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Co2P–CoN Double Active Centers Confined in N‐Doped Carbon Nanotube: Heterostructural Engineering for Trifunctional Catalysis toward HER, ORR, OER, and Zn–Air Batteries Driven Water Splitting

Guo, Yingying, Yuan, Pengfei, Zhang, Jianan, Xia, Huicong, Cheng, Fangyi, Zhou, Mengfan, Li, Jin, Qiao, Yueyang, Mu, Shichun, Xu, Qun·2018·Advanced Functional Materials

Abstract

Developing active, robust, and nonprecious electrocatalysts for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR) is highly crucial and challenging. In this work, a facile strategy is developed for scalable fabrication of dicobalt phosphide (Co 2 P)–cobalt nitride (CoN) core–shell nanoparticles with double active sites encapsulated in nitrogen‐doped carbon nanotubes (Co 2 P/CoN‐in‐NCNTs) by straight forward pyrolysis method. Both density functional theory calculation and experimental results reveal that pyrrole nitrogen coupled with Co 2 P is the most active one for HER, while Co–N–C active sites existing on the interfaces between CoN and N‐doped carbon shells are responsible for the ORR and OER activity in this catalyst. Furthermore, liquid‐state and all‐solid‐state Zn–air batteries are equipped. Co 2 P/CoN‐in‐NCNTs show high power density as high as 194.6 mW cm−2, high gravimetric energy density of 844.5 W h kg−1, very low charge–discharge polarization, and excellent reversibility of 96 h at 5 mA cm−2 in liquid system. Moreover, the Co 2 P/CoN‐in‐NCNTs profiles confirm excellent activity for water splitting.

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Metadata

Authors
Guo, Y., Yuan, P., Zhang, J., Xia, H., Cheng, F., Zhou, M., Li, J., Qiao, Y., Mu, S., & Xu, Q.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2018-10-23
Volume
28
Issue
51
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2898563333
Cited by
539
References
7
FWCI
15.21
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Co2P–CoN Double Active Centers Confined in N‐Doped Carbon Nanotube: Heterostructural Engineering for Trifunctional Catalysis toward HER, ORR, OER, and Zn–Air Batteries Driven Water Splitting. https://app.cochat.ai/papers/10.1002/adfm.201805641
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Guo, Y., Yuan, P., Zhang, J., Xia, H., Cheng, F., Zhou, M., Li, J., Qiao, Y., Mu, S., & Xu, Q. (2018). Co2P–CoN Double Active Centers Confined in N‐Doped Carbon Nanotube: Heterostructural Engineering for Trifunctional Catalysis toward HER, ORR, OER, and Zn–Air Batteries Driven Water Splitting. Advanced Functional Materials. https://doi.org/10.1002/adfm.201805641

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