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Phase Engineering of High‐Entropy Alloys
Abstract
High‐entropy alloys (HEAs) are based on five or more principal elements with equal or nearly equal molar fractions and possess many significant advantages over traditional alloys, including high strength and hardness, excellent corrosion resistance, outstanding thermal stability, and irradiation resistance. Phase structure plays a vital role in determining the property of HEAs. For further enhancing the performance of HEAs in various application fields, a controllable synthesis with desired phases is required. In this review, the diverse phase structures of HEAs and the related properties are first introduced. Then, alternative tuning strategies to promote the desired phase structure of HEAs are focused upon. Property adjusting of phase‐engineered HEAs is also discussed in depth. Lastly, some insights into the challenges and future prospects in this rapidly emerging research field are provided.
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Cites
The conflicts between strength and toughness
Ritchie, R. O. (2011) · Nature Materials · doi:10.1038/nmat3115 · Cited by 3,989
Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys
Guo, S., Ng, C., Lu, J., & Liu, C. T. (2011) · Journal of Applied Physics · doi:10.1063/1.3587228 · Cited by 2,911
Tuning element distribution, structure and properties by composition in high-entropy alloys
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Cited by
High-entropy materials for catalysis: A new frontier
Sun, Y., & Dai, S. (2021) · Science Advances · doi:10.1126/sciadv.abg1600 · Cited by 942
High-entropy alloys in electrocatalysis: from fundamentals to applications
Ren, J.-T., Chen, L., Wang, H.-Y., & Yuan, Z.-Y. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00557g · Cited by 551
Subnanometer high-entropy alloy nanowires enable remarkable hydrogen oxidation catalysis
Zhan, C., Xu, Y., Bu, L., Zhu, H., Feng, Y., Yang, T., Zhang, Y., Yang, Z., Huang, B., Shao, Q., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-26425-2 · Cited by 486
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Zeng, K., Hu, R., Zhang, J., Li, X., Xu, Y., Mu, X., Wu, H., Liu, S., Liu, H., Chen, J., et al. (2025) · Nature Communications · doi:10.1038/s41467-025-58495-x · Cited by 58
“More-over, accounting for the disparate physicochemical properties and small size of HEA catalysts, it is also a signi fi cant challenge to tailor their local structure and active site ensembles by post treatments 2,15,37 .”
Metadata
- Authors
- Chang, X., Zeng, M., Liu, K., & Fu, L.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2020-02-26
- Volume
- 32
- Issue
- 14
- Pages
- e1907226-e1907226
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3007409912
- Cited by
- 464
- References
- 5
- FWCI
- 17.26
- Type
- journal article
- Language
- en
- Open access
- closed
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