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Composite Silica Spheres with Magnetic and Luminescent Functionalities

Salgueiriño‐Maceira, V., Correa‐Duarte, M. A., Spasova, M., Liz‐Marzán, L. M., Farle, M.·2006·Advanced Functional Materials

Abstract

A new class of highly fluorescent, photostable, and magnetic core/shell nanoparticles in the submicrometer size range has been synthesized from a modified Stöber method combined with the layer‐by‐layer (LbL) assembly technique. Luminescent magnetic nanoparticles are prepared via two main steps. The first step involves controlled addition of tetraethoxysilane to a dispersion of Fe 3 O 4/γ‐Fe 2 O 3 nanoparticles, which are thereby homogeneously incorporated as cores into monodisperse silica spheres. The second step involves the LbL assembly of polyelectrolytes and luminescent CdTe quantum dots onto the surfaces of the silica‐coated magnetite/maghemite particles, which are finally covered with an outer shell of silica. These spherical particles have a typical diameter of 220 ± 10 nm and a saturation magnetization of 1.34 emu g–1 at room temperature, and exhibit strong excitonic photoluminescence. Nanoparticles with such a core/shell architecture have the added benefit of providing a robust platform (the outer silica shell) for incorporating diverse functionalities into a single nanoparticle.

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Metadata

Authors
Salgueiriño‐Maceira, V., Correa‐Duarte, M. A., Spasova, M., Liz‐Marzán, L. M., & Farle, M.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2006-01-24
Volume
16
Issue
4
Pages
509-514
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2100753997
Cited by
377
References
1
FWCI
29.30
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Composite Silica Spheres with Magnetic and Luminescent Functionalities. https://app.cochat.ai/papers/10.1002/adfm.200500565
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Salgueiriño‐Maceira, V., Correa‐Duarte, M. A., Spasova, M., Liz‐Marzán, L. M., & Farle, M. (2006). Composite Silica Spheres with Magnetic and Luminescent Functionalities. Advanced Functional Materials. https://doi.org/10.1002/adfm.200500565

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