The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
3D Hierarchical ZnIn2S4 Nanosheets with Rich Zn Vacancies Boosting Photocatalytic CO2 Reduction
Abstract
Zinc vacancy (V Zn) is successfully introduced into 3D hierarchical ZnIn 2 S 4 (3D‐ZIS). The photo‐electrochemical experiments demonstrate that the charge separation and carrier transfer are more efficient in the 3D‐ZIS with rich V Zn. Of note, for the first time, it is found that V Zn can decrease the carrier transport activation energy (CTAE), from 1.14 eV for Bulk‐ZIS (Bulk ZnIn 2 S 4) to 0.93 eV for 3D‐ZIS, which may provide a feasible platform for further understanding the mechanism of photocatalytic CO 2 reduction. In situ Fourier transform infrared (FT‐IR) results reveal that the presence of rich V Zn ensures CO 2 chemical activation, promoting single‐electron reduction of CO 2 to CO 2−. In addition, in situ FT‐IR and CO 2 temperature programmed desorption results show that V Zn can promote the formation of surface hydroxyl. To the best of current knowledge, there are no reports on the photoreduction of CO 2 simply by virtue of 3D‐ZIS with V Zn and few literature reports on the photocatalytic reduction of CO 2 concerned with CTAE. Additionally, this work finds that surface hydroxyl may play a crucial role in the process of CO 2 photoreduction. The work may provide some novel ways to ameliorate solar energy conversion performance and a better understanding of photoreaction mechanisms.
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Shi, Y., & Zhang, B. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00434a · Cited by 3,253
Photocatalytic Reduction of CO2 on TiO2 and Other Semiconductors
Habisreutinger, S. N., Schmidt‐Mende, L., & Stolarczyk, J. K. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201207199 · Cited by 2,989
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Hierarchically porous materials: synthesis strategies and structure design
Yang, X.-Y., Chen, L.-H., Li, Y., Rooke, J. C., Sanchez, C., & Su, B.-L. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00829a · Cited by 1,439
Construction of ZnIn2S4–In2O3 Hierarchical Tubular Heterostructures for Efficient CO2 Photoreduction
Wang, S., Guan, B. Y., & Lou, X. W. D. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b02200 · Cited by 1,218
Jiao, X., Chen, Z., Li, X., Sun, Y., Gao, S., Yan, W., Wang, C., Zhang, Q., Lin, Y., Luo, Y., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b02290 · Cited by 1,049
Wang, S., Zhu, B., Liu, M., Zhang, L., Yu, J., & Zhou, M. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.10.019 · Cited by 876
Zhang, S., Liu, X., Liu, C., Luo, S., Wang, L., Cai, T., Zeng, Y., Yuan, J., Dong, W., Pei, Y., et al. (2018) · ACS Nano · doi:10.1021/acsnano.7b07974 · Cited by 709
Yu, H., Li, J., Zhang, Y., Yang, S., Han, K., Dong, F., Ma, T., & Huang, H. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201813967 · Cited by 657
Self-citationQin, J., Wang, S., & Wang, X. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.03.018 · Cited by 637
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Tan, M., Ma, Y., Yu, C., Luan, Q., Li, J., Liu, C., Dong, W., Su, Y., Qiao, L., Gao, L., et al. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202111740 · Cited by 394
Self-citationZnIn2S4‐Based Photocatalysts for Energy and Environmental Applications
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Metadata
- Authors
- He, Y., Rao, H., Song, K., Li, J., Yu, Y., Lou, Y., Li, C., Han, Y., Shi, Z., & Feng, S.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2019-09-02
- Volume
- 29
- Issue
- 45
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2970934007
- Cited by
- 481
- References
- 35
- FWCI
- 10.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- He, Y., Rao, H., Song, K., Li, J., Yu, Y., Lou, Y., Li, C., Han, Y., Shi, Z., & Feng, S. (2019). 3D Hierarchical ZnIn2S4 Nanosheets with Rich Zn Vacancies Boosting Photocatalytic CO2 Reduction. Advanced Functional Materials. https://doi.org/10.1002/adfm.201905153
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