The DOI matches its Crossref record; 51 of the 51 references it cites were found in a registry or an index.
On the Controlled Loading of Single Platinum Atoms as a Co‐Catalyst on TiO2 Anatase for Optimized Photocatalytic H2 Generation
Open accessAbstract
Single‐atom (SA) catalysis is a novel frontline in the catalysis field due to the often drastically enhanced specific activity and selectivity of many catalytic reactions. Here, an atomic‐scale defect engineering approach to form and control traps for platinum SA sites as co‐catalyst for photocatalytic H 2 generation is described. Thin sputtered TiO 2 layers are used as a model photocatalyst, and compared to the more frequently used (001) anatase sheets. To form stable SA platinum, the TiO 2 layers are reduced in Ar/H 2 under different conditions (leading to different but defined Ti 3+‐O v surface defects), followed by immersion in a dilute hexachloroplatinic acid solution. HAADF‐STEM results show that only on the thin‐film substrate can the density of SA sites be successfully controlled by the degree of reduction by annealing. An optimized SA‐Pt decoration can enhance the normalized photocatalytic activity of a TiO 2 sputtered sample by 150 times in comparison to a conventional platinum‐nanoparticle‐decorated TiO 2 surface. HAADF‐STEM, XPS, and EPR investigation jointly confirm the atomic nature of the decorated Pt on TiO 2. Importantly, the density of the relevant surface exposed defect centers—thus the density of Pt‐SA sites, which play the key role in photocatalytic activity—can be precisely optimized.
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Cites
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
Momma, K., & Izumi, F. (2011) · Journal of Applied Crystallography · doi:10.1107/s0021889811038970 · Cited by 26,054
Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides
Asahi, R., Morikawa, T., Ohwaki, T., Aoki, K., & Taga, Y. (2001) · Science · doi:10.1126/science.1061051 · Cited by 12,252
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Single-atom catalysis of CO oxidation using Pt1/FeOx
Qiao, B., Wang, A., Yang, X., Allard, L. F., Jiang, Z., Cui, Y., Liu, J., Li, J., & Zhang, T. (2011) · Nature Chemistry · doi:10.1038/nchem.1095 · Cited by 7,526
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
Liu, L., & Corma, A. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00776 · Cited by 4,777
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
Yang, X.-F., Wang, A., Qiao, B., Li, J., Liu, J., & Zhang, T. (2013) · Accounts of Chemical Research · doi:10.1021/ar300361m · Cited by 4,770
Heterogeneous single-atom catalysis
Wang, A., Li, J., & Zhang, T. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-018-0010-1 · Cited by 4,191
TiO2 Nanotubes: Synthesis and Applications
Roy, P., Berger, S., & Schmuki, P. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201001374 · Cited by 3,134
Self-citationDefective TiO2 with oxygen vacancies: synthesis, properties and photocatalytic applications
Pan, X., Yang, M.-Q., Fu, X., Zhang, N., & Xu, Y.-J. (2013) · Nanoscale · doi:10.1039/c3nr00476g · Cited by 2,151
Platinum single-atom and cluster catalysis of the hydrogen evolution reaction
Cheng, N., Stambula, S., Wang, D., Banis, M. N., Liu, J., Riese, A., Xiao, B., Li, R., Sham, T.-K., Liu, L.-M., et al. (2016) · Nature Communications · doi:10.1038/ncomms13638 · Cited by 2,072
Cited by
Chen, Y., Soler, L., Cazorla, C., Oliveras, J., Bastús, N. G., Puntes, V. F., & Llorca, J. (2023) · Nature Communications · doi:10.1038/s41467-023-41976-2 · Cited by 157
Huang, H., Chen, Z., Yang, Y., Lin, Y., Fan, Y., Wu, X., Ji, Y., Wang, Y., Yang, C., Yu, Y., et al. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202414298 · Cited by 19
Metadata
- Authors
- Hejazi, S., Mohajernia, S., Osuagwu, B., Zoppellaro, G., Andryskova, P., Tomanec, O., Kment, S., Zbořil, R., & Schmuki, P.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2020-03-03
- Volume
- 32
- Issue
- 16
- Pages
- e1908505-e1908505
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3009511332
- Cited by
- 319
- References
- 51
- FWCI
- 8.48
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Hejazi, S., Mohajernia, S., Osuagwu, B., Zoppellaro, G., Andryskova, P., Tomanec, O., Kment, S., Zbořil, R., & Schmuki, P. (2020). On the Controlled Loading of Single Platinum Atoms as a Co‐Catalyst on TiO2 Anatase for Optimized Photocatalytic H2 Generation. Advanced Materials. https://doi.org/10.1002/adma.201908505
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