Various shape memory effects of stimuli-responsive shape memory polymers
Abstract
One-step dual-shape memory polymers (SMPs) recover their original (permanent) shape upon small variation of environmental conditions such as temperature, electric field, light, magnetic field, and solvent/chemicals. For advanced applications such as aerospace and medical devices, complicated, multiple-step, spatially controllable, and two-way shape memory effects (SMEs) are required. In the past decade, researchers have devoted great effort to improve the versatility of the SME of SMPs to meet the needs of advanced applications. This paper is intended to review the up-to-date research endeavors on advanced SMEs. The problems facing the various SMPs are discussed. The challenges and opportunities for future research are discussed. (Some figures may appear in colour only in the online journal)
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Several reversible switching structures have been employed, such as crystallization/melting transition, vitrification/glass transition, liquid crystal anisotropic/isotropic transition, reversible molecule cross-linking reactions, and supramolecular association/disassociation.
“Several reversible switching structures have been employed, such as crystallization/melting transition, vitrification/glass transition, liquid crystal anisotropic/isotropic transition, reversible molecule cross-linking reactions, and supramolecular association/disassociation”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [38]
Net-points determine the permanent shape and can be formed by molecular entanglement, a crystalline phase, chemical cross-linking, an interpenetrated network, or a cyclodextrin polymer's inclusion.
“Net-points determine the permanent shape and can be formed by, e.g., molecular entanglement, a crystalline phase, chemical cross-linking, an interpenetrated network, or a cyclodextrin polymer's inclusion”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [38]
Multi-step programming is not a prerequisite for achieving the multiple-way SME; one-step programming has also been applied.
“multi-step programming is not a prerequisite for achieving the multiple-way SME and one-step programming has been also applied”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [38]
In strategy (ii), the broad glass/melting transition may be considered a consecutive distribution of a certain number of glass/melting transitions, and recovery of the permanent shape from different temporary shapes is triggered at various temperatures corresponding to the deformation temperatures.
“In case of strategy (ii), the broad glass/melting transition may be considered a consecutive distribution of a certain number of glass/melting transitions, and the recovery process of the permanent shape from the different temporary shapes is triggered at various temperatures, corresponding to the temperatures at which the material is deformed”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [38]
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“In case of strategy (ii), the broad glass/melting transition may be considered a consecutive distribution of a certain number of glass/melting transitions, and the recovery process of the permanent shape from the different temporary shapes is triggered at various temperatures, corresponding to the temperatures at whic…”
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- Authors
- Meng, H., Mohamadian, H., Stubblefield, M., Jerro, D., Ibekwe, S., Pang, S.-S., & Li, G.
- Affiliations
- Southern University and Agricultural and Mechanical College (US)
- Louisiana State University (US)
- Venue
- Smart Materials and Structures
- Publisher
- IOP Publishing
- Published
- 2013-08-13
- Volume
- 22
- Issue
- 9
- Pages
- 093001
- ISSN
- 0964-1726 (ISSN-L)
- 1361-665X
- OpenAlex
- W2143647212
- Cited by
- 257
- References
- 385
- Citations by year
- 2026: 1 · 2025: 5 · 2024: 10 · 2023: 3 · 2022: 6 · 2021: 5 · 2020: 7 · 2019: 11 · 2018: 5 · 2017: 14 · 2016: 11 · 2015: 37 · 2014: 56 · 2013: 53 · 2012: 32
- FWCI
- 69.38
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Smart Materials and Structures (publishedVersion)
- Civil War Book Review (submittedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Biomedical Engineering › Dielectric materials and actuators
- Keywords
- shape memory polymers, stimuli-responsive materials, two-way shape memory effect, shape recovery, thermoresponsive polymers, photoresponsive polymers, aerospace applications, medical devices
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