Preparation and application of modified zeolites as adsorbents in wastewater treatment
Abstract
Natural zeolite has been recognized as a useful adsorbent for wastewater treatment for removing cations. Natural zeolite is a kind of porous material with large specific surface area but limited adsorption capacity. In recent years, emphasis has been given to prepare the surface modified zeolite using various procedures to enhance the potential of zeolite for pollutants. Modification treatment for zeolite can greatly change surface chemistry and pore structure. The article describes various modification methods of zeolite, and introduces the removal mechanisms of common pollutants such as ammonium, phosphorus and heavy metals. In addition, this review paper intends to present feasibility of applying modified zeolite to constructed wetlands which will be beneficial to achieve higher removal effect.
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Salt treatments can remove water or inorganic impurities by exchanging metal ions within the structure.
“The treatments with salts can remove water or inorganic impurities by exchanging metal ions within the structure.”
From Adsorption of heavy metals on natural zeolites: A review (2023) · cites this paper as Shi et al., 2018
Acid treatment increases the Si/Al ratio because of the dealumination process.
“Moreover, it increases the Si/Al ratio because of the dealumination process (Shi et al., 2018;Wang and Peng, 2010).”
From Adsorption of heavy metals on natural zeolites: A review (2023) · cites this paper as Shi et al., 2018
Treatments with bases can dissolve Si in zeolite and decrease the Si/Al ratio against acid treatment.
“Treatments with bases can dissolve the Si in zeolite and decrease the Si/Al ratio against acid treatment.”
From Adsorption of heavy metals on natural zeolites: A review (2023) · cites this paper as Shi et al., 2018
Higher pH in base treatment can eliminate the crystal structure of zeolite.
“In addition, the higher pH in the treatment with base can eliminate the crystal structure of zeolite (Jovanovic et al., 2012;Shi et al., 2018).”
From Adsorption of heavy metals on natural zeolites: A review (2023) · cites this paper as Shi et al., 2018
The main disadvantage of salt treatment is the high cost of salt reagents.
“Thus, the main disadvantage of salt treatment is the high cost of salt reagents (Liu et al., 2017;Shi et al., 2018).”
From Adsorption of heavy metals on natural zeolites: A review (2023) · cites this paper as Shi et al., 2018
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Harnessing the potential of zeolites for effective fluoride removal from wastewater: a review
Asare, J. A., Alhassan, S. I., Yan, L., Amanze, C., Wu, B., Gang, H., Wei, D., Cao, Y., Wang, H., & Huang, L. (2025) · Environmental Science and Pollution Research · doi:10.1007/s11356-025-36109-9 · Cited by 3 · see citing works
- Authors
- Shi, J., Yang, Z., Dai, H., Lu, X., Peng, L., Tan, X., Shi, L., & Fahim, R.
- Affiliations
- Southeast University (CN)
- Jiangsu University of Science and Technology (CN)
- School of Energy and Environment, Southeast University, No.2 Sipailou Road, Nanjing 210096, China
- Venue
- Water Science and Technology
- Publisher
- IWA Publishing
- Published
- 2018-06-01
- Volume
- 2017
- Issue
- 3
- Pages
- 621-635
- ISSN
- 0273-1223 (ISSN-L)
- 1996-9732
- OpenAlex
- W2806420184
- Cited by
- 132
- References
- 104
- Citations by year
- 2026: 13 · 2025: 18 · 2024: 27 · 2023: 26 · 2022: 23 · 2021: 16 · 2020: 5 · 2019: 3 · 2018: 1
- FWCI
- 0.39
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Water Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Environmental Science › Waste Management and Disposal › Constructed Wetlands for Wastewater Treatment
- Keywords
- modified zeolite, natural zeolite, adsorbents, wastewater treatment, surface modification, cation removal, ammonium removal, phosphorus removal, heavy metal removal, adsorption mechanism, constructed wetlands
- MeSH terms
- Phosphorus, Water Pollutants, Chemical, Zeolites, Water Purification, Wetlands, Wastewater
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