Waste PET as a Reactant for Lanthanide MOF Synthesis and Application in Sensing of Picric Acid
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In this study, a lanthanide metal organic framework based on the ligand of terephthalic acid derived from waste polyethylene terephthalate (PET) bottles was designed and synthesized. The structure and morphology of the Tb-BDC was investigated by X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM). The Tb-BDC displays a high selectivity and sensitivity towards picric acid (TNP). The luminescence intensities exhibit a linear relation, with a concentration of TNP over the range of 1 × 10−5–1 × 10−4 M, with a limit of detection of 1 × 10−5 M. The sensing mechanism is also discussed. This is the first time that waste PET materials have been used as the starting precursor of terephthalic acid (BDC) for the fabrication of lanthanide MOF (metal organic framework), which is applied in sensing TNP.
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Waste PET bottles can be used as a carbon source to synthesize MOF-derived materials, including composites of ZnO and a lanthanide-based MOF (Tb-BDC) via controlled hydrolysis.
“Al-Enizi and co-workers employed waste polyethylene terephthalate (PET) bottles as a carbon source to synthesize MOF-derived materials [96] .They successfully prepared composites of ZnO and also used PET as a precursor to construct a lanthanide-based MOF (Tb-BDC) via controlled hydrolysis [97] .”
From Functional carbon materials from waste plastics: synthesis and applications (2025) · cites this paper as [97]
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- Authors
- Zhang, F., Chen, S., Nie, S., Luo, J., Lin, S., Wang, Y., & Yang, H.
- Affiliations
- Huanghuai University (CN)
- Guiyang Inspection Center for Food and Drug Control, Guiyang 550081, China; shuyeechan@126.com
- Guiyang University (CN)
- Hanshan Normal University (CN)
- Corresponding author
- Wang, Yi
- Yang, Huan
- Venue
- Polymers
- Publisher
- MDPI AG
- Published
- 2019-12-05
- Volume
- 11
- Issue
- 12
- Pages
- 2015
- ISSN
- 2073-4360 (ISSN-L)
- PMC
- PMC6960514
- OpenAlex
- W2993672444
- Cited by
- 56
- References
- 36
- Citations by year
- 2026: 10 · 2025: 12 · 2024: 12 · 2023: 11 · 2022: 7 · 2021: 1 · 2020: 2 · 2018: 1
- FWCI
- 0.94
- Type
- journal article
- Language
- en
- Open access
- gold
- dx.doi.org
- Licence
- Locations
- Polymers (publishedVersion, cc-by)
- Europe PMC (PubMed Central) (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- Funders
- Programs for Science and Technology Development of Henan province (192102210019)
- Department of Science and Technology in Guangdong (2017B090921002)
- Natural Science Foundation of Guizhou Province of China ([2019] 1008)
- Discipline and Master's Site Construction Project of Guiyang University by Guiyang City Financial Support Guiyang University (HC-2019)
- Major construction project of first-rate university in Guizhou province (2017158134)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Lanthanide and Transition Metal Complexes
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Keywords
- PET waste, metal-organic frameworks, lanthanide MOFs, terbium, terephthalic acid, luminescent sensors, plastic waste valorization
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