Recent Advances of Triglyceride Catalytic Pyrolysis via Heterogenous Dolomite Catalyst for Upgrading Biofuel Quality: A Review
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This review provides the recent advances in triglyceride catalytic pyrolysis using heterogeneous dolomite catalysts for upgrading biofuel quality. The production of high-quality renewable biofuels through catalytic cracking pyrolysis has gained significant attention due to their high hydrocarbon and volatile matter content. Unlike conventional applications that require high operational costs, long process times, hazardous material pollution, and enormous energy demand, catalytic cracking pyrolysis has overcome these challenges. The use of CaO, MgO, and activated dolomite catalysts has greatly improved the yield and quality of biofuel, reducing the acid value of bio-oil. Modifications of the activated dolomite surface through bifunctional acid–base properties also positively influenced bio-oil production and quality. Dolomite catalysts have been found to be effective in catalyzing the pyrolysis of triglycerides, which are a major component of vegetable oils and animal fats, to produce biofuels. Recent advances in the field include the use of modified dolomite catalysts to improve the activity and selectivity of the catalytic pyrolysis process. Moreover, there is also research enhancement of the synthesis and modification of dolomite catalysts in improving the performance of biofuel yield conversion. Interestingly, this synergy contribution has significantly improved the physicochemical properties of the catalysts such as the structure, surface area, porosity, stability, and bifunctional acid–base properties, which contribute to the catalytic reaction’s performance.
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Green diesel from upgrading procedures has lower cold-filter point, better economic value, and more diverse uses.
“Green diesel generated by upgrading procedures (e.g., aromatization and isomerization) has a lower cold-filter point, better economic value, and more diverse uses.”
From Biofuel production: exploring renewable energy solutions for a greener future (2024) · cites this paper as [173]
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- Authors
- Zamri, M. F. M. A., Shamsuddin, A. H., Ali, S., Bahru, R., Milano, J., Tiong, S. K., Fattah, I. M. R., & Raja Shahruzzaman, R. M. H.
- Affiliations
- Universiti Tenaga Nasional (MY)
- Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Serdang 43400, Selangor, Malaysia
- National University of Malaysia (MY)
- Institute of Sustainable Energy, Universiti Tenaga Nasional, Jalan IKRAM-UNITEN, Kajang 43000, Selangor, Malaysia
- University of Technology Sydney (AU)
- Corresponding author
- Shamsuddin, Abd Halim
- ORCID
- Venue
- Nanomaterials
- Publisher
- MDPI AG
- Published
- 2023-06-27
- Volume
- 13
- Issue
- 13
- Pages
- 1947
- ISSN
- 2079-4991 (ISSN-L)
- PMC
- PMC10343513
- OpenAlex
- W4382280827
- Cited by
- 24
- References
- 110
- Citations by year
- 2026: 11 · 2025: 8 · 2024: 4 · 2023: 1
- FWCI
- 0.54
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Nanomaterials (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Universiti Putra Malaysia Institutional Repository (Universiti Putra Malaysia) (submittedVersion, cc-by)
- Funders
- UNITEN (J510050002-IC-BOLDREFRESH2025, KETTHA 201801)
- Ministry of Energy and Natural Resources (J510050002-IC-BOLDREFRESH2025, KETTHA 201801)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Physical Sciences › Engineering › Biomedical Engineering › Biodiesel Production and Applications
- Physical Sciences › Engineering › Mechanical Engineering › Catalysis and Hydrodesulfurization Studies
- Keywords
- bio-oil upgrading, biofuel quality, calcium oxide catalyst, magnesium oxide catalyst, vegetable oils, animal fats, catalyst modification, catalyst preparation
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