous silicate domains in geothermal brine precipitates
Manceau, A. (2005) · American Mineralogist · doi:10.2138/am.2005.1599 · Cited by 17
Self-citationAging promotes todorokite formation from layered manganese oxide at near-surface conditions
Cui, H., Liu, F., Feng, X., Tan, W., & Wang, M. K. (2010) · Journal of Soils and Sediments · doi:10.1007/s11368-010-0261-z · Cited by 16
Kim, T. W., Yoo, H., Kim, I. Y., Ha, H.-W., Han, A. R., Chang, J., Lee, J. S., & Hwang, S. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201100218 · Cited by 14
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High-performance Cu2+ adsorption of birnessite using electrochemically controlled redox reactions
Yang, X., Liu, L., Tan, W., Qiu, G., & Liu, F. (2018) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2018.04.069 · Cited by 75
Lenz, C., Behrends, T., Jilbert, T., Silveira, M., & Slomp, C. P. (2014) · Chemical Geology · doi:10.1016/j.chemgeo.2014.01.013 · Cited by 49
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Petrash, D. A., Lalonde, S. V., González-Arismendi, G., Gordon, R. A., Méndez, J. A., Gingras, M. K., & Konhauser, K. O. (2015) · Chemical Geology · doi:10.1016/j.chemgeo.2015.03.017 · Cited by 46
Metadata
- Authors
- Manceau, A., Marcus, M. A., & Grangeon, S.
- Venue
- American Mineralogist
- Publisher
- Mineralogical Society of America
- Published
- 2012-05-01
- Volume
- 97
- Issue
- 5-6
- Pages
- 816-827
- ISSN
- 0003-004X (ISSN-L)
- OpenAlex
- W2041291423
- Cited by
- 351
- References
- 56
- FWCI
- 12.78
- Type
- journal article
- Language
- en
- Open access
- closed
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