The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate oxygen isotopes in Beijing
Open accessAbstract
Abstract. Air quality models have not been able to reproduce the magnitude of the observed concentrations of fine particulate matter (PM2.5) during wintertime Chinese haze events. The discrepancy has been at least partly attributed to low biases in modeled sulfate production rates, due to the lack of heterogeneous sulfate production on aerosols in the models. In this study, we explicitly implement four heterogeneous sulfate formation mechanisms into a regional chemical transport model, in addition to gas-phase and in-cloud sulfate production. We compare the model results with observations of sulfate concentrations and oxygen isotopes, Δ17O(SO42-), in the winter of 2014–2015, the latter of which is highly sensitive to the relative importance of different sulfate production mechanisms. Model results suggest that heterogeneous sulfate production on aerosols accounts for about 20 % of sulfate production in clean and polluted conditions, partially reducing the modeled low bias in sulfate concentrations. Model sensitivity studies in comparison with the Δ17O(SO42-) observations suggest that heterogeneous sulfate formation is dominated by transition metal ion-catalyzed oxidation of SO2.
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Cites
The contribution of outdoor air pollution sources to premature mortality on a global scale
Lelieveld, J., Evans, J. S., Fnais, M., Giannadaki, D., & Pozzer, A. (2015) · Nature · doi:10.1038/nature15371 · Cited by 5,977
Enhanced Role of Transition Metal Ion Catalysis During In-Cloud Oxidation of SO 2
Harris, E., Sinha, B., van Pinxteren, D., Tilgner, A., Fomba, K. W., Schneider, J., Roth, A., Gnauk, T., Fahlbusch, B., Mertes, S., et al. (2013) · Science · doi:10.1126/science.1230911 · Cited by 362
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Rate constant for the reaction of nitrogen dioxide with sulfur(IV) over the pH range 5.3-13
Clifton, C. L., Altstein, N., & Huie, R. E. (1988) · Environmental Science & Technology · doi:10.1021/es00170a018 · Cited by 152
Isotopic constraints on non‐photochemical sulfate production in the Arctic winter
McCabe, J. R., Savarino, J., Alexander, B., Gong, S., & Thiemens, M. H. (2006) · Geophysical Research Letters · doi:10.1029/2005gl025164 · Cited by 63
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Pye, H. O. T., Nenes, A., Alexander, B., Ault, A. P., Barth, M. C., Clegg, S. L., Collett Jr., J. L., Fahey, K. M., Hennigan, C. J., Herrmann, H., et al. (2020) · Atmospheric Chemistry and Physics · doi:10.5194/acp-20-4809-2020 · Cited by 785
Self-citationControl of particulate nitrate air pollution in China
Zhai, S., Jacob, D. J., Wang, X., Liu, Z., Wen, T., Shah, V., Li, K., Moch, J. M., Bates, K. H., Song, S., et al. (2021) · Nature Geoscience · doi:10.1038/s41561-021-00726-z · Cited by 363
Self-citationFast sulfate formation from oxidation of SO2 by NO2 and HONO observed in Beijing haze
Wang, J., Li, J., Ye, J., Zhao, J., Wu, Y., Hu, J., Liu, D., Nie, D., Shen, F., Huang, X., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-16683-x · Cited by 357
Self-citationLiu, T., Chan, A. W. H., & Abbatt, J. P. D. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.0c06496 · Cited by 292
Liu, P., Ye, C., Xue, C., Zhang, C., Mu, Y., & Sun, X. (2020) · Atmospheric Chemistry and Physics · doi:10.5194/acp-20-4153-2020 · Cited by 268
Metadata
- Authors
- Shao, J., Chen, Q., Wang, Y., Lu, X., He, P., Sun, Y., Shah, V., Martin, R. V., Philip, S., Song, S., Zhao, Y., Xie, Z., Zhang, L., & Alexander, B.
- Venue
- Atmospheric Chemistry and Physics
- Publisher
- Copernicus GmbH
- Published
- 2019-05-08
- Volume
- 19
- Issue
- 9
- Pages
- 6107-6123
- ISSN
- 1680-7316 (ISSN-L)
- 1680-7324
- OpenAlex
- W2910302786
- Cited by
- 232
- References
- 5
- FWCI
- 14.58
- Type
- journal article
- Language
- en
- Open access
- gold
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- Shao, J., Chen, Q., Wang, Y., Lu, X., He, P., Sun, Y., Shah, V., Martin, R. V., Philip, S., Song, S., Zhao, Y., Xie, Z., Zhang, L., & Alexander, B. (2019). Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate oxygen isotopes in Beijing. Atmospheric Chemistry and Physics. https://doi.org/10.5194/acp-19-6107-2019
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