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Relationship between Crystalline Order and Exciton Diffusion Length in Molecular Organic Semiconductors
Open accessAbstract
The effect of crystalline order on the exciton diffusion length (LD) is shown for the archetypal organic semiconductor 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA; see figure). LD increases from ∼6.5 nm in the amorphous limit to ∼25 nm for single crystals. These changes in diffusion length are connected to changes in the fluorescence quantum yield, which is useful for understanding where crystal-size-dependant diffusion trends are likely to be observed for other organic materials.
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Metadata
- Authors
- Lunt, R. R., Benziger, J. B., & Forrest, S. R.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2010-03-19
- Volume
- 22
- Issue
- 11
- Pages
- 1233-1236
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2013354708
- Cited by
- 342
- References
- 18
- FWCI
- 14.52
- Type
- journal article
- Language
- en
- Open access
- green
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- Lunt, R. R., Benziger, J. B., & Forrest, S. R. (2010). Relationship between Crystalline Order and Exciton Diffusion Length in Molecular Organic Semiconductors. Advanced Materials. https://doi.org/10.1002/adma.200902827
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