The DOI matches its Crossref record; 20 of the 20 references it cites were found in a registry or an index.
Nucleophilic Phosphine Organocatalysis
Abstract
Phosphines have recently become popular choices as nucleophilic catalysts in organic synthesis. The unique reactivity of phosphines compared to amines has allowed the discovery of new nucleophilic addition reactions at the α‐ and γ‐positions of unsaturated carbonyl compounds, as well as novel [3+2] and [4+2] cycloaddition reactions of activated alkynes and alkenes. The accessibility of chiral phosphines has rendered several of these transformations enantioselective and has made possible the kinetic resolution of racemic secondary alcohols by phosphine‐catalyzed acylation. This mini‐review presents recent advances in nucleophilic phosphine organocatalysis for carbon‐carbon bond formation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Recent Advances in the Baylis−Hillman Reaction and Applications
Basavaiah, D., Rao, A. J., & Satyanarayana, T. (2003) · Chemical Reviews · doi:10.1021/cr010043d · Cited by 1,597
4‐Dialkylaminopyridines as Highly Active Acylation Catalysts. [New synthetic method (25)]
Höfle, G., Steglich, W., & Vorbrüggen, H. (1978) · Angewandte Chemie International Edition in English · doi:10.1002/anie.197805691 · Cited by 1,203
Proline-catalyzed asymmetric reactions
List, B. (2002) · Tetrahedron · doi:10.1016/s0040-4020(02)00516-1 · Cited by 1,154
Enantioselective Organocatalysis
Dalko, P. I., & Moisan, L. (2001) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20011015)40:20<3726::aid-anie3726>3.0.co;2-d · Cited by 1,127
Reactions of Electron-Deficient Alkynes and Allenes under Phosphine Catalysis
Lu, X., Zhang, C., & Xu, Z. (2001) · Accounts of Chemical Research · doi:10.1021/ar000253x · Cited by 1,030
Application of the Principle of Hard and Soft Acids and Bases to Organic Chemistry
Pearson, R. G., & Songstad, J. (1967) · Journal of the American Chemical Society · doi:10.1021/ja00984a014 · Cited by 906
Zhang, C., & Lu, X. (1995) · The Journal of Organic Chemistry · doi:10.1021/jo00114a048 · Cited by 655
Amino acids and peptides as asymmetric organocatalysts
Jarvo, E. R., & Miller, S. J. (2002) · Tetrahedron · doi:10.1016/s0040-4020(02)00122-9 · Cited by 655
Swain, C. G., & Scott, C. B. (1953) · Journal of the American Chemical Society · doi:10.1021/ja01097a041 · Cited by 628
Nucleophilic reactivity constants toward methyl iodide and trans-dichlorodi(pyridine)platinum(II)
Pearson, R. G., Sobel, H. R., & Songstad, J. (1968) · Journal of the American Chemical Society · doi:10.1021/ja01004a021 · Cited by 455
Cited by
Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis
Hoyle, C. E., Lowe, A. B., & Bowman, C. N. (2010) · Chemical Society Reviews · doi:10.1039/b901979k · Cited by 1,639
Organocatalytic Ring-Opening Polymerization
Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489
Zhou, F., Liu, Y., & Zhou, J. (2010) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201000161 · Cited by 1,252
Organocatalysis: Opportunities and Challenges for Polymer Synthesis
Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907
Palladium-Catalyzed Cross-Coupling Reactions: A Powerful Tool for the Synthesis of Agrochemicals
Devendar, P., Qu, R.-Y., Kang, W.-M., He, B., & Yang, G.-F. (2018) · Journal of Agricultural and Food Chemistry · doi:10.1021/acs.jafc.8b03792 · Cited by 448
Metadata
- Authors
- Methot, J. L., & Roush, W. R.
- Venue
- Advanced Synthesis & Catalysis
- Publisher
- Wiley
- Published
- 2004-08
- Volume
- 346
- Issue
- 9-10
- Pages
- 1035-1050
- ISSN
- 1615-4150 (ISSN-L)
- 1615-4169
- OpenAlex
- W2068871883
- Cited by
- 983
- References
- 20
- FWCI
- 13.13
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Nucleophilic Phosphine Organocatalysis. https://app.cochat.ai/papers/10.1002/adsc.200404087
- The paper
- Methot, J. L., & Roush, W. R. (2004). Nucleophilic Phosphine Organocatalysis. Advanced Synthesis & Catalysis. https://doi.org/10.1002/adsc.200404087
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
