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Recent Advances in Electrochemical CO2‐to‐CO Conversion on Heterogeneous Catalysts

Zheng, Tingting, Jiang, Kun, Wang, Haotian·2018·Advanced Materials

Abstract

Electrochemical reduction of carbon dioxide (CO 2) to fuels and chemicals provides a promising solution for renewable energy storage and utilization. Among the many possible reaction pathways, CO 2 conversion to carbon monoxide (CO) is the first step in the synthesis of more complex carbon‐based fuels and feedstocks, and holds great significance for the chemical industry. Herein, recent advances in heterogeneous catalysts for selective CO evolution from electrochemical reduction of CO 2 are described. With Au catalysts as a paradigm, principles for catalyst design including size, morphology, and grain boundary densities tuning, surface modifications, as well as metal‐support interaction are comprehensively summarized, which shed light on the development of other transition metal catalysts targeting efficient CO 2‐to‐CO conversion. In addition, recently emerged novel materials including transition metal single‐atom catalysts, which present significantly different catalytic behaviors compared to their bulk counterparts and thus open up many unexpected opportunities, are summarized. Furthermore, the technical aspects with respect to large‐scale production of CO are presented, focusing on the full‐cell design and implementation. Finally, short comments related to the future direction of real‐word CO 2 electrolysis for CO supply are provided in terms of catalyst optimization and technical breakthrough.

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Metadata

Authors
Zheng, T., Jiang, K., & Wang, H.
Venue
Advanced Materials
Publisher
Wiley
Published
2018-08-20
Volume
30
Issue
48
Pages
e1802066-e1802066
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2888253280
Cited by
579
References
113
FWCI
13.52
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Recent Advances in Electrochemical CO2‐to‐CO Conversion on Heterogeneous Catalysts. https://app.cochat.ai/papers/10.1002/adma.201802066
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Zheng, T., Jiang, K., & Wang, H. (2018). Recent Advances in Electrochemical CO2‐to‐CO Conversion on Heterogeneous Catalysts. Advanced Materials. https://doi.org/10.1002/adma.201802066

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