The DOI matches its Crossref record; 127 of the 127 references it cites were found in a registry or an index.
A Review of The Methanol Economy: The Fuel Cell Route
Open accessAbstract
This review presents methanol as a potential renewable alternative to fossil fuels in the fight against climate change. It explores the renewable ways of obtaining methanol and its use in efficient energy systems for a net zero-emission carbon cycle, with a special focus on fuel cells. It investigates the different parts of the carbon cycle from a methanol and fuel cell perspective. In recent years, the potential for a methanol economy has been shown and there has been significant technological advancement of its renewable production and utilization. Even though its full adoption will require further development, it can be produced from renewable electricity and biomass or CO2 capture and can be used in several industrial sectors, which make it an excellent liquid electrofuel for the transition to a sustainable economy. By converting CO2 into liquid fuels, the harmful effects of CO2 emissions from existing industries that still rely on fossil fuels are reduced. The methanol can then be used both in the energy sector and the chemical industry, and become an all-around substitute for petroleum. The scope of this review is to put together the different aspects of methanol as an energy carrier of the future, with particular focus on its renewable production and its use in high-temperature polymer electrolyte fuel cells (HT-PEMFCs) via methanol steam reforming.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Cohen, A. J., Brauer, M., Burnett, R., Anderson, H. R., Frostad, J., Estep, K., Balakrishnan, K., Brunekreef, B., Dandona, L., Dandona, R., et al. (2017) · The Lancet · doi:10.1016/s0140-6736(17)30505-6 · Cited by 6,583
A comprehensive review on PEM water electrolysis
Carmo, M., Fritz, D. L., Mergel, J., & Stolten, D. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.01.151 · Cited by 5,492
Carbon capture and storage (CCS): the way forward
Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
A comparative overview of hydrogen production processes
Nikolaidis, P., & Poullikkas, A. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2016.09.044 · Cited by 3,231
An overview of current status of carbon dioxide capture and storage technologies
Leung, D. Y. C., Caramanna, G., & Maroto-Valer, M. M. (2014) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2014.07.093 · Cited by 3,198
Renewable Power-to-Gas: A technological and economic review
Götz, M., Lefebvre, J., Mörs, F., McDaniel Koch, A., Graf, F., Bajohr, S., Reimert, R., & Kolb, T. (2016) · Renewable Energy · doi:10.1016/j.renene.2015.07.066 · Cited by 2,573
A Process for Capturing CO2 from the Atmosphere
Keith, D. W., Holmes, G., St. Angelo, D., & Heidel, K. (2018) · Joule · doi:10.1016/j.joule.2018.05.006 · Cited by 1,910
Hydrogen Production From Water Electrolysis: Current Status and Future Trends
Ursua, A., Gandia, L. M., & Sanchis, P. (2012) · Proceedings of the IEEE · doi:10.1109/jproc.2011.2156750 · Cited by 1,700
Methanol as a fuel for internal combustion engines
Verhelst, S., Turner, J. W., Sileghem, L., & Vancoillie, J. (2019) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2018.10.001 · Cited by 1,226
Methanol Steam Reforming for Hydrogen Production
Palo, D. R., Dagle, R. A., & Holladay, J. D. (2007) · Chemical Reviews · doi:10.1021/cr050198b · Cited by 1,186
Research works printed but not linked: 48
- Frensch, 2018, Model-Supported Analysis of Degradation Phenomena of a PEM Water Electrolysis Cell under Dynamic Operation, ECS Trans., 85, 37, 10.1149/08511.0037ecst · doi:10.1149/08511.0037ecst
- Larscheid, 2018, Potential of new business models for grid integrated water electrolysis, Renew. Energy, 125, 599, 10.1016/j.renene.2018.02.074 · doi:10.1016/j.renene.2018.02.074
- Cui, X., and Kær, S.K. (2019). Thermodynamic analyses of a moderate-temperature carbon dioxide hydrogenation to methanol via reverse water gas shift process with in situ water removal. Ind. Eng. Chem. Res. · doi:10.1021/acs.iecr.9b01312
- Alberico, 2015, Towards a methanol economy based on homogeneous catalysis: Methanol to H2 and CO2 to methanol, Chem. Commun., 51, 6714, 10.1039/C4CC09471A · doi:10.1039/c4cc09471a
- Zhao, K. (2019). A Brief Review of China’s Methanol Vehicle Pilot and Policy, Methanol Institute. Technical report.
- Ott, J., Gronemann, V., Pontzen, F., Fiedler, E., Grossmann, G., Kersebohm, D.B., Weiss, G., and Witte, C. (2012). Methanol. Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA. · doi:10.1002/14356007.a16_465.pub3
- 1995, Focus on the Chemical Value of Methanol, J. Univ. Eng. Sci., 7, 209
- Bertau, M., Offermanns, H., Plass, L., Schmidt, F., and Wernicke, H.J. (2014). Methanol: The Basic Chemical and Energy Feedstock of the Future: Asinger’s Vision Today, Springer. · DOI · Paper page
- Bertau, M., Offermanns, H., Plass, L., Schmidt, F., and Wernicke, H.J. (2014). Methanol Generation. Methanol: The Basic Chemical and Energy Feedstock of the Future: Asinger’s Vision Today, Springer. · DOI · Paper page
- Christiansen, 2011, Concepts in Syngas Manufacture, Catalyst Science Series, Volume 10, 379
- Bell, D., Towler, B., and Fan, M. (2011). Coal Gasification and Its Applications, Elsevier Ltd.. [1st ed.]. · doi:10.1016/b978-0-8155-2049-8.10003-8
- Liu, K., Song, C., and Subramani, V. (2009). Hydrogen and Syngas Production and Purification Technologies, John Wiley & Sons. · doi:10.1002/9780470561256
- Bertau, M., Offermanns, H., Plass, L., Schmidt, F., and Wernicke, H.J. (2014). Methanol Generation Economics. Methanol: The Basic Chemical and Energy Feedstock of the Future: Asinger’s Vision Today, Springer. · DOI · Paper page
- Isayama, 2008, Biodiesel production by supercritical process with crude bio-methanol prepared by wood gasification, Bioresour. Technol., 99, 4775, 10.1016/j.biortech.2007.09.056 · doi:10.1016/j.biortech.2007.09.056
- Cui, 2019, An enumeration-based synthesis framework for multi-effect distillation processes, Chem. Eng. Res. Des., 144, 216, 10.1016/j.cherd.2019.02.018 · doi:10.1016/j.cherd.2019.02.018
- Cui, 2017, A hybrid design combining double-effect thermal integration and heat pump to the methanol distillation process for improving energy efficiency, Chem. Eng. Process. Process. Intensif., 119, 81, 10.1016/j.cep.2017.06.003 · doi:10.1016/j.cep.2017.06.003
- Dehghani, 2014, Sorption-enhanced methanol synthesis: Dynamic modeling and optimization, J. Taiwan Inst. Chem. Eng., 45, 1490, 10.1016/j.jtice.2013.12.001 · doi:10.1016/j.jtice.2013.12.001
- Bukhtiyarova, 2017, Methanol Synthesis from Industrial CO2 Sources: A Contribution to Chemical Energy Conversion, Catal. Lett., 147, 416, 10.1007/s10562-016-1960-x · doi:10.1007/s10562-016-1960-x
- Joo, 2004, CAMERE Process for methanol synthesis from CO2 hydrogenation, Stud. Surf. Sci. Catal., 153, 67, 10.1016/S0167-2991(04)80221-0 · doi:10.1016/s0167-2991(04)80221-0
- Jensen, 2016, Characterization of a planar solid oxide cell stack operated at elevated pressure, J. Electrochem. Soc., 163, F1596, 10.1149/2.1171614jes · doi:10.1149/2.1171614jes
- Ebbesen, 2013, Biogas upgrading using SOEC with a Ni-ScYSZ electrode, ECS Transactions, Volume 57, 3217, 10.1149/05701.3217ecst · doi:10.1149/05701.3217ecst
- Yoneima, 2016, Effect of Sulfur on the Sintering of Nickel Particles, Mater. Trans., 57, 1374, 10.2320/matertrans.M2015464 · doi:10.2320/matertrans.m2015464
- Brett, 2005, Methanol as a direct fuel in intermediate temperature (500–600 °C) solid oxide fuel cells with copper based anodes, Chem. Eng. Sci., 60, 5649, 10.1016/j.ces.2005.05.030 · doi:10.1016/j.ces.2005.05.030
- Lin, 2013, Pilot-scale chemical–biological system for efficient H2S removal from biogas, Bioresour. Technol., 135, 283, 10.1016/j.biortech.2012.10.040 · doi:10.1016/j.biortech.2012.10.040
- Hansen, 2013, Biogas upgrading: By steam electrolysis or co-electrolysis of biogas and steam?, ECS Trans., 57, 3089, 10.1149/05701.3089ecst · doi:10.1149/05701.3089ecst
- Kiaee, 2013, Improvement of power system frequency stability using alkaline electrolysis plants, Proc. Inst. Mech. Eng. Part J. Power Energy, 227, 115, 10.1177/0957650912466642 · doi:10.1177/0957650912466642
- Guinot, 2015, Profitability of an electrolysis based hydrogen production plant providing grid balancing services, Int. J. Hydrog. Energy, 40, 8778, 10.1016/j.ijhydene.2015.05.033 · doi:10.1016/j.ijhydene.2015.05.033
- Bellotti, 2015, Thermo-economic comparison of hydrogen and hydro-methane produced from hydroelectric energy for land transportation, Int. J. Hydrog. Energy, 40, 2433, 10.1016/j.ijhydene.2014.12.066 · doi:10.1016/j.ijhydene.2014.12.066
- Balta, 2010, Potential methods for geothermal-based hydrogen production, Int. J. Hydrog. Energy, 35, 4949, 10.1016/j.ijhydene.2009.09.040 · doi:10.1016/j.ijhydene.2009.09.040
- Rashid, 2015, Hydrogen Production by Water Electrolysis: A Review of Alkaline Water Electrolysis, PEM Water Electrolysis and High Temperature Water Electrolysis, Int. J. Eng. Adv. Technol. (IJEAT), 4, 2249
- Li, 2019, The effect of Fe3+ contamination in feed water on proton exchange membrane electrolyzer performance, Int. J. Hydrog. Energy, 44, 12952, 10.1016/j.ijhydene.2019.04.015 · doi:10.1016/j.ijhydene.2019.04.015
- Paulose, 2006, Visible light photoelectrochemical and water-photoelectrolysis properties of titania nanotube arrays, J. Photochem. Photobiol. Chem., 178, 8, 10.1016/j.jphotochem.2005.06.013 · doi:10.1016/j.jphotochem.2005.06.013
- Icardi, 2008, Compact direct methanol fuel cells for portable application, J. Power Sour., 176, 460, 10.1016/j.jpowsour.2007.08.048 · doi:10.1016/j.jpowsour.2007.08.048
- González-Espasandín, Ó., Leo, T.J., and Navarro-Arévalo, E. (2014). Fuel cells: A real option for unmanned aerial vehicles propulsion. Sci. World J., 2014. · doi:10.1155/2014/497642
- 2014, Effectiveness of heat-integrated methanol steam reformer and polymer electrolyte membrane fuel cell stack systems for portable applications, J. Power Sour., 270, 166, 10.1016/j.jpowsour.2014.07.072 · doi:10.1016/j.jpowsour.2014.07.072
- Thomas, 2019, Hydrogen mass transport resistance changes in a high temperature polymer membrane fuel cell as a function of current density and acid doping, Electrochim. Acta, 317, 521, 10.1016/j.electacta.2019.06.021 · doi:10.1016/j.electacta.2019.06.021
- Andreasen, S.J., Kær, S.K., Justesen, K.K., and Sahlin, S.L. (2016). High Temperature PEM Fuel Cell Systems, Control and Diagnostics. High Temperature Polymer Electrolyte Membrane Fuel Cells, Springer International Publishing. · doi:10.1007/978-3-319-17082-4_21
- Andreasen, S.J. (2009). Design and Control of High Temperature PEM Fuel Cell System. [Ph.D. Thesis, Aalborg University].
- 2012, Investigating the effects of methanol-water vapor mixture on a PBI-based high temperature PEM fuel cell, Int. J. Hydrog. Energy, 37, 18231, 10.1016/j.ijhydene.2012.09.009 · doi:10.1016/j.ijhydene.2012.09.009
- (2013). Mobile Hybrid Power shows APU with Serenergy HTPEM. Fuel Cells Bull., 2013, 8. · doi:10.1016/s1464-2859(13)70107-x
- Arsalis, 2011, Modeling and off-design performance of a 1kWe HT-PEMFC (high temperature-proton exchange membrane fuel cell)-based residential micro-CHP (combined-heat-and-power) system for Danish single-family households, Energy, 36, 993, 10.1016/j.energy.2010.12.009 · doi:10.1016/j.energy.2010.12.009
- (2013). ZBT, Helbio, Advent demo HTPEM stack in CHP configuration. Fuel Cells Bull., 2013, 11. · doi:10.1016/s1464-2859(13)70114-7
- Nielsen, 2019, Status on Demonstration of Fuel Cell Based Micro-CHP Units in Europe, Fuel Cells, 19, 340, 10.1002/fuce.201800189 · doi:10.1002/fuce.201800189
- Oh, 2004, The electrical and physical properties of alternative material bipolar plate for PEM fuel cell system, Electrochim. Acta, 50, 777, 10.1016/j.electacta.2004.03.061 · doi:10.1016/j.electacta.2004.03.061
- Ji, F., Yang, L., Li, Y., Sun, H., and Sun, G. (2019). Performance enhancement by optimizing the reformer for an internal reforming methanol fuel cell. Energy Sci. Eng., 1–11. · doi:10.1002/ese3.461
- Koponen, 2017, Control and energy efficiency of PEM water electrolyzers in renewable energy systems, Int. J. Hydrog. Energy, 42, 29648, 10.1016/j.ijhydene.2017.10.056 · doi:10.1016/j.ijhydene.2017.10.056
- Konda, 2011, Optimal transition towards a large-scale hydrogen infrastructure for the transport sector: The case for the Netherlands, Int. J. Hydrog. Energy, 36, 4619, 10.1016/j.ijhydene.2011.01.104 · doi:10.1016/j.ijhydene.2011.01.104
- Fornero, 2011, CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. ‘kinetic limit’, Catal. Today, 172, 158, 10.1016/j.cattod.2011.02.036 · doi:10.1016/j.cattod.2011.02.036
Cited by
Efficiency and optimal load capacity of E-Fuel-Based energy storage systems
Tsiklios, C., Schneider, S., Hermesmann, M., & Müller, T. E. (2023) · Advances in Applied Energy · doi:10.1016/j.adapen.2023.100140 · Cited by 48
Zhu, J., Cui, X., & Araya, S. S. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.05.109 · Cited by 39
Self-citationZhu, J., Araya, S. S., Cui, X., & Kær, S. K. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.12.223 · Cited by 39
Self-citation
Metadata
- Authors
- Simon Araya, S., Liso, V., Cui, X., Li, N., Zhu, J., Sahlin, S. L., Jensen, S. H., Nielsen, M. P., & Kær, S. K.
- Venue
- Energies
- Publisher
- MDPI AG
- Published
- 2020-01-29
- Volume
- 13
- Issue
- 3
- Pages
- 596
- ISSN
- 1996-1073 (ISSN-L)
- OpenAlex
- W3003215080
- Cited by
- 298
- References
- 127
- FWCI
- 6.58
- Type
- journal article
- Language
- en
- Open access
- gold
- Funders
- EUDP (64018-0118, 64018-0552)
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: A Review of The Methanol Economy: The Fuel Cell Route. https://app.cochat.ai/papers/10.3390/en13030596
- The paper
- Simon Araya, S., Liso, V., Cui, X., Li, N., Zhu, J., Sahlin, S. L., Jensen, S. H., Nielsen, M. P., & Kær, S. K. (2020). A Review of The Methanol Economy: The Fuel Cell Route. Energies. https://doi.org/10.3390/en13030596
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.