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Fabrications and Applications of Stimulus-Responsive Polymer Films and Patterns on Surfaces: A Review
Open accessAbstract
In the past two decades, we have witnessed significant progress in developing high performance stimuli-responsive polymeric materials. This review focuses on recent developments in the preparation and application of patterned stimuli-responsive polymers, including thermoresponsive layers, pH/ionic-responsive hydrogels, photo-responsive film, magnetically-responsive composites, electroactive composites, and solvent-responsive composites. Many important new applications for stimuli-responsive polymers lie in the field of nano- and micro-fabrication, where stimuli-responsive polymers are being established as important manipulation tools. Some techniques have been developed to selectively position organic molecules and then to obtain well-defined patterned substrates at the micrometer or submicrometer scale. Methods for patterning of stimuli-responsive hydrogels, including photolithography, electron beam lithography, scanning probe writing, and printing techniques (microcontact printing, ink-jet printing) were surveyed. We also surveyed the applications of nanostructured stimuli-responsive hydrogels, such as biotechnology (biological interfaces and purification of biomacromoles), switchable wettability, sensors (optical sensors, biosensors, chemical sensors), and actuators.
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“Moreover, the chemical configuration of stimuli-responsive nanomicelles may be changed intensely reacting to pH, temperature, light, ultrasound, and enzyme deprivation (Figure 6) [131,132].”
From Recent Advances in Nanomicelles Delivery Systems. (2020) · cites this paper as [131]
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Metadata
- Authors
- Chen, J.-K., & Chang, C.-J.
- Affiliations
- National Taiwan University of Science and Technology (TW)
- Feng Chia University (TW)
- Corresponding author
- Chang, Chi-Jung
- Venue
- Materials
- Publisher
- MDPI AG
- Published
- 2014-01-28
- Volume
- 7
- Issue
- 2
- Pages
- 805-875
- ISSN
- 1996-1944 (ISSN-L)
- PMC
- PMC5453090
- OpenAlex
- W2138602189
- Cited by
- 193
- References
- 301
- Citations by year
- 2026: 5 · 2025: 14 · 2024: 6 · 2023: 7 · 2022: 16 · 2021: 16 · 2020: 20 · 2019: 16 · 2018: 26 · 2017: 18 · 2016: 23 · 2015: 18 · 2014: 7
- FWCI
- 6.01
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Materials (publishedVersion, cc-by)
- Europe PMC (PubMed Central) (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
- Funders
- National Science Council
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Biomaterials › Hydrogels: synthesis, properties, applications
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › Nanofabrication and Lithography Techniques
- Keywords
- stimuli-responsive polymers, thermosensitive hydrogel, pH-responsive hydrogels, electroactive composites, photolithography, electron beam lithography, microcontact printing, inkjet printing, switchable wettability, biosensors, chemical sensors, actuators, biointerfaces
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