The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
A Graphene‐Supported Single‐Atom FeN5 Catalytic Site for Efficient Electrochemical CO2 Reduction
Abstract
Electrochemical conversion of CO 2 into valued products is one of the most important issues but remains a great challenge in chemistry. Herein, we report a novel synthetic approach involving prolonged thermal pyrolysis of hemin and melamine molecules on graphene for the fabrication of a robust and efficient single‐iron‐atom electrocatalyst for electrochemical CO 2 reduction. The single‐atom catalyst exhibits high Faradaic efficiency (ca. 97.0 %) for CO production at a low overpotential of 0.35 V, outperforming all Fe‐N‐C‐based catalysts. The remarkable performance for CO 2‐to‐CO conversion can be attributed to the presence of highly efficient singly dispersed FeN 5 active sites supported on N‐doped graphene with an additional axial ligand coordinated to FeN 4. DFT calculations revealed that the axial pyrrolic nitrogen ligand of the FeN 5 site further depletes the electron density of Fe 3d orbitals and thus reduces the Fe–CO π back‐donation, thus enabling the rapid desorption of CO and high selectivity for CO production.
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Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution
Xue, Y., Huang, B., Yi, Y., Guo, Y., Zuo, Z., Li, Y., Jia, Z., Liu, H., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03896-4 · Cited by 1,011
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887
Achieving Highly Efficient, Selective, and Stable CO2 Reduction on Nitrogen-Doped Carbon Nanotubes
Wu, J., Yadav, R. M., Liu, M., Sharma, P. P., Tiwary, C. S., Ma, L., Zou, X., Zhou, X.-D., Yakobson, B. I., Lou, J., et al. (2015) · ACS Nano · doi:10.1021/acsnano.5b01079 · Cited by 652
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Recent Advances in MOF‐Derived Single Atom Catalysts for Electrochemical Applications
Song, Z., Zhang, L., Doyle‐Davis, K., Fu, X., Luo, J., & Sun, X. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001561 · Cited by 412
Electrocatalysis of Single-Atom Sites: Impacts of Atomic Coordination
Lu, B., Liu, Q., & Chen, S. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01950 · Cited by 394
Ding, J., Wu, D., Zhu, J., Huang, S., Rodríguez-Hernández, F., Chen, Y., Lu, C., Zhou, S., Zhang, J., Tranca, D., et al. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.131320 · Cited by 25
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Metadata
- Authors
- Zhang, H., Li, J., Xi, S., Du, Y., Hai, X., Wang, J., Xu, H., Wu, G., Zhang, J., Lu, J., & Wang, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-09-09
- Volume
- 58
- Issue
- 42
- Pages
- 14871-14876
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2964478950
- Cited by
- 490
- References
- 7
- FWCI
- 14.58
- Type
- journal article
- Language
- en
- Open access
- closed
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